The mechanical properties and sustainability of phosphogypsum-slag binder activated by nano-ettringite.

The cementitious material based on phosphogypsum (PG) and ground granulated blast furnace slag (GBFS) demonstrates good economy and sustainability, whereas its drawback of ultra-slow strength development seems unacceptable. In this study, an attempt to drive the hydration of PG-GBFS and further facilitate the strength development by introducing nano-ettringite (NE) was carried out. The impact of 1- 5 % NE on the compressive strength, hydration process, dissolution behavior, and microstructure evolution of PG-GBFS were investigated. The results showed that the incorporation of NE significantly increased the compressive strength of PG-GBFS. At 7 d, the strength grew from 0 MPa to a range of 7.6- 20.2 MPa, and at 28 d, it was enhanced from 22.9 MPa to a range of 45.6- 79.0 MPa. The reason was that the introduction of NE induced the formation of AFt, thereby accelerating the hydration process and promoting the development of the skeletal network, resulting in higher early strength. Besides, NE facilitated the formation of C-S(A)-H gel, which further refined the pore structure and led to continuous growth in later strength. Additionally, PG-GFBS with 5 % NE exhibited significantly lower total costs (35.0 % of NaOH-activated slag and 51.7 % of water glass-activated slag) and lower carbon emissions (30.8 % of NaOH-activated slag and 49.8 % of water glass-activated slag) at the same 28 d compressive strength, indicating its strong competitiveness in both sustainability and economy.

Effect of Polyacrylic Acid on Rheology of Cement Paste Plasticized by Polycarboxylate Superplasticizer.

Viscosity-enhancing agents (VEA) have been widely employed in high flowability cement-based materials, so as to ensure that no bleeding and segregation would occur. However, in most cases, interaction between VEA and superplasticizer would be unavoidable. In this study, the effect of polyacrylic acid (PAA), known as one of the most commonly used VEAs, on rheology performance of cement paste containing polycarboxylate superplasticizer (PCE), was studied. The initial fluidity was assessed with mini slump, and rheological behavior of cement paste was evaluated with rotor rheometer. Adsorption amount was examined with total organic carbon (TOC) analyzer, and the zeta potential was also tested. The interaction between PAA and PCE in the presence of calcium ion (Ca2+) was analyzed with conductivity, X-ray photoelectron spectroscope (XPS), and dynamic light scattering (DLS). The results illustrate that PAA can adsorb onto the surface of cement particles to plasticize cement paste, being similar to PCE. In the presence of Ca2+, PAA can be curled and crosslinked, as a result of the combination between carboxyl groups (COO−) and Ca2+, thereby affecting the adsorption performance and conformation behavior. It is interesting that negative impact of PAA on dispersion efficiency of PCE can be demonstrated; one reason is the reduced adsorption amount of PCE by PAA competitively adsorbing onto the cement surface, and another possible reason is the invalided PCE by adsorption of PAA. Additionally, molecular weight of PAA should be considered if being used as VEA in PCE system.