External Stefan and Internal Marangoni Thermo-Fluid Dynamics for Evaporating Capillary Bridges.

We probe the evaporation mechanisms of wettability-moderated, confined capillary bridges and bulges. For the first time, we explore the internal Marangoni hydrodynamics and external Stefan advection dynamics in the surrounding gaseous domain due to evaporative effects. A transient simulation approach based on the level set (LS) method and the Arbitrary Lagrangian-Eulerian (ALE) framework was adopted to computationally model the capillary bridge profiles and evaporation phenomenon with generic contact line dynamics (both CCR and CCA modes). The governing equations corresponding to the transport processes in both the liquid and gaseous domains are simulated in a fully coupled manner with appropriate boundary conditions to precisely trace the liquid-vapor interface and the three-phase contact point during evaporation. The effect of the bridge confinement phenomenon, i.e., the extent of confined ambient surrounding the liquid-vapor interface between the solid surfaces, is explored. Also, the role of wetting state and contact line dynamics during CCR and CCA modes of evaporation were probed, and good agreement with experimental observations was noted. Results show that the evaporation rate is primarily dictated by the confinement phenomenon, and wettability effects play a marginal role. A higher confinement curtails the evaporation rate due to an increased local vapor concentration around the liquid bridges. However, the wetting state substantially affects the internal Marangoni effect dynamics and the Stefan advection dynamics due to its explicit influence on the nonuniform evaporative flux along the liquid-vapor interface. Between superhydrophobic confinements, the contact lines are confined in the wedge-shaped region, thereby locally augmenting the vapor concentration. As a result, the large evaporative flux near the bulge region develops a higher temperature gradient, thereby inducing upscaled thermal Marangoni flow compared to hydrophilic confinements. These findings may have significant implications for the efficient designing and development of thermofluidic systems involving thermal transport, mixing, and deposition of dissolved particles in liquid bridges.

Jet or wet? Droplet post-impact regimes on concave contours.

Droplet collision and subsequent spreading or wetting interactions with the solid substrate exhibit rich and interesting physics and are also important for various utilities. The fluid dynamics becomes more interesting and insightful when the wettability and geometry of the surface are tuned and altered. This study investigates the post-impact regimes of droplet impact on hydrophilic and superhydrophobic concave profile grooves (having dimensions comparable to that of the droplet). The post-collision hydrodynamics for such substrate-droplet system is three-dimensional, as in addition to droplet dynamics in the azimuthal direction, liquid jets may also be generated in the axial direction of the groove. Thereby the system may either lead to wetting or jetting, depending on the impact conditions. The effect of the impact Weber number (We) on the jet velocity, non-dimensional spreading width (γ) and non-dimensional south-pole film thickness (h*) has been probed and quantified. The observations reveal that the role of the wettability of the substrate is more profound in the recoiling stage than in the spreading stage, because inertial forces dominate in the latter. It is also noted that the spreading width increases and south-pole height decreases with increasing the impact Weber number. The opposite trend is noted upon increasing the groove concavity by altering just one dimension of the groove. The jet velocity is found to be the highest immediately after the impact and eventually decreases in a nonlinear fashion. Further, it has been found that the jet velocity increases with increasing the impact Weber number and that this effect is more prominent for superhydrophobic surfaces. A semi-analytical framework has been proposed to predict the jet velocity evolution in terms of governing Weber (We) and capillary (Ca) numbers. The predictions of the proposed model are in good agreement with the experimental observations.

Marangoni Flows in a Bilayer Liquid Microfilm Interface on Wave-Contoured Hot Substrates.

