Pyroreflectometry as a technique for the accurate measurement of very high temperatures in molten materials.

Experimental research into severe nuclear accidents often requires the accurate measurement of high temperatures of molten materials. Measurements of very high temperatures (1500-2500 °C) in liquid materials using standard pyrometry can entail uncertainties in the order of 5%-10%. Pyroreflectometry is a powerful technique with the potential to significantly reduce these uncertainties. A method is proposed to optimize pyroreflectometry temperature measurements in the 1500-2500 °C range and to allow more easily the detection of the solid-liquid phase transition. The originality of this research essentially relies on the use of pyroreflectometry based on two wavelengths (1.3 and 1.55 µm) and its application to liquid materials at high temperature, which implies to adapt technological elements and metrological procedures. The proposed procedure first requires temperature calibration, which is undertaken using three eutectic fixed-point cells, reducing temperature uncertainty. Second, precise settings are adopted to enable reflectivity measurements on specular surfaces, such as the surfaces of molten metals. Pyroreflectometry measurements on liquid surfaces have been validated on an iron sample. Subsequently, the application of pyroreflectometry at very high temperatures was validated on various materials: metal (iron and 18MND5 steel), oxide (alumina), and carbide (rhenium-carbon eutectic). For each of these samples, the uncertainties of temperature measurements in the 1500-2500 °C range were estimated in the range of 1%-2%, performing well against standard pyrometry measurements. The principal difficulties encountered during the pyroreflectometry characterization were the fine-tuning of parameters (optical head orientation and lens focusing) to enable measurements on highly specular surfaces and ensuring inert interactions between the samples and the crucible.

Low Rm magnetohydrodynamics as a means of measuring the surface shear viscosity of a liquid metal: A first attempt on Galinstan.

This paper introduces an experimental apparatus which generates the end-driven annular flow of a liquid metal pervaded by a uniform magnetic field. Unlike past viscometers involving an annular channel with particular values of the depth-to-width ratio, the present experiment enables us to drive the viscous shear at the surface of an annular liquid metal bath put in rotation. The magnetic interaction parameter N and the Boussinesq number related to the surface shear viscosity can be monitored from the magnitude of the applied magnetic field; the latter being set large enough for avoiding artefacts related to centrifugation and surface dilatation. This essential feature is obtained due to the ability of the magnetic field to set dimensionality of the annular flow in the channel between 2D-1/2 (swirling flow) and 2D axisymmetric (extinction of the overturning flow if N is large enough). By tracking the azimuthal velocity of tracers seeded along the oxidised surface of liquid Galinstan, an estimate for the surface shear viscosity of a liquid metal can be given.