Nanocomposite Marvels: Unveiling Breakthroughs in Photocatalytic Water Splitting for Enhanced Hydrogen Evolution.

An overview of the significant innovations in photocatalysts for H2 development, photocatalyst selection criteria, and photocatalytic modifications to improve the photocatalytic activity was examined in this Review, as well as mechanisms and thermodynamics. A variety of semiconductors have been examined in a structured fashion, such as TiO2-, g-C3N4-, graphene-, sulfide-, oxide-, nitride-, oxysulfide-, oxynitrides, and cocatalyst-based photocatalysts. The techniques for enhancing the compatibility of metals and nonmetals is discussed in order to boost photoactivity within visible light irradiation. In particular, further deliberation has been carried out on the development of heterojunctions, such as type I, type II, and type III, along with Z-systems, and S-scheme systems. It is important to thoroughly investigate these issues in the sense of visible light irradiations to enhance the efficacy of photocatalytic action. In fact, another advancement in this area may include hiring mediators including grapheme oxide and metals to establish indirect Z-scheme montages with a correct band adjustment. The potential consideration of reaction chemology, mass transfer, kinetics of reactions, restriction of light diffusion, and the process and selection of suitable light and photoreactor also will optimize sustainable hydrogen output efficiency and selectivity.

Enhancing lung cancer detection through hybrid features and machine learning hyperparameters optimization techniques.

Machine learning offers significant potential for lung cancer detection, enabling early diagnosis and potentially improving patient outcomes. Feature extraction remains a crucial challenge in this domain. Combining the most relevant features can further enhance detection accuracy. This study employed a hybrid feature extraction approach, which integrates both Gray-level co-occurrence matrix (GLCM) with Haralick and autoencoder features with an autoencoder. These features were subsequently fed into supervised machine learning methods. Support Vector Machine (SVM) Radial Base Function (RBF) and SVM Gaussian achieved perfect performance measures, while SVM polynomial produced an accuracy of 99.89% when utilizing GLCM with an autoencoder, Haralick, and autoencoder features. SVM Gaussian achieved an accuracy of 99.56%, while SVM RBF achieved an accuracy of 99.35% when utilizing GLCM with Haralick features. These results demonstrate the potential of the proposed approach for developing improved diagnostic and prognostic lung cancer treatment planning and decision-making systems.

Mathematical modeling of active contraction of the human cardiac myocyte: A review.

Background and objective: In this present research paper, a mathematical model has been developed to study myocyte contraction in the human cardiac muscle, using the Land model. Different parts of the human heart with a focus on the composition of the myocyte cells have been explored numerically to enabling us to determine the interaction of various parameters in the heart muscle. The main objective of the work is to direct the study of the Land model, which has been exploited to simulate the contraction of real human myocytes. Methods: Mathematical models has been developed based on the Hill model and Huxley model. Myocyte contraction for different scenarios, such as in isometric tension and isotonic tension have been studied. Results: It is found that increase in stretch, the peak active tension increases, in line with well-established length-dependent tension generation. Five parameters are selected: [Ca2+]T50, Tref, TRPN50, ß0, and ß1, which have been varied in between the range of -50%-100%, to examine the isometric effects of each parameter on the behavior of the tension developed in the intact myocyte cells, with the most sensitive parameter being [Ca2+]T50. Conclusion: In conclusion, it is found that the Land model provides a good platform for the analysis of the active contraction of the human cardiac myocyte.

Eco-Design of Polymer Matrix Composite Parts: A Review.

This research presents a series of analyses related to the eco-design of polymer matrix composite parts, addressing various aspects of it. The main objective was to clarify the definition of ecological design, the benefits of its implementation and its importance in all stages of obtaining a product (design, manufacturing, recycling). Global environmental issues are presented, emphasizing the importance of adopting sustainable approaches in product design and manufacturing. Special attention is paid to the analysis of waste recycling technologies for polymer matrix composite materials. The analysis carried out identifies specific ecological design principles applicable to these materials and presents recent trends in the field. Relevant case studies are highlighted, demonstrating the benefits of ecological design in order to obtain sustainable products. Additionally, the conducted research allowed for finding answers to the questions "what", "why", "when" and "how" it is necessary to apply the principles of eco-design in the case of composite materials with a polymer matrix. In general, the research promotes eco-design as an indispensable strategy for sustainable and responsible production, inspiring companies to adopt these principles for the benefit of the environment and their business performance.

A review of different twisted tape configurations used in heat exchanger and their impact on thermal performance of the system.

