Space-Time Quantum Metasurfaces.

Metasurfaces have recently entered the realm of quantum photonics, enabling manipulation of quantum light using a compact nanophotonic platform. Realizing the full potential of metasurfaces at the deepest quantum level requires the ability to tune coherent light-matter interactions continuously in space and time. Here, we introduce the concept of space-time quantum metasurfaces for arbitrary control of the spectral, spatial, and spin properties of nonclassical light using a compact photonic platform. We show that space-time quantum metasurfaces allow on-demand tailoring of entanglement among all degrees of freedom of a single photon. We also show that spatiotemporal modulation induces asymmetry at the fundamental level of quantum fluctuations, resulting in the generation of steered and vortex photon pairs out of vacuum. Space-time quantum metasurfaces have the potential to enable novel photonic functionalities, such as encoding quantum information into high-dimensional color qudits using designer modulation protocols, sculpting multispectral and multispatial modes in spontaneous emission, and generating reconfigurable hyperentanglement for high-capacity quantum communications.

Near-Field Radiative Heat Transfer Eigenmodes.

The near-field electromagnetic interaction between nanoscale objects produces enhanced radiative heat transfer that can greatly surpass the limits established by far-field blackbody radiation. Here, we present a theoretical framework to describe the temporal dynamics of the radiative heat transfer in ensembles of nanostructures, which is based on the use of an eigenmode expansion of the equations that govern this process. Using this formalism, we identify the fundamental principles that determine the thermalization of collections of nanostructures, revealing general but often unintuitive dynamics. Our results provide an elegant and precise approach to efficiently analyze the temporal dynamics of the near-field radiative heat transfer in systems containing a large number of nanoparticles.

Surface-wave-assisted nonreciprocity in spatio-temporally modulated metasurfaces.

Emerging photonic functionalities are mostly governed by the fundamental principle of Lorentz reciprocity. Lifting the constraints imposed by this principle could circumvent deleterious effects that limit the performance of photonic systems. Most efforts to date have been limited to waveguide platforms. Here, we propose and experimentally demonstrate a spatio-temporally modulated metasurface capable of complete violation of Lorentz reciprocity by reflecting an incident beam into far-field radiation in forward scattering, but into near-field surface waves in reverse scattering. These observations are shown both in nonreciprocal beam steering and nonreciprocal focusing. We also demonstrate nonreciprocal behavior of propagative-only waves in the frequency- and momentum-domains, and simultaneously in both. We develop a generalized Bloch-Floquet theory which offers physical insights into Lorentz nonreciprocity for arbitrary spatial phase gradients, and its predictions are in excellent agreement with experiments. Our work opens exciting opportunities in applications where free-space nonreciprocal wave propagation is desired.

Metasurface-based ultra-lightweight high-gain off-axis flat parabolic reflectarray for microwave beam collimation/focusing.

Ultra-lightweight deployable antennas with high-gain are pivotal communication components for small satellites, which are intrinsically constrained in size, weight, and power. In this work, we design and demonstrate metasurface-based ultra-lightweight flat off-axis reflectarrays for microwave beam collimation and focusing, similar to a parabolic dish-antenna. Our ultra-thin reflectarrays employ resonators of variable sizes to cover the full 2π phase range, and are arranged on the metasurface to realize a two-dimensional parabolic focusing phase distribution. We demonstrate a 30° off-axis focusing reflector that exhibits a measured gain of 27.5 dB at the central operating frequency of 11.8 GHz and a 3 dB directionality <[Formula: see text]1.6°. Furthermore, we carry out full-wave simulations of the reflectarray, showing high gain of the beam focusing/collimation functionality, in good agreement with measurements. The demonstrated reflectarrays will enable low-cost, lightweight, and high-gain deployable transceivers for small-satellite platforms.

Highly Plasmonic Titanium Nitride by Room-Temperature Sputtering.

Titanium nitride (TiN) has recently emerged as an attractive alternative material for plasmonics. However, the typical high-temperature deposition of plasmonic TiN using either sputtering or atomic layer deposition has greatly limited its potential applications and prevented its integration into existing CMOS device architectures. Here, we demonstrate highly plasmonic TiN thin films and nanostructures by a room-temperature, low-power, and bias-free reactive sputtering process. We investigate the optical properties of the TiN films and their dependence on the sputtering conditions and substrate materials. We find that our TiN possesses one of the largest negative values of the real part of the dielectric function as compared to all other plasmonic TiN films reported to date. Two-dimensional periodic arrays of TiN nanodisks are then fabricated, from which we validate that strong plasmonic resonances are supported. Our room-temperature deposition process can allow for fabricating complex plasmonic TiN nanostructures and be integrated into the fabrication of existing CMOS-based photonic devices to enhance their performance and functionalities.