This study explores the thermal Marangoni hydrodynamics in an immiscible, binary-liquid thin-film system, which is open to the gas phase at the top and rests on a heated substrate with wavy topology. The sinusoidal contour of the heated (constant-temperature) substrate results in temperature gradients along the liquid-liquid and liquid-gas interfaces, causing fluctuations in the interfacial tension, ultimately leading to Marangoni hydrodynamics in the liquid-liquid films. This type of flow is notable in liquid film coatings on patterned surfaces, which are widely used in MEMS/NEMS applications (Weinstein, S. J.; Palmer, H. J. Liquid Film Coating: Scientific Principles and Their Technological Implications; 1997, pp 19-62; Palacio, M.; Bhushan, B. Adv. Mater. 2008, 20, 1194-1198) and biological cell sorting operations (Witek, M. A.; Freed, I. M.; Soper, S. A. Anal. Chem. 2019, 92, 105-131). We solve the coupled Navier-Stokes and energy equations by the perturbation technique to obtain approximate analytical solutions and an understanding of the thermal and hydrodynamic transport in the system domain. Our study explores the parametric influence of the relative thermal conductivity of the liquid layers (k), film thickness ratio (r), and the system's Biot number (Bi) on these transport phenomena. While the strength of the thermal Marangoni effect that is generated reduces with an increase in the relative thermal conductivity (k), the impact of r depends on the k value. We observe that for k > 1 the intensity of Marangoni flow increases with r; however, the opposite holds for k < 1. Furthermore, larger values of Bi induce higher resistance to the vertical conduction from the wavy substrate compared to the convection resistance offered at the top surface, destructively interfering with the ability of the patterned substrate to generate interfacial temperature fluctuations and hence weakening the Marangoni flow.

Augmenting the Leidenfrost Temperature of Droplets via Nanobubble Dispersion.

Droplets may rebound/levitate when deposited over a hot substrate (beyond a critical temperature) due to the formation of a stable vapor microcushion between the droplet and the substrate. This is known as the Leidenfrost phenomenon. In this article, we experimentally allow droplets to impact the hot surface with a certain velocity, and the temperature at which droplets show the onset of rebound with minimal spraying is known as the dynamic Leidenfrost temperature (TDL). Here we propose and validate a novel paradigm of augmenting the TDL by employing droplets with stable nanobubbles dispersed in the fluid. In this first-of-its-kind report, we show that the TDL can be delayed significantly by the aid of nanobubble-dispersed droplets. We explore the influence of the impact Weber number (We), the Ohnesorge number (Oh), and the role of nanobubble concentration on the TDL. At a fixed impact velocity, the TDL was noted to increase with the increase in nanobubble concentration and decrease with an increase in impact velocity for a particular nanobubble concentration. Finally, we elucidated the overall boiling behaviors of nanobubble-dispersed fluid droplets with the substrate temperature in the range of 150-400 °C against varied impact We through a detailed phase map. These findings may be useful for further exploration of the use of nanobubble-dispersed fluids in high heat flux and high-temperature-related problems and devices.

Hydrodynamics of electro-capillarity propelled non-Newtonian droplets through micro-confinements.

In this article, we theoretically explore the dynamics of droplet motion and its evolution during electro-capillarity propelled actuation within microfluidic systems. The study covers a wide gamut of fluids, wherein we investigate the dynamics of both pseudoplastic and dilatant fluid droplets. It is observed that change in the fluid rheology of the non-Newtonian fluids leads to significant morphing of the droplet dynamics during the actuation and propulsion event when compared to the Newtonian counterparts. We validate the theory using experimental reports on similar systems employing Newtonian droplets. The influence of governing parameters such as the actuation voltage and its transients, dielectric layer thickness on the electrodes and electrode spacing is probed. We also explore the influence of the interfacial properties of the system, such as channel wall friction, droplet wettability, and capillary friction, and establish that the fluid rheology, in conjunction with the interfacial features regulate the electro-actuation and propulsion of the droplets. We further provide theoretical estimates on the optimal design of the electro-actuation system in terms of a proposed electro-interfacial tension parameter. The findings may hold significance towards design and development of microfluidics with electro-actuation systems.

Magneto-Elastic Effect in Non-Newtonian Ferrofluid Droplets Impacting Superhydrophobic Surfaces.