Heat transfer in water with the help of solar energy is an effective way to harness renewable energy and reduce reliance on non-renewable sources of energy. The utilization of turbulent promoters is an efficient solution to ameliorate the performance of heat exchangers (HE). The current work summarizes the experimental and numerical behaviour of HE reported in the literature, including the thermal examinations of HT and fluid flow characteristics with various turbulent promoters and tube arrangements. This article reviews multiple studies in which different twisted tape (TT) geometry enhances the HT rate in various HE tubes. The current work also compares the thermal performance (η) of TT configurations in HE tubes using correlations developed by different investigators. Maximum heat transfer and minimum friction factor concerning fluid utilized in the system may also produce the optimal form for twisted tapes.

A Numerical Investigation on Hydrothermal Performance of Micro Channel Heat Sink with Periodic Spatial Modification on Sidewalls.

Electronic gadgets have been designed to incorporating very small components such as microcontrollers, electronic chips, transistors, microprocessors, etc. These components are exceptionally heat sensitive and can be wrecked if heat is not released. As a result, the thermal control of such components is critical to their optimum performance and extended life. The use of a microchannel heat sink (MCHS) has shown promising solutions to remove the excess heat. In this paper, we have proposed a novel design of MCHS and investigated it numerically. Four different surface modifications on the sidewall of the passage, namely, extended triangular surface (ETS), extended circular surface (ECS), triangular groove surface (TGS), and the circular groove surface (CGS) in the passage of the microchannel have been exploited in the Reynolds number of 100-900. In the presence of geometrical modification, the cooling capacities have been enhanced. The results show that the Nusselt numbers of ETS-MCHS, ECS-MCHS, TGS-MCHS, and CGS-MCHS are increased by 4.30, 3.61, 1.62, and 1.41 times in comparison to the Nusselt number of MCHS with smooth passage, while the friction factor values are increased by 7.33, 6.03, 2.74, and 1.68 times, respectively. In addition, the thermohydraulic performance parameter (THPP) has been evaluated and discussed. The fact that MCHS have THPP values greater than unity demonstrates that the passage's geometries are a practical means of achieving effective thermal management.

Analysis of Microchannel Heat Sink of Silicon Material with Right Triangular Groove on Sidewall of Passage.

Microchannel heat sink (MCHS) is a promising solution for removing the excess heat from an electronic component such as a microprocessor, electronic chip, etc. In order to increase the heat removal rate, the design of MCHS plays a vital role, and can avoid damaging heat-sensitive components. Therefore, the passage of the MCHS has been designed with a periodic right triangular groove in the flow passage. The motivation for this form of groove shape is taken from heat transfer enhancement techniques used in solar air heaters. In this paper, a numerical study of this new design of microchannel passage is presented. The microchannel design has five variable groove angles, ranging from 15° to 75°. Computational fluid dynamics (CFD) is used to simulate this unique microchannel. Based on the Navier-Stokes and energy equations, a 3D model of the microchannel heat sink was built, discretized, and laminar numerical solutions for heat transfer, pressure drop, and thermohydraulic performance were derived. It was found that Nusselt number and thermo-hydraulic performance are superior in the microchannel with a 15° groove angle. In addition, thermohydraulic performance parameters (THPP) were evaluated and discussed. THPP values were found to be more than unity for a designed microchannel that had all angles except 75°, which confirm that the proposed design of the microchannel is a viable solution for thermal management.

Performance of Microchannel Heat Sink Made of Silicon Material with the Two-Sided Wedge.

New designs of the microchannel with a two-sided wedge shape at the base were studied numerically. Five different wedge angles ranging from 3° to 15° were incorporated into the microchannel design. Simulation of this novel microchannel was carried out using Computational Fluid Dynamics (CFD). Three-dimensional models of the microchannel heat sink were created, discretized, and based on Navier-Stokes and energy equations; laminar numerical solutions were obtained for heat transfer and pressure drop. Flow characteristics of water as coolant in a microchannel were studied. It was observed that numerical results are in good agreement with experimental results. It was found that the Nusselt number and friction factor are significantly varied with the increase in Reynolds number. The Nusselt number varies in the following ranges of 5.963-8.521, 5.986-8.550, 6.009-8.568, 6.040-8.609, and 6.078-8.644 at 3°, 6°, 9°, 12°, and 15°, respectively. The microchannel with a wedge angle of 15° was found to be better in terms of Nusselt number and thermo-hydraulic performance. The enhancement in the Nusselt number is found as 1.017-1.036 for a wedge angle of 15°; however, friction factors do not show the perceptible values at distinct values of wedge angle. Moreover, the thermo-hydraulic performance parameters (THPP) were evaluated and found to be maximum in the range of 1.027-1.045 for a wedge angle of 15°. However, minimum THPP was found in the range of 1.005-1.0185 for a wedge angle of 3°.