High-Temperature Refractory Metasurfaces for Solar Thermophotovoltaic Energy Harvesting.

Solar energy promises a viable solution to meet the ever-increasing power demand by providing a clean, renewable energy alternative to fossil fuels. For solar thermophotovoltaics (STPV), high-temperature absorbers and emitters with strong spectral selectivity are imperative to efficiently couple solar radiation into photovoltaic cells. Here, we demonstrate refractory metasurfaces for STPV with tailored absorptance and emittance characterized by in situ high-temperature measurements, featuring thermal stability up to at least 1200 °C. Our tungsten-based metasurface absorbers have close-to-unity absorption from visible to near-infrared and strongly suppressed emission at longer wavelengths, while our metasurface emitters provide wavelength-selective emission spectrally matched to the band-edge of InGaAsSb photovoltaic cells. The projected overall STPV efficiency is as high as 18% when a fully integrated absorber/emitter metasurface structure is employed, which is comparable to the efficiencies of the best currently available commercial single-junction PV cells and can be further improved to potentially exceed those in mainstream photovoltaic technologies. Our work opens a path forward for high-performance STPV systems based on refractory metasurface structures.

Casimir force phase transitions in the graphene family.

The Casimir force is a universal interaction induced by electromagnetic quantum fluctuations between any types of objects. The expansion of the graphene family by adding silicene, germanene and stanene (2D allotropes of Si, Ge, and Sn), lends itself as a platform to probe Dirac-like physics in honeycomb staggered systems in such a ubiquitous interaction. We discover Casimir force phase transitions between these staggered 2D materials induced by the complex interplay between Dirac physics, spin-orbit coupling and externally applied fields. In particular, we find that the interaction energy experiences different power law distance decays, magnitudes and dependences on characteristic physical constants. Furthermore, due to the topological properties of these materials, repulsive and quantized Casimir interactions become possible.

Metasurface Broadband Solar Absorber.

We demonstrate a broadband, polarization independent, wide-angle absorber based on a metallic metasurface architecture, which accomplishes greater than 90% absorptance in the visible and near-infrared range of the solar spectrum, and exhibits low absorptivity (emissivity) at mid- and far-infrared wavelengths. The complex unit cell of the metasurface solar absorber consists of eight pairs of gold nano-resonators that are separated from a gold ground plane by a thin silicon dioxide spacer. Our experimental measurements reveal high-performance absorption over a wide range of incidence angles for both s- and p-polarizations. We also investigate numerically the frequency-dependent field and current distributions to elucidate how the absorption occurs within the metasurface structure.

Radiative heat transfer in 2D Dirac materials.

We compute the radiative heat transfer between two sheets of 2D Dirac materials, including topological Chern insulators and graphene, within the framework of the local approximation for the optical response of these materials. In this approximation, which neglects spatial dispersion, we derive both numerically and analytically the short-distance asymptotic of the near-field heat transfer in these systems, and show that it scales as the inverse of the distance between the two sheets. Finally, we discuss the limitations to the validity of this scaling law imposed by spatial dispersion in 2D Dirac materials.

Friction forces on atoms after acceleration.

The aim of this paper is to revisit the calculation of atom-surface quantum friction in the quantum field theory formulation put forward by Barton (2010 New J. Phys. 12 113045). We show that the power dissipated into field excitations and the associated friction force depend on how the atom is boosted from being initially at rest to a configuration in which it is moving at constant velocity (v) parallel to the planar interface. In addition, we point out that there is a subtle cancellation between the one-photon and part of the two-photon dissipating power, resulting in a leading order contribution to the frictional power which goes as v(4). These results are also confirmed by an alternative calculation of the average radiation force, which scales as v(3).

Geometry-induced Casimir suspension of oblate bodies in fluids.

We predict that a low-permittivity oblate body (disk-shaped object) above a thin metal substrate (plate with a hole) immersed in a fluid of intermediate permittivity will experience a metastable equilibrium (restoring force) near the center of the hole. Stability is the result of a geometry-induced transition in the sign of the force, from repulsive to attractive, that occurs as the disk approaches the hole--in planar or nearly planar geometries, the same material combination yields a repulsive force at all separations, in accordance with the Dzyaloshinskii-Lifshitz-Pitaevskii condition of fluid-induced repulsion between planar bodies. We explore the stability of the system with respect to rotations and lateral translations of the disks and demonstrate interesting transitions (bifurcations) in the rotational stability of the disks as a function of their size. Finally, we consider the reciprocal situation in which the disk-plate materials are interchanged and find that in this case the system also exhibits metastability. The forces in the system are sufficiently large to be observed in experiments and should enable measurements based on the diffusion dynamics of the suspended bodies.