In this article, we propose, with the aid of detailed experiments and scaling analysis, the existence of magneto-elastic effects in the impact hydrodynamics of non-Newtonian ferrofluid droplets on superhydrophobic surfaces in the presence of a magnetic field. The effects of magnetic Bond number (Bom), Weber number (We), polymer concentration, and magnetic nanoparticle (Fe3O4) concentration in the ferrofluids were investigated. In comparison to Newtonian ferrofluid droplets, addition of polymers caused rebound suppression of the droplets relatively at lower Bom for a fixed magnetic nanoparticle concentration and We. We further observed that for a fixed polymer concentration and We, increasing magnetic nanoparticle concentration also triggers earlier rebound suppression with increasing Bom. In the absence of the magnetic nanoparticles, the non-Newtonian droplets do not show rebound suppression for the range of Bom investigated. Likewise, the Newtonian ferrofluids show rebound suppression at large Bom. This intriguing interplay of elastic effects of polymer chains and the magnetic nanoparticles, dubbed as the magneto-elastic effect, is noted to lead to the rebound suppression. We establish a scaling relationship to show that the rebound suppression is observed as a manifestation of the onset of magneto-elastic instability only when the proposed magnetic Weissenberg number (Wim) exceeds unity. We also put forward a phase map to identify the various regimes of impact ferrohydrodynamics of such droplets and the occurrence of the magneto-elastic effect.

Competitive Electrohydrodynamic and Electrosolutal Advection Arrests Evaporation Kinetics of Droplets.

This article reports the hitherto unreported phenomenon of arrested evaporation dynamics in pendant droplets because of electric field stimulus. The evaporation kinetics of pendant droplets of electrically conducting saline solutions in the presence of a transverse, alternating electric field is investigated experimentally. While the increase of field strength reduces the evaporation rate, increment in field frequency has the opposite effect. The same has been explained on the solvation kinetics of ions in polar water. Theoretical analysis reveals that change in surface tension and the diffusion-driven evaporation model cannot predict the decelerated evaporation. With the aid of particle image velocimetry, suppression of internal circulation velocity within the droplet is observed under electric field stimulus, which directly affects the evaporation rate. A mathematical scaling model is proposed to quantify the effects of electrohydrodynamic circulation and electrothermal and electrosolutal advection on the evaporation kinetics. The analysis encompasses major governing parameters, namely, the thermal and solutal Marangoni numbers, the electrohydrodynamic number, the electro-Prandtl and electro-Schmidt numbers, and their respective contributions. It has been shown that the electrothermal Marangoni effect is suppressed by the electric field, leading to deteriorated evaporation rates. Additionally, the electrosolutal Marangoni effect further suppresses the internal advection, further reducing the evaporation rate by a larger proportion. Stability analysis reveals that the electric body force retards the stable internal advection. The stability mapping also illustrates that if the field strength is high enough for the electrosolutal advection to overshadow the solutal Marangoni effect completely, it can lead to improvement in evaporation rates.

Interplay of electro-thermo-solutal advection and internal electrohydrodynamics governed enhanced evaporation of droplets.

The article experimentally examines and theoretically establishes the influence of electric field on the evaporation kinetics of pendant droplets. It is observed that the evaporation of saline-pendant droplets can be augmented by the application of an external alternating electric field. The evaporation behaviour is modulated by an increase in the field strength and frequency. The classical diffusion driven evaporation model is found insufficient in predicting the improved evaporation rates. The change in surface tension due to field constraint is also unable to explain the observed physics. Consequently, the internal hydrodynamics of the droplet is investigated through particle image velocimetry. The electric field is found to induce enhanced internal advection, which improves the evaporation rates. A scaled analytical model is proposed to quantify the role of internal electrohydrodynamics, electro-thermal and electro-solutal effects. Stability maps reveal that the advection is caused nearly equally by the electro-solutal and electro-thermal effects within the droplet. The model is able to illustrate the influence played by the governing thermal and solutal Marangoni number, the electro-Prandtl and electro-Schmidt number, and the associated electrohydrodynamic number. The magnitude of the internal circulation can be predicted by the proposed model, which validates the proposed mechanism.

Enhanced cluster order-disorder transition-induced dilatancy in silane-functionalized nanosilica colloids.

