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Chem Commun (Camb) ; 53(60): 8478-8481, 2017 Jul 25.
Artigo em Inglês | MEDLINE | ID: mdl-28703241

RESUMO

Using a one pot microwave procedure, mixed-metal "egg yolk" MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. In contrast, the solvothermal method produces homogeneous mixed-metal MOFs. The influence of Cr and V on the flexibility and breathing was studied via T-XRPD and CO2 adsorption measurements.

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