RESUMO
China is the largest coke producer and consumer. There is a pressing need to address the high emissions of air pollutants and carbon dioxide associated with traditional coking production. As the nation pursues a transition towards carbon neutrality, expanding supply chains for coking plants to produce hydrogen, methanol, and other green alternatives has garnered significant attention. However, the relative advantages of these strategies have remained uncertain. In this study, we integrate a life cycle assessment-economic analysis-scenario analysis model to evaluate various coke oven gas (COG) utilization routes (COGtM: COG-to-methanol, COGtLNG: COG-to-liquefied natural gas, COGtSA: COG-to-synthetic ammonia, and COGtH: COG-to-hydrogen). The results indicate that COGtSA emerges as the preferred option for balancing environmental and economic benefits. Meanwhile, COGtM demonstrates economic viability but is associated with higher environmental impacts. Despite being recognized as a significant strategic direction under carbon neutrality initiatives, COGtH faces economic feasibility and risk resilience limitations. COGtLNG encounters both financial and environmental challenges, necessitating strategic development from an energy security perspective. The projected coking capacity is anticipated to experience a slight increase in the mid-term yet a significant decline in the long term, influenced by steel production capacity. In potential future markets, COGtM is estimated to potentially capture a maximum market share of 16-34% in the methanol market. Furthermore, against the backdrop of continuously expanding potential demand for hydrogen, COGtH holds advantages as a transitional solution, but in the long run, it can only meet a small portion of the market. COGtSA can meet 7-14% of market demand and emerges as the most viable pathway from the viewpoint of balancing environmental and economic aspects and covering future markets.
RESUMO
The search for building hierarchical porous materials with accelerated photo-induced electrons and charge-carrier separation is important because they hold great promise for applications in various fields. Here, a facile strategy of confining metal-organic framework (MOF) in the 1D channel of the 2D covalent organic framework (COF) to construct a novel COF@MOF micro/nanopore network is proposed. Specifically, a nitrogen-riched COF (TTA-BPDA-COF) is chosen as the platform for in-situ growth of a Co-based MOF (ZIF-L-Co) to form a TTA-BPDA-COF@ZIF-L-Co hybrid material. The hierarchical porous structure endows TTA-BPDA-COF@ZIF-L-Co with superior adsorption capacity. In addition, the integration of TTA-BPDA-COF and ZIF-L-Co forms a Z-scheme photocatalytic system, which significantly improved the redox properties and accelerated the separation of photogenerated charges and holes, achieving great improvement in photocatalytic activity. This confinement engineering strategy provides a new idea to construct a versatile molecular-material photocatalytic platform.