Herein, we report a novel nanosilica-based shear-thickening fluid, whose shear-thickening performance has been largely augmented by surface functionalizing silica employing silane chains. The functionalized shear-thickening colloids were transparent; this suggested that they have promise for application. An enhancement in viscosity was observed by over an order of magnitude by the usage of functionalized particles, which could be explained on the basis of enhanced hydroclustering and an order-to-disorder transition of the particles due to physical bonding of the silane with the base polymer. It was also observed that the shear-thickening behavior was grossly modified due to the presence of the functionalized nanoparticles. Oscillatory analysis showed that the functionalized colloids exhibited an improved dynamic response, with enhanced elastic behavior under variant strain and frequency conditions. Additionally, impact resistance tests revealed that the thickening of the viscosity upon impact was augmented by over an order of magnitude; this established these functionalized colloids as excellent candidates for liquid armors. The viscoelastic behavior was modeled based on the Cox-Merz formalism. Additionally, three-element viscoelastic modeling was performed, and it was observed that while the silica-based colloids conformed to the predominantly viscous model, the functionalized system transited to a predominantly elastic model. The present article can have important implications for the design and engineering of shear-thickening fluids employing nanomaterials.

Superhydrophobic Surface Curvature Dependence of Internal Advection Dynamics within Sessile Droplets.

Sessile droplets seated on superhydrophobic surfaces are known to exhibit internal circulation patterns. The present article experimentally demonstrates and theoretically confirms, for the very first time, that the nature and velocity of the internal circulation in sessile droplets seated on superhydrophobic surfaces are strongly governed by the curvature of the surface and its directionality. Sessile droplets were rested on concave and convex superhydrophobic surfaces, and both with one curvature (cylindrical) and two curvatures (spherical) and varying droplet diameter to curve diameters were studied. Particle image velocimetry (PIV) was employed for flow visualization and quantification. It was observed that increasing convexity of the surface leads to deterioration in the velocity of advection within the droplet, whereas increasing concavity of the surface augments the velocity of circulation. A scaling model based on the effective curvature-modulated change in wettability has been put forward to predict the phenomenon, but it was found to be weak in deducing the circulation velocities. Consequently, potential flow theory is employed and the curvatures are approximated as equivalent wedges, with the rested droplet engulfing the wedge partly. Based on the curvature of the surface, the equivalent included wedge angle is deduced. Flow theory over wedged structures is employed to deduce the changes in the internal velocity in the presence of curved surfaces. The spatiotemporally averaged experimental velocities are found to conform to predictions from the proposed model, and good agreement between the theoretical predictions and experimental observations is achieved. The present findings may have strong implications in thermofluidic transport phenomena or multiphase transport processes at the interfacial and/or microscale.

Magnetohydrodynamics- and magnetosolutal-transport-mediated evaporation dynamics in paramagnetic pendant droplets under field stimulus.

Evaporation kinetics of pendant droplets is an area of immense importance in several applications, in addition to possessing rich fluid dynamics and thermal transport physics. This article experimentally and analytically sheds insight into the augmented evaporation dynamics of paramagnetic pendant droplets in the presence of a magnetic field stimulus. The literature provides information that solutal advection and the solutal Marangoni effect lead to enhanced evaporation in droplets with solvated ions. The main focus of this article is to modulate the thermosolutal advection with the aid of an external magnetic field and comprehend the dynamics of the evaporation process under such complex multiphysics interactions. Experimental observations reveal that the evaporation rate enhances as a direct function of the magnetic moment of the solvated magnetic element ions, thereby pointing at the magnetophoretic and magnetosolutal advection. Additionally, flow visualization by particle image velocimetry illustrates that the internal advection currents within the droplet increase in magnitude and are distorted in orientation by the magnetic field. A mathematical formalism based on magnetothermal and magnetosolutal advection has been proposed via scaling analysis of the species and energy conservation equations. The formalism takes into account all major governing factors, viz., the magnetothermal and magnetosolutal Marangoni numbers, magneto-Prandtl and magneto-Schmidt numbers, and the Hartmann number. The modeling establishes the magnetosolutal advection to be the dominant factor behind the augmented evaporation dynamics. Accurate validation of the experimental internal circulation velocity is obtained from the proposed model. This study reveals rich insight into the magnetothermosolutal hydrodynamics in paramagnetic droplets.

Electrohydrodynamic fibrillation governed enhanced thermal transport in dielectric colloids under a field stimulus.

Electrorheological (ER) fluids are known to exhibit enhanced viscous effects under an electric field stimulus. The present article reports the hitherto unreported phenomenon of greatly enhanced thermal conductivity in such electro-active colloidal dispersions in the presence of an externally applied electric field. Typical ER fluids are synthesized employing dielectric fluids and nanoparticles and experiments are performed employing an in-house designed setup. Greatly augmented thermal conductivity under a field's influence was observed. Enhanced thermal conduction along the fibril structures under the field effect is theorized as the crux of the mechanism. The formation of fibril structures has also been experimentally verified employing microscopy. Based on classical models for ER fluids, a mathematical formalism has been developed to predict the propensity of chain formation and statistically feasible chain dynamics at given Mason numbers. Further, a thermal resistance network model is employed to computationally predict the enhanced thermal conduction across the fibrillary colloid microstructure. Good agreement between the mathematical model and the experimental observations is achieved. The domineering role of thermal conductivity over relative permittivity has been shown by proposing a modified Hashin-Shtrikman (HS) formalism. The findings have implications towards better physical understanding and design of ER fluids from both 'smart' viscoelastic as well as thermally active materials points of view.

Governing Influence of Thermodynamic and Chemical Equilibria on the Interfacial Properties in Complex Fluids.

We propose a comprehensive analysis and a quasi-analytical mathematical formalism to predict the surface tension and contact angles of complex surfactant-infused nanocolloids. The model rests on the foundations of the interaction potentials for the interfacial adsorption-desorption dynamics in complex multicomponent colloids. Surfactant-infused nanoparticle-laden interface problems are difficult to deal with because of the many-body interactions and interfaces involved at the meso-nanoscales. The model is based on the governing role of thermodynamic and chemical equilibrium parameters in modulating the interfacial energies. The influence of parameters such as the presence of surfactants, nanoparticles, and surfactant-capped nanoparticles on interfacial dynamics is revealed by the analysis. Solely based on the knowledge of interfacial properties of independent surfactant solutions and nanocolloids, the same can be deduced for complex surfactant-based nanocolloids through the proposed approach. The model accurately predicts the equilibrium surface tension and contact angle of complex nanocolloids available in the existing literature and present experimental findings.

Electro-elastoviscous response of polyaniline functionalized nano-porous zeolite based colloidal dispersions.

The present article discusses the typical influence of grafted conducting polymers in the mesoscale pores of dielectric particles on the static and dynamic electrorheology and electro-viscoelastic behavior of corresponding colloids. Nanocrystalline meso-nanoporous zeolite has been prepared by chemical synthesis and subsequently polyaniline (PANI) coating has been implemented. Electrorheological (ER) suspensions have been formed by dispersing the nanoparticles in silicone oil and their viscoelastic behaviors are examined to understand the nature of such complex colloidal systems under electric fields. PANI-Zeolite ER fluids demonstrate higher static electroviscous effects and yield stress potential than untreated Zeolite, typically studied in literature. Transient electro-viscous characterizations show a stable and negligible hysteresis behavior when both the fluids are exposed to constant as well as time varying electric field intensities. Further oscillatory shear experiments of frequency and strain sweeps exhibit predominant elastic behavior in case of Zeolite based ER suspensions as compared to PANI systems. Detailed investigations reveal Zeolite based ER suspensions display enhanced relative yielding as well as electro-viscoelastic stability than the PANI-Zeolite. The steady state viscous behaviors are scaled against the non-dimensional Mason number to model the system behavior for both fluids. Experimental data of flow behaviors of both the ER fluids are compared with semi-classical models and it is found that the CCJ model possesses a closer proximity than traditional Bingham model, thereby revealing the fluids to be generic pseudo-linear fluids. The present article reveals that while the PANI based fluids are typically hailed superior in literature, it is only restricted to steady shear utilities. In case of dynamic and oscillatory systems, the traditional Zeolite based fluids exhibit superior ER caliber.

Augmenting static and dynamic mechanical strength of carbon nanotube/epoxy soft nanocomposites via modulation of purification and functionalization routes.

