Ultrasmall Cu3(PO4)2 Nanoparticles Reinforced Hydrogel Membