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1.
Bioresour Technol ; 394: 130296, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38185447

RESUMO

In this work, a novel boehmite-modified carbon adsorbent (BMCC) derived from moldy corn was used for simultaneous removal of P and bisphenol A (BPA) from livestock wastewater. The results showed that BMCC had a high specific surface area (308.82 m2/g) with boehmite nanoparticles anchored on its surface. BMCC showed high P and BPA decontamination capabilities (40.98 mg/g for P and 54.65 mg/g for BPA by Langmuir model). The adsorbed amount of P declined as pH increased from 4 to 10, while the adsorbed amount of BPA remained steady until pH increased to 10. After 6 cycles of BMCC use, the P and BPA adsorption efficiencies reduced by 21.75 % and 19.41 %, respectively. The adsorption of P was dominated by electrostatic attraction and complexation, while the adsorption of BPA was controlled by hydrogen bonding, electrostatic interaction, and π-π association. In conclusion, BMCC is an effective treatment for decontaminating P- and BPA-contaminated livestock wastewater.


Assuntos
Hidróxido de Alumínio , Óxido de Alumínio , Carbono , Fenóis , Poluentes Químicos da Água , Animais , Águas Residuárias , Gado , Fósforo , Descontaminação , Cinética , Compostos Benzidrílicos , Adsorção , Concentração de Íons de Hidrogênio
2.
Bioresour Technol ; 387: 129602, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-37536465

RESUMO

To investigate how sulfur addition affects humification and carbon loss during swine manure (SM) biostabilisation, various proportions of sulfur, i.e., 0 (CK), 0.2%-0.8% (S1-S4) were added to SM in a 70-day pilot-scale test. Compared to CK (16.07%), sulfur addition resulted in the mineralization of 17.05%-24.27% of the total organic carbon. Sulfur addition also reduced CH4 emissions, which were 3.7%-29.3% lower than that of CK. The total global warming potential values were in the range of 913.1-968.2 g CO2 eq kg-1 for all treatments. Although the sulfur-added treatments showed lower HA/FA ratios than CK after 70 days, no significant impact on the maturity of the final products was observed. Sulfur addition impacted the microbial community, CH4, CO2, N2O emissions, and affected the variation of temperature in biowaste biostabilization. These discoveries provided an important basis for understanding the function of sulfur in regulating the aerobic bio-decomposition of organic waste.


Assuntos
Carbono , Esterco , Suínos , Animais , Dióxido de Carbono/análise , Aquecimento Global , Hidrolases , Enxofre , Solo
3.
Preprint em Inglês | medRxiv | ID: ppmedrxiv-20162842

RESUMO

IntroductionD-dimer concentration has been used to identify candidates for intensified anticoagulant treatment for both venous thromboembolism prevention and mitigation of the microthrombotic complications associated with COVID-19. Thromboelastography (TEG) maximum amplitude (MA) has been validated as an indicator of hypercoagulability and MA [≥] 68 mm has been utilized as a marker of hypercoagulability in other conditions. We evaluated the relationship between coagulation, inflammatory, and TEG parameters in patients with COVID-19 on extracorporeal membrane oxygenation (ECMO). MethodsWe performed a single center retrospective analysis of consecutive patients that received ECMO for the treatment of COVID-19. TEG, inflammatory, and coagulation markers were compared in patients with and without thrombotic complications. Correlation tests were performed to identify the coagulation and inflammatory markers that best predict hypercoagulability as defined by an elevated TEG MA. Results168 TEGs were available in 24 patients. C-reactive protein and fibrinogen were significantly higher in patients that developed a thrombotic event versus those that did not (p=0.038 and p=0.043 respectively). D-dimer was negatively correlated with TEG MA (p<0.001) while fibrinogen was positively correlated (p<0.001). A fibrinogen > 441 mg/dL had a sensitivity of 91.2% and specificity of 85.7% for the detection of MA [≥] 68 mm. ConclusionsIn critically ill patients with COVID-19, D-dimer concentration had an inverse relationship with hypercoagulability as measured by TEG MA. D-dimer elevation may reflect severity of COVID-19 related sepsis rather than designate patients likely to benefit from anticoagulation. Fibrinogen concentration may represent a more useful marker of hypercoagulability in this population.

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