The Effect of Roughness in Absorbing Materials on Solar Air Heater Performance.

Artificial roughness on the absorber of the solar air heater (SAH) is considered to be the best passive technology for performance improvement. The roughened SAHs perform better in comparison to conventional SAHs under the same operational conditions, with some penalty of higher pumping power requirements. Thermo-hydraulic performance, based on effective efficiency, is much more appropriate to design roughened SAH, as it considers both the requirement of pumping power and useful heat gain. The shape, size, and arrangement of artificial roughness are the most important factors for the performance optimization of SAHs. The parameters of artificial roughness and operating parameters, such as the Reynolds number (Re), temperature rise parameter (ΔT/I) and insolation (I) show a combined effect on the performance of SAH. In this case study, various performance parameters of SAH have been evaluated to show the effect of distinct artificial roughness, investigated previously. Therefore, thermal efficiency, thermal efficiency improvement factor (TEIF) and the effective efficiency of various roughened absorbers of SAH have been predicted. As a result, thermal and effective efficiencies strongly depend on the roughness parameter, Re and ΔT/I. Staggered, broken arc hybrid-rib roughness shows a higher value of TEIF, thermal and effective efficiencies consistently among all other distinct roughness geometries for the ascending values of ΔT/I. This roughness shows the maximum value of effective efficiency equals 74.63% at a ΔT/I = 0.01 K·m2/W. The unique combination of parameters p/e = 10, e/Dh = 0.043 and α = 60° are observed for best performance at a ΔT/I higher than 0.00789 K·m2/W.

Ecodesign of the Aluminum Bronze Cutting Process.

The realization of products from materials with high properties generally involves very high energy consumption. Thus, in the research, it was considered to optimize the machining process by cutting of an aluminum bronze alloy, so as to obtain a reduction in energy consumption in correlation with the roughness of the machined surfaces. The research focused on the processing of a semi-finished product with a diameter of Ø = 20 mm made of aluminum bronze (C62300). In addition, in the research, the aim was to establish some correlations between the amount of power consumed and the quality of the surfaces processed by cutting. In this sense, the forces were measured in the 3 directions specific to the cutting process (Fc; Ff; Fp) for 3 tools construction variants and power consumed. The results showed that, if a certain constructive variant of the cutting tool is used in the processing, a reduction of the power consumed to cutting can be obtained by approximately 30% and a reduction of the roughness of the processed surface by approximately 90-100%. Furthermore, following the statistical processing of the results, it was shown that it would be advisable to use, especially in roughing processes, the cutting tool variant that offers the greatest reduction in roughness and cutting power.

Modeling of Melt Flow and Heat Transfer in Stationary Gas Tungsten Arc Welding with Vertical and Tilted Torches.

A 3D numerical simulation was conducted to study the transient development of temperature distribution in stationary gas tungsten arc welding with filler wire. Heat transfer to the filler wire and the workpiece was investigated with vertical (90°) and titled (70°) torches. Heat flux, current flux, and gas drag force were calculated from the steady-state simulation of the arc. The temperature in the filler wire was determined at three different time intervals: 0.12 s, 0.24 s, and 0.36 s. The filler wire was assumed not to deform during this short time, and was therefore simulated as solid. The temperature in the workpiece was calculated at the same intervals using heat flux, current flux, gas drag force, Marangoni convection, and buoyancy. It should be noted that heat transfer to the filler wire was faster with the titled torch compared to the vertical torch. Heat flux to the workpiece was asymmetrical with both the vertical and tilted torches when the filler wire was fully inserted into the arc. It was found that the overall trends of temperature contours for both the arc and the workpiece were in good agreement. It was also observed that more heat was transferred to the filler wire with the 70° torch compared with the 90° torch. The melted volume of the filler wire (volume above 1750 °K) was 12 mm3 with the 70° torch, compared to 9.2 mm3 with the 90° torch.

Improving the Performance of Steel Machining Processes through Cutting by Vibration Control.

