1.
Chemistry
; 24(55): 14707-14711, 2018 Oct 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30020549
RESUMO
In the presence of different cations, reactions of [SbBr6 ]3- and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix }n- polyhalide units, can vary, resulting in unprecedented structural types. The nature of Iâ â â Br interactions was studied by DFT calculations; estimated energy values are 1.6-6.9â kcal mol-1 . Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.