Multiscale Modeling of Sintering-Driven Conductivity in Large Nanowire Ensembles.

Thermally driven sintering is widely used to enhance the conductivity of metal nanowire (NW) ensembles in printed electronics applications, with rapid nonisothermal sintering being increasingly employed to minimize substrate damage. The rational design of the sintering process and the NW morphology is hindered by a lack of mechanistically motivated and computationally efficient models that can predict sintering-driven neck growth between NWs and the resulting change in ensemble conductivity. We present a de novo modeling framework that, for the first time, links rotation-regulated nanoscale neck growth observed in atomistic simulations to continuum conductivity evolution in inch-scale NW ensembles via an analytical neck growth model and master curve formulations of neck growth and resistivity. This framework is experimentally validated against the emergent intense pulsed light-sintering process for Ag NWs. An ultralow computational effort of 0.2 CPU-h is achieved, 4-10 orders of magnitude reduction as compared to the state of the art. We show that the inherent local variation in the relative NW orientation within an ensemble drives significant junction-specific differences in neck growth kinetics and junction resistivity. This goes beyond the conventional assumption that the neck growth kinetics is the same at all the NW junctions in an ensemble, with significant implications on how nanoscale neck growth affects ensemble-scale conductivity. Through its low computational time, easy and rapid recalibration, and experimental relevance, our framework constitutes a much-needed foundational enabler for a priori design of the sintering process and the NWs.

Review of functional materials for potential use as wearable infection sensors in limb prostheses.

The fundamental goal of prosthesis is to achieve optimal levels of performance and enhance the quality of life of amputees. Socket type prostheses have been widely employed despite their known drawbacks. More recently, the advent of osseointegrated prostheses have demonstrated potential to be a better alternative to socket prosthesis eliminating most of the drawbacks of the latter. However, both socket and osseointegrated limb prostheses are prone to superficial infections during use. Infection prone skin lesions from frictional rubbing of the socket against the soft tissue are a known problem of socket type prosthesis. Osseointegration, on the other hand, results in an open wound at the implant-stump interface. The integration of infection sensors in prostheses to detect and prevent infections is proposed to enhance quality of life of amputees. Pathogenic volatiles having been identified to be a potent stimulus, this paper reviews the current techniques in the field of infection sensing, specifically focusing on identifying portable and flexible sensors with potential to be integrated into prosthesis designs. Various sensor architectures including but not limited to sensors fabricated from conducting polymers, carbon polymer composites, metal oxide semiconductors, metal organic frameworks, hydrogels and synthetic oligomers are reviewed. The challenges and their potential integration pathways that can enhance the possibilities of integrating these sensors into prosthesis designs are analysed.

Experimental Investigation into the Dynamics of a Radially Contracting Actuator with Embedded Sensing Capability.

Dynamics, control, and sensing are still challenges for pneumatically actuated soft actuators. We consider feasible solutions based on a radially contracting actuator to overcome these challenges. The radially contracting actuator was inspired by the movement of the stomach wall. It was capable of achieving radial contraction by inflating its circular air chamber. A quasi-static model that relates the pressure with the deformed wall of the air chamber was proposed and validated. In this article, we conduct a thorough experimental investigation into the contracting dynamics of the actuator with embedded sensing capability. We analyze the kinematics of the actuator at its rest and pressurization states focusing on the midpoint of the deformed wall. The actuator dynamics is characterized under the square wave pressure input by two variables that are the pressure in the air chamber and the trajectories of the midpoint. To achieve the desired contraction, we construct a feed-forward control based on the quasi-static model. It proves that the actuator is capable of tracking a prescribed triangular wave displacement of the midpoint with small deviations. A custom-made soft sensor is integrated into the actuator, which brings in the embedded sensing capability without affecting the actuator compliance. The resistance changes of the sensor versus the controlled contraction are examined, which are used to indicate the amount of radial contraction. The experimental investigation provides a foundation for the closed-loop control and practical applications of the radially contracting actuator developed.

Rapid Pulsed Light Sintering of Silver Nanowires on Woven Polyester for personal thermal management with enhanced performance, durability and cost-effectiveness.

Fabric-based personal heating patches have small geometric profiles and can be attached to selected areas of garments for personal thermal management to enable significant energy savings in built environments. Scalable fabrication of such patches with high thermal performance at low applied voltage, high durability and low materials cost is critical to the widespread implementation of these energy savings. This work investigates a scalable Intense Pulsed Light (IPL) sintering process for fabricating silver nanowire on woven polyester heating patches. Just 300 microseconds of IPL sintering results in 30% lesser electrical resistance, 70% higher thermal performance, greater durability (under bending up to 2 mm radius of curvature, washing, humidity and high temperature), with only 50% the added nanowire mass compared to state-of-the-art. Computational modeling combining electromagnetic and thermal simulations is performed to uncover the nanoscale temperature gradients during IPL sintering, and the underlying reason for greater durability of the nanowire-fabric after sintering. This large-area, high speed, and ambient-condition IPL sintering process represents an attractive strategy for scalably fabricating personal heating fabric-patches with greater thermal performance, higher durability and reduced costs.

Profiling of headspace volatiles from Escherichia coli cultures using silicone-based sorptive media and thermal desorption GC-MS.

Headspace sorptive extraction technique using silicone based sorptive media coated stir bars is used for the first time here to extract, identify, and quantify heavy volatile organic compounds present in Escherichia coli culture headspace. Detection of infection presence is largely accomplished in laboratories through physical sampling and subsequent growth of cultures for biochemical testing. The use of volatile biomarkers released from pathogens as indicators for pathogenic presence can vastly reduce the time needed whilst improving the success rates for infection detection. To validate this, by using a contactless headspace sorptive extraction technique, the volatile compounds released from E. coli, grown in vitro, have been extracted and identified. Two different sorptive media for extracting these headspace volatiles were compared in this study and the identified volatiles were quantified. The large phase volume and wider retention of this sorptive technique compared to traditional sampling approach enabled preconcentration and collection of wider range of volatiles towards developing an extensive database of such heavy volatiles associated with E. coli. This supplements the existing data of potential bacterial markers and use of internal standards in these tests allows semi-quantitative estimation of these compounds towards the development and optimization of novel pathogen sensing devices.

Bio-inspired flow sensor from printed PEDOT:PSS micro-hairs.

This paper reports on the creation of a low-cost, disposable sensor for low flow velocities, constructed from extruded micro-sized 'hair' of conducting polymer PEDOT. These microstructures are inspired by hair strands found in many arthropods and chordates, which play a prime role in sensing air flows. The paper describes the fabrication techniques and the initial prototype testing results toward employing this sensing mechanism in applications requiring sensing of low flow rates such as a flow sensor in neonatal resuscitators. The fabricated 1000 µm long, 6 µm diameter micro-hairs mimic the bending movement of tactile hair strands to sense the velocity of air flow. The prototype sensor developed is a four-level direct digital-output sensor and is capable of detecting flow velocities of up to 0.97 m s(-1).