Strong Casimir force reduction through metallic surface nanostructuring.

The Casimir force between bodies in vacuum can be understood as arising from their interaction with an infinite number of fluctuating electromagnetic quantum vacuum modes, resulting in a complex dependence on the shape and material of the interacting objects. Becoming dominant at small separations, the force has a significant role in nanomechanics and object manipulation at the nanoscale, leading to a considerable interest in identifying structures where the Casimir interaction behaves significantly different from the well-known attractive force between parallel plates. Here we experimentally demonstrate that by nanostructuring one of the interacting metal surfaces at scales below the plasma wavelength, an unexpected regime in the Casimir force can be observed. Replacing a flat surface with a deep metallic lamellar grating with sub-100 nm features strongly suppresses the Casimir force and for large inter-surfaces separations reduces it beyond what would be expected by any existing theoretical prediction.

Terahertz metamaterials for linear polarization conversion and anomalous refraction.

Polarization is one of the basic properties of electromagnetic waves conveying valuable information in signal transmission and sensitive measurements. Conventional methods for advanced polarization control impose demanding requirements on material properties and attain only limited performance. We demonstrated ultrathin, broadband, and highly efficient metamaterial-based terahertz polarization converters that are capable of rotating a linear polarization state into its orthogonal one. On the basis of these results, we created metamaterial structures capable of realizing near-perfect anomalous refraction. Our work opens new opportunities for creating high-performance photonic devices and enables emergent metamaterial functionalities for applications in the technologically difficult terahertz-frequency regime.

The role of magnetic dipoles and non-zero-order Bragg waves in metamaterial perfect absorbers.

We develop a simple treatment of a metamaterial perfect absorber (MPA) based on grating theory. We analytically prove that the condition of MPA requires the existence of two currents, which are nearly out of phase and have almost identical amplitude, akin to a magnetic dipole. Furthermore, we show that non-zero-order Bragg modes within the MPA may consume electromagnetic energy significantly.

Stable suspension and dispersion-induced transitions from repulsive Casimir forces between fluid-separated eccentric cylinders.

We numerically demonstrate a stable mechanical suspension of a silica cylinder within a metallic cylinder separated by ethanol, via a repulsive Casimir force between the silica and the metal. We investigate cylinders with both circular and square cross sections, and show that the latter exhibit a stable orientation as well as a stable position, via a method to compute Casimir torques for finite objects. Furthermore, the stable orientation of the square cylinder undergoes a 45 degrees transition as the separation length scale is varied, which is explained as a consequence of material dispersion.

Contribution of drifting carriers to the Casimir-Lifshitz and Casimir-Polder interactions with semiconductor materials.

We develop a theory for Casimir-Lifshitz and Casimir-Polder interactions with semiconductor or insulator surfaces that takes into account charge drift in the bulk material through use of the classical Boltzmann equation. We derive frequency-dependent dispersion relations that give the usual Lifshitz results for dielectrics as a limiting case and, in the quasistatic limit, coincide with those recently computed to account for Debye screening in the thermal Lifshitz force with conducting surfaces with small density of carriers.

Probing quantum-vacuum geometrical effects with cold atoms.

The lateral Casimir-Polder force between an atom and a corrugated surface should allow one to study experimentally nontrivial geometrical effects in the electromagnetic quantum vacuum. Here, we derive the theoretical expression of this force in the scattering approach. We show that large corrections to the "proximity force approximation" could be measured using present-day technology with a Bose-Einstein condensate used as a vacuum field sensor.

Ultrasensitive detection of DNA sequences in solution by specific enzymatic labeling.

We present a newly developed technique for the direct detection of very low concentrations of specific nucleic acid sequences in homogeneous solution based on a polymerase extension reaction. This method consists of synthesizing a highly fluorescent nucleic acid reporter molecule using a sequence of the target as a template. Synthesis of the reporter molecule is accomplished by hybridizing a short complementary oligonucleotide primer to the target and extending the reporter using a polymerase and free nucleotides. One of these nucleotides is partially labeled with a fluorophore. The reaction sample is then flowed through the capillary cell of a single molecule detector. Detection of the reporter signifies the presence of the target being sought. Under carefully selected conditions, fluorescence from the reporter molecule is much stronger than that of the free nucleotide background over the detection time. We have derived practical equations that allow us to determine an optimal range of values for the relative reporter and free-nucleotide concentrations. This method allows for the rapid, direct detection of individual targets at femtomolar concentrations without the use of an amplification procedure, such as the polymerase chain reaction.