RESUMO
Physical keyboards are common peripherals for personal computers and are efficient standard text entry devices. Recent research has investigated how physical keyboards can be used in immersive head-mounted display-based Virtual Reality (VR). So far, the physical layout of keyboards has typically been transplanted into VR for replicating typing experiences in a standard desktop environment. In this paper, we explore how to fully leverage the immersiveness of VR to change the input and output characteristics of physical keyboard interaction within a VR environment. This allows individual physical keys to be reconfigured to the same or different actions and visual output to be distributed in various ways across the VR representation of the keyboard. We explore a set of input and output mappings for reconfiguring the virtual presentation of physical keyboards and probe the resulting design space by specifically designing, implementing and evaluating nine VR-relevant applications: emojis, languages and special characters, application shortcuts, virtual text processing macros, a window manager, a photo browser, a whack-a-mole game, secure password entry and a virtual touch bar. We investigate the feasibility of the applications in a user study with 20 participants and find that, among other things, they are usable in VR. We discuss the limitations and possibilities of remapping the input and output characteristics of physical keyboards in VR based on empirical findings and analysis and suggest future research directions in this area.
RESUMO
We report on quantum chemical calculations at the DFT (BP86/TZP) and ab initio (CCSD(T)/III+) levels of the title compounds. The geometries, vibrational spectra, heats of formation, and homolytic and heterolytic bond dissociation energies are given. The calculated bond length of Cu-CN is in reasonable agreement with experiment. The theoretical geometries for CuNC and the other group 11 cyanides and isocyanides which have not been measured as isolated species provide a good estimate for the exact values. The theoretical bond dissociation energies and heats of formation should be accurate with an error limit of +/-5 kcal/mol. The calculation of the vibrational spectra shows that the C-N stretching mode of the cyanides, which lies between 2170 and 2180 cm(-)(1), is IR inactive. The omega(1)(C-N) vibrations of the isocyanides are shifted by approximately 100 cm(-)(1) to lower wavenumbers. They are predicted to have a very large IR intensity. The nature of the metal-ligand interactions was investigated with the help of an energy partitioning analysis in two different ways using the charged fragments TM(+) + CN(-) (TM = transition metal) and the neutral fragments TM(*) + CN(*) as bonding partners. The calculations suggest that covalent interactions are the driving force for the formation of the TM-CN and TM-NC bonds, but the finally formed bonds are better described in terms of interactions between TM(+) and CN(-), which have between 73% and 80% electrostatic character. The contribution of the pi bonding is rather small. The lower energy of the metal cyanides than that of the isocyanides comes from the stronger electrostatic interaction between the more diffuse electron density at the carbon atom of the cyano ligand and the positively charged nucleus of the metal.