A detailed experimental investigation was carried out to establish the relationship between CNT purification and functionalization routes and the average response of CNT/epoxy nanocomposites under static and dynamic loading. It was shown that the relative improvement in the mechanical properties of the epoxy matrix due to the addition of CNTs depends on the choice of purification and functionalization steps. A better dispersion of CNTs was recorded for the functionalized CNTs as compared to the oxidized and CVD grown CNTs. Moreover, tensile, 3-point bending and nanoDMA testing performed on nanocomposites processed with CVD-grown, oxidized and functionalized CNTs revealed that COOH functionalization after the oxidation of CNTs at 350 °C is the optimized processing route to harness the excellent properties of CNTs in CNT/epoxy nanocomposites.

Non-Fourier thermal transport induced structural hierarchy and damage to collagen ultrastructure subjected to laser irradiation.

Comprehending the mechanism of thermal transport through biological tissues is an important factor for optimal ablation of cancerous tissues and minimising collateral tissue damage. The present study reports detailed mapping of the rise in internal temperature within the tissue mimics due to NIR (1064 nm) laser irradiation, both for bare mimics and with gold nanostructures infused. Gold nanostructures such as mesoflowers and nanospheres have been synthesised and used as photothermal converters to enhance the temperature rise, resulting in achieving the desired degradation of malignant tissue in targeted region. Thermal history was observed experimentally and simulated considering non-Fourier dual phase lag (DPL) model incorporated Pennes bio-heat transfer equation using COMSOL Multiphysics software. The gross deviation in temperature i.e. rise from the classical Fourier model for bio-heat conduction suggests additional effects of temperature rise on the secondary structures and morphological and physico-chemical changes to the collagen ultrastructures building the tissue mass. The observed thermal denaturation in the collagen fibril morphologies have been explained based on the physico-chemical structure of collagen and its response to thermal radiation. The large shift in frequency of amides A and B is pronounced at a depth of maximum temperature rise compared with other positions in tissue phantom. Observations for change in band of amide I, amide II, and amide III are found to be responsible for damage to collagen ultra-structure. Variation in the concentration of gold nanostructures shows the potentiality of localised hyperthermia treatment subjected to NIR radiation through a proposed free radical mechanism.

Effect of Interaction of Nanoparticles and Surfactants on the Spreading Dynamics of Sessile Droplets.

While a body of literature on the spreading dynamics of surfactants and a few studies on the spreading dynamics of nanocolloids exist, to the best of the authors' knowledge, there are no reports on the effect of presence of surfactants on the spreading dynamics of nanocolloidal suspensions. For the first time the present study reports an extensive experimental and theoretical study on the effect of surfactant impregnated nanocolloidal complex fluids in modulating the spreading dynamics. A segregation analysis of the effect of surfactants alone, nanoparticle alone, and the combined effect of nanoparticle and surfactants in altering the spreading dynamics have been studied in detail. The spreading dynamics of nanocolloidal solutions alone and of the surfactant impregnated nanocolloidal solutions are found to be grossly different, and particle morphology is found to play a predominant role. For the first time the present study experimentally proves that the classical Tanner's law is disobeyed by the complex fluids in the case of particle alone and combined particle and surfactant case. We also discuss the role of imbibitions across the particle wedge in the precursor film in tuning spreading dynamics. We propose an analytical model to predict the nature of dependency of contact radius on time for the complex colloids. A detailed theoretical examination of the governing factors, the interacting forces at the three phase contact line, and the effects of interplay of surfactants and the nanoparticles at the precursor film in modulating the spreading dynamics has been presented for such complex colloids.

Wettability of Complex Fluids and Surfactant Capped Nanoparticle-Induced Quasi-Universal Wetting Behavior.