Machining processes through cutting are accompanied by dynamic phenomena that influence the quality of the processed surfaces. Thus, this research aimed to design, make, and use a tool with optimal functional geometry, which allowed a reduction of the dynamic phenomena that occur in the cutting process. In order to carry out the research, the process of cutting by front turning with transversal advance was taken into account. Additionally, semi-finished products with a diameter of Ø = 150 mm made of C45 steel were chosen for processing (1.0503). The manufacturing processes were performed with the help of two tools: a cutting tool, the classic construction version, and another that was the improved construction version. In the first stage of the research, an analysis was made of the vibrations that appear in the cutting process when using the two types of tools. Vibration analysis considered the following: use of the Fast Fourier Transform (FFT) method, application of the Short-Time Fourier-Transformation (STFT) method, and observation of the acceleration of vibrations recorded during processing. After the vibration analysis, the roughness of the surfaces was measured and the parameter Ra was taken into account, but a series of diagrams were also drawn regarding the curved profiles, filtered profiles, and Abbott-Firestone curve. The research showed that use of the tool that is the improved constructive variant allows accentuated reduction of vibrations correlated with an improvement of the quality of the processed surfaces.

Redesign of the Geometry of Parts Produced from PBT Composite to Improve Their Operational Behavior.

Parts produced from PBT-GF30 (70% polybutylene terephthalate +30% fiberglass) are very often used in car construction, due to the properties of this material. The current trend is to make parts with a shape designed to be as complex as possible, to take over many functions in operation. During the research, a part that is a component of the structure of car safety systems, and that must be completely reliable in operation, was analyzed. This piece has a complex shape that involves the intersection of several walls. Thus, the research aimed at establishing the optimal radius of connection between the walls (R), the ratio between the thickness of the intersecting walls (K) and the angle of inclination of the walls (α). The composite central design method was used to design the experiments. Both new parts and parts subject to an artificial aging process were tested. All parts were subjected to shear stress, to determine the load (L) and displacement (D) at which they break. In order to observe other changes in the properties of the parts, in addition to the mechanical ones, an analysis of the color of the new and aged parts was performed, as well as a topography of the surface layer in the breaking area. The design of the parts involved changes to the parameters of the injection process. In these conditions, a PBT-GF30 viscosity analysis was performed for new and artificially aged parts.

Ultrasonic Welding of PBT-GF30 (70% Polybutylene Terephthalate + 30% Fiber Glass) and Expanded Polytetrafluoroethylene (e-PTFE).

The ultrasonic welding of polymeric materials is one of the methods often used in practice. However, each couple of material subjected to ultrasonic welding is characterized by different values of technological parameters. Therefore, the main objective of the research presented in this paper is to optimize the parameters for the ultrasonic welding of two materials, namely PBT-GF30 (70% polybutylene terephthalate + 30% fiber glass) and expanded polytetrafluoroethylene (e-PTFE). In this sense, the research was carried out considering a plate-type part made of PBT-GF30, which had a thickness of 2.1 mm, and a membrane-type part made of e-PTFE, with a thickness of 0.3 mm. The condition imposed on the welded joints made, namely to correspond from a technical point of view, was that the detachment pressure of the membrane should be at least 4 bar. To this end, a test device was designed. Additionally, the topography of the material layer from the plate-type part was analyzed, as well as the chemical composition and surface condition for the membrane-type part. The obtained results allowed the optimization of the following parameters: The welding force; welding time; amplitude; and holding time. All experimental results were processed using STATISTICS software, which established how each parameter influences the characteristics of welded joints.

Smart Cutting Tools Used in the Processing of Aluminum Alloys.

The processing of aluminum alloys in optimal conditions is a problem that has not yet been fully resolved. The research carried out so far has proposed various intelligent tools, but which cannot be used in the presence of cooling-lubricating fluids. The objective of the research carried out in the paper was to design intelligent tools that would allow a control of the vibrations of the tool tip and to determine a better roughness of the processed surfaces. The designed intelligent tools can be used successfully in the processing of aluminum alloys, not being sensitive to coolants-lubricants. In the research, the processing by longitudinal turning of a semi-finished product with a diameter Ø = 55 mm of aluminum alloy A2024-T3510 was considered. Two constructive variants of smart tools were designed, realized, and used, and the obtained results were compared with those registered for the tools in the classic constructive variant. The analysis of vibrations that occur during the cutting process was performed using the following methods: Fast Fourier Transform (FFT); Short-Time Fourier-Transformation (STFT); the analysis of signal of vibrations. A vibration analysis was also performed by modeling using the Finite Element Method (FEM). In the last part of the research, an analysis of the roughness of the processed surfaces, was carried out and a series of diagrams were drawn regarding curved profiles; filtered profiles; Abbott-Firestone curve. Research has shown that the use of smart tools in the proposed construction variants is a solution that can be used in very good conditions for processing aluminum alloys, in the presence of cooling-lubrication fluids.

