1.
J Am Chem Soc
; 133(24): 9282-5, 2011 Jun 22.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21612204
RESUMO
The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).
