RESUMO
A new photorefractive (PR) material sensitized with a novel functional unit DiPBI is prepared based on the guest/host approach. This unique mixture exhibits strong absorption in the whole range of visible light. Moreover, the photorefractive performance as well as PR speed is improved by far compared to the widely used sensitizer PCBM.
Assuntos
Corantes/química , Dimerização , Fulerenos/química , Imidas/química , Fenômenos Ópticos , Perileno/análogos & derivados , Absorção , Eletricidade , Perileno/químicaRESUMO
A novel dipolar-modulated charge-doped trilayer n-n organic heterojunction with a bidirectional tunable energy band discontinuity is constructed. The rectifying mechanism of the trilayer is similar to the rectifying and inverse-rectifying characteristics from n-p and p-n junctions, respectively. Zero-bias optoelectronic behavior and persistent photoconductivity are discovered. These results show that what are viewed as technological hurdles in the development of an organic n-n heterojunction should, in fact, lead to a better approach in organic optoelectronics.