Even though there are quite large studies on wettability of aqueous surfactants and a few studies on effects of nanoparticles on wettability of colloids, to the best of authors' knowledge, there is no study reported on the combined effect of surfactant and nanoparticles in altering the wettability. The present study, for the first time, reports an extensive experimental and theoretical study on the combined effect of surfactants and nanoparticles on the wettability of complex fluids such as nanocolloids on different substrates, ranging from hydrophilic with a predominantly polar surface energy component (silicon wafer and glass) to near hydrophobic range with a predominantly dispersive component of surface energy (aluminum and copper substrates). Systematically planned experiments are carried out to segregate the contributing effects of surfactants, particles, and combined particle and surfactants in modulating the wettability. The mechanisms and the governing parameters behind the interactions of nanocolloids alone and of surfactant capped nanocolloids with different surfaces are found to be grossly different. The article, for the first time, also analyzes the interplay of the nature of surfaces, surfactant and particle concentrations on contact angle, and contact angle hysteresis (CAH) of particle and surfactant impregnated colloidal suspensions. In the case of nanoparticle suspensions, the contact angle is observed to decrease for the hydrophobic system and increase for the hydrophilic systems considered. On the contrary, the combined particle and surfactant colloidal system shows a quasi-unique wetting behavior of decreasing contact angle with particle concentration on all substrates. Also interestingly, the combined particle surfactant system at all particle concentrations shows a wetting angle much lower than that of the only-surfactant case at the same surfactant concentration. Such counterintuitive observations have been explained based on the near-surface interactivity of the particle, fluid, and surfactant molecules based on effective slip length considerations. The CAH analyses of colloidal suspensions at varying surfactant and particle concentrations reveal in-depth physical insight into contact line pinning, and a unique novel relationship is established between the contact angle and differential energy for distorting the instantaneous contact angle for a pinned sessile droplet. A detailed theoretical analysis of the governing parameters influencing the wettability has been presented invoking the principles of DLVO (Derjaguin-Landau-Verwey-Overbeek), surface energy and interaction parameters influencing at the molecular scale, and the theoretical framework is found to support the experimental observations.

Effects of interplay of nanoparticles, surfactants and base fluid on the surface tension of nanocolloids.

A systematically designed study has been conducted to understand and demarcate the degree of contribution by the constituting elements to the surface tension of nanocolloids. The effects of elements such as surfactants, particles and the combined effects of these on the surface tension of these complex fluids are studied employing the pendant drop shape analysis method by fitting the Young-Laplace equation. Only the particle has shown an increase in the surface tension with particle concentration in a polar medium like DI water, whereas only a marginal effect of particles on surface tension in weakly polar mediums like glycerol and ethylene glycol has been demonstrated. Such behaviour has been attributed to the enhanced desorption of particles to the interface and a theory has been presented to quantify this. The combined particle and surfactant effect on the surface tension of a complex nanofluid system showed a decreasing behaviour with respect to the particle and surfactant concentration with a considerably feeble effect of particle concentration. This combined colloidal system recorded a surface tension value below the surface tension of an aqueous surfactant system at the same concentration, which is a counterintuitive observation as only the particle results in an increase in the surface tension and only the surfactant results in a decrease in the surface tension. The possible physical mechanism behind such an anomaly happening at the complex fluid air interface has been explained. Detailed analyses based on thermodynamic, mechanical and chemical equilibrium of the constituents and their adsorption-desorption characteristics as extracted from the Gibbs adsorption analysis have been provided. The present paper conclusively explains several physical phenomena observed, yet hitherto unexplained, in the case of the surface tension of such complex fluids by segregating the individual contributions of each component of the colloidal system.

Interplay of chemical and thermal gradient on bacterial migration in a diffusive microfluidic device.

Living systems are constantly under different combinations of competing gradients of chemical, thermal, pH, and mechanical stresses allied. The present work is about competing chemical and thermal gradients imposed on E. coli in a diffusive stagnant microfluidic environment. The bacterial cells were exposed to opposing and aligned gradients of an attractant (1 mM sorbitol) or a repellant (1 mM NiSO4) and temperature. The effects of the repellant/attractant and temperature on migration behavior, migration rate, and initiation time for migration have been reported. It has been observed that under competing gradients of an attractant and temperature, the nutrient gradient (gradient generated by cells itself) initiates directed migration, which, in turn, is influenced by temperature through the metabolic rate. Exposure to competing gradients of an inhibitor and temperature leads to the imposed chemical gradient governing the directed cell migration. The cells under opposing gradients of the repellant and temperature have experienced the longest decision time (∼60 min). The conclusion is that in a competing chemical and thermal gradient environment in the range of experimental conditions used in the present work, the migration of E. coli is always initiated and governed by chemical gradients (either generated by the cells in situ or imposed upon externally), but the migration rate and percentage of migration of cells are influenced by temperature, shedding insights into the importance of such gradients in deciding collective dynamics of such cells in physiological conditions.