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Guang Pu Xue Yu Guang Pu Fen Xi ; 25(8): 1199-202, 2005 Aug.
Artigo em Chinês | MEDLINE | ID: mdl-16329479

RESUMO

Cooperative luminescence phenomenon of Yb:YAG crystals was studied. Up-converted blue luminescence was obviously observed in Yb:YAG under excitation in the near-infrared region with a wavelength 940 nm. Experimental evidence was provided by the fact that the intensity of 498 nm luminescence shows a quadratic dependence on excitation power, and the intensity of blue luminescence increased with the increase in Yb ion concentration. It is concluded that this luminescence is due to a cooperative process resulting from a strong interaction of Yb ions. The cooperative luminescence is possiblely assigned to the strong interaction of 4f(13) electrons and neighboring Yb3+ ions in a covalent host lattice such as YAG. Theoretical cooperative luminescence spectrum was calculated.


Assuntos
Luminescência , Nanoestruturas/química , Itérbio/química , Óxido de Alumínio/química , Cristalização , Transferência de Energia , Érbio/química , Hólmio/química , Medições Luminescentes/instrumentação , Medições Luminescentes/métodos , Espectrofotometria Infravermelho , Espectroscopia de Luz Próxima ao Infravermelho , Ítrio/química
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