Microplastics and Co-pollutants in soil and marine environments: Sorption and desorption dynamics in unveiling invisible danger and key to ecotoxicological risk assessment.

Microplastics (MPs) and their co-pollutants pose significant threats to soil and marine environments, necessitating understanding of their colonization processes to combat the plastic pandemic and protect ecosystems. MPs can act as invisible carriers, concentrating and transporting pollutants, leading to a more widespread and potentially toxic impact than the presence of either MPs or the pollutants alone. Analyzing the sorption and desorption dynamics of MPs is crucial for understanding pollutants amplification and predicting the fate and transport of pollutants in soil and marine environments. This review provides an in-depth analysis of the sorption and desorption dynamics of MPs, highlighting the importance of considering these dynamics in ecotoxicological risk assessment of MPs pollution. The review identifies limitations of current frameworks that neglect these interactions and proposes incorporating sorption and desorption data into robust frameworks to improve the ability to predict ecological risks posed by MPs and co-pollutants in soil and marine environments. However, failure to address the interplay between sorption and desorption can result in underestimation of the true impact of MPs and co-pollutants, affecting livelihoods and agro-employments, and exacerbate poverty and community disputes (SDGs 1, 2, 3, 8, 9, and 16). It can also affect food production and security (SDG 2), life below water and life on land (DSGs 14 and 15), cultural practices, and natural heritage (SDG 11.4). Hence, it is necessary to develop new approaches to ecotoxicological risk assessment that consider sorption and desorption processes in the interactions between the components in the framework to address the identified limitations.

A review on titanium oxide nanoparticles modified metal-organic frameworks for effective CO2 conversion and efficient wastewater remediation.

Environmental pollution has been increasing since last decade due to increasing industrialisation and urbanisation. Various kinds ofenvironmental pollutants including carbon dioxide (CO2), dyes, pharmaceuticals, phenols, heavy metals along with many organic and inorganic species have been discovered in the various environmental compartments which possess harmful impacts tox human health, wildlife, and ecosystems. Thus, various efforts have been made through regulations, technological advancements, and public awareness campaigns to reduce the impact of the pollution. However, finding suitable alternatives to mitigate their impacts remained a challenge. Metal-organic frameworks (MOFs) are one of the advanced materials with unique features such as high porosity and stability which exhibit versatile applications in environmental remediation. Their composites with titanium oxide nanoparticles (TiO2) have been discovered to offer potential feature such as light harvesting capacity and catalytic activity. The composite integration and properties have been confirmed through characterization using surface area analysis, scanning electron/transmission electron microscopy, atomic force microscopy, fourier transformed infrared spectroscopy, X-ray diffraction analysis, X-ray photoelectron spectroscopy, thermogravimetric analysis, and others. Thus, this work rigorously discussed potential applications of the MOF@TiO2 nanomaterials for the CO2 capture and effective utilization in methanol, ethanol, acetone, acetaldehyde, and other useful products that served as fuel to various industrial processes. Additionally, the work highlights the effective performance of the materials towards photocatalytic degradation of both organic and inorganic pollutants with indepth mechanistic insights. The article will offer significant contribution for the development of sustainable and efficient technologies for the environmental monitoring and pollution mitigation.