Preparation and Characterization of Composites Materials with Rubber Matrix and with Polyvinyl Chloride Addition (PVC).

An important problem that arises at present refers to the increase in performances in the exploitation of the conveyor belts. Additionally, it is pursued to use some materials, which can be obtained by recycling rubber and PVC waste, in their structure. Thus, the research aimed at creating conveyor belts using materials obtained from the recycling of rubber and PVC waste. Under these conditions, conveyor belts were made that had in their structure two types of rubber and PVC, which was obtained by adding in certain proportions of reclaimed rubber and powder obtained from grinding rubber waste. In order to study the effect of adding PVC on properties, four types of conveyor belts were made, with the structure of rubber, PVC and textile reinforcement. These have been subjected to certain mechanical tests, also being analyzed from the point of view of the behavior of the accelerated aging. The results obtained showed that the addition of PVC lead to a decrease in tensile stress for the strips made, but also an increase in the tensile strain. Additionally, the elasticity tests performed before and after the accelerated aging showed that the presence of PVC in the structure of the conveyor belts determined a substantial reduction of the aging process of the rubber in the conveyor belts. Under these conditions, it has been established that the use of PVC in the structure of rubber matrix conveyor belts is beneficial if conveyor belts are to be produced that are less subject to mechanical stress, but that work in conditions that can cause accelerated aging of materials. An analysis with the finite element method (FEM) of the test samples was also performed.

Methods for Determining the Thermal Transfer in Phase-Changing Materials (PCMs).

A very important issue that needs to be solved as simply and correctly as possible is how to establish the thermal performance of phase-changing materials (PCM). The undertaken researches have analyzed the values of the thermal performances of the PCM taking into account the method of finite elements and the experimental research, respectively, based on a modern measurement system that was designed and implemented. Butyl stearate which has been encapsulated through complex coacervation in polymethyl methacrylate has been used as a PCM. Samples were made containing 10%, 20%, 30% and 40% PCM, respectively, within their structure. The research has established that at both the hot plate and the cold plate interface, the evolution of the temperature over time, established by both the finite element method (FEM) and experimental research, are quite close, and the best results have been obtained for the P30 sample. A very important thing observed during the finite element method (FEM) is that the simulated thermal flow variation extends between 2700-3110W/m2 being small enough not to influence the temperature measurement at the interface of hot or cold plates. Thus, the use of the FEM or the experimental research method can be applied with good results, provided that the correct initial conditions are used in the finite element method and that the experimental research is performed using the best possible apparatus.

Constructive Optimization of Vulcanization Installations in Order to Improve the Performance of Conveyor Belts.

Conveyor belts of special importance must have superior mechanical characteristics. The joining by vulcanization of the conveyor belts allows to obtain superior performances, but it has been found that at the vulcanizing joint of the conveyor belts, there is a "bell"-type defect. This type of defect can cause the quick removal of the conveyor belts from use; thus, within this paper, we realized the constructive optimization of vulcanization installations using the finite element method (FEM). Thus, the FEM analysis was performed for the installation used at the present time, which has four spacers for stiffening, moving to the next stage to a stiffening system with seven spacers and, in the last stage, it was proposed to use a stiffening plate. The joined conveyor belts were of type ST 2000, and by the constructive optimization of the vulcanizing press type DSLQ, the bell-type defect was greatly reduced. Also, an analysis of the effects that the constructive optimization of the vulcanization installation has on the resistance to extraction of the metallic insert from the rubber matrix of the costs determined by the proposed constructive modifications, has been performed.

Use of Ultrasound in Reconditioning by Welding of Tools Used in the Process of Regenerating Rubber.

Addressing the problem of reconditioning large parts is of particular importance, due to their value and to the fact that the technologies for their reconditioning are very complex. The tools used to refine regenerated rubber which measure 660 mm in diameter and 2130 mm in length suffer from a rather fast dimensional wear. Within this research, the authors looked for a welding reconditioning procedure that would allow a very good adhesion between the deposited material layer and the base material. In this regard, the MAG (Metal Active Gas) welding process was used, but the ultrasonic activation of the welding process was also considered. Thus, the wire used for welding was activated considering a variation of the frequency of ultrasounds in the range f = 18-22 kHz respectively of the oscillation amplitude A = 30-60 µm. Under these conditions it was found that the presence of ultrasonic waves during the welding cladding process results in uniform deposition of hard carbons at the grain boundary and in the elimination of any existing oxides on the deposition surface, but at the same time increases the adhesion between the base material and the additional material, all of which positively influence the wear and corrosion resistance of the tools used to refine the regenerated rubber.