Publisher Correction: Room-temperature superconductivity in a carbonaceous sulfur hydride.

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Room-temperature superconductivity in a carbonaceous sulfur hydride.

One of the long-standing challenges in experimental physics is the observation of room-temperature superconductivity1,2. Recently, high-temperature conventional superconductivity in hydrogen-rich materials has been reported in several systems under high pressure3-5. An  important discovery leading to room-temperature superconductivity is the pressure-driven disproportionation of hydrogen sulfide (H2S) to H3S, with a confirmed transition temperature of 203 kelvin at 155 gigapascals3,6. Both H2S and CH4 readily mix with hydrogen to form guest-host structures at lower pressures7, and are of  comparable size at 4 gigapascals. By introducing methane at low pressures into the H2S + H2 precursor mixture for H3S, molecular exchange is allowed within a large assemblage of van der Waals solids that are hydrogen-rich with H2 inclusions; these guest-host structures become the building blocks of superconducting compounds at extreme conditions. Here we report superconductivity in a photochemically transformed carbonaceous sulfur hydride system, starting from elemental precursors, with a maximum superconducting transition temperature of 287.7 ± 1.2 kelvin (about 15 degrees Celsius) achieved at 267 ± 10 gigapascals. The superconducting state is observed over a broad pressure range in the diamond anvil cell, from 140 to 275 gigapascals, with a sharp upturn in transition temperature above 220 gigapascals. Superconductivity is established by the observation of zero resistance, a magnetic susceptibility of up to 190 gigapascals, and reduction of the transition temperature under an external magnetic field of up to 9 tesla, with an upper critical magnetic field of about 62 tesla according to the Ginzburg-Landau model at zero temperature. The light, quantum nature of hydrogen limits the structural and stoichiometric determination of the system by X-ray scattering techniques, but Raman spectroscopy is used to probe the chemical and structural transformations before metallization. The introduction of chemical tuning within our ternary system could enable the preservation of the properties of room-temperature superconductivity at lower pressures.

Two- and three-dimensional extended solids and metallization of compressed XeF2.

The application of pressure, internal or external, transforms molecular solids into extended solids with more itinerant electrons to soften repulsive interatomic interactions in a tight space. Examples include insulator-to-metal transitions in O(2), Xe and I(2), as well as molecular-to-non-molecular transitions in CO(2) and N(2). Here, we present new discoveries of novel two- and three-dimensional extended non-molecular phases of solid XeF(2) and their metallization. At approximately 50 GPa, the transparent linear insulating XeF(2) transforms into a reddish two-dimensional graphite-like hexagonal layered structure of semiconducting XeF(4). Above 70 GPa, it further transforms into a black three-dimensional fluorite-like structure of the first observed metallic XeF(8) polyhedron. These simultaneously occurring molecular-to-non-molecular and insulator-to-metal transitions of XeF(2) arise from the pressure-induced delocalization of non-bonded lone-pair electrons to sp(3)d(2) hybridization in two-dimensional XeF(4) and to p(3)d(5) in three-dimensional XeF(8) through the chemical bonding of all eight valence electrons in Xe and, thereby, fulfilling the octet rule at high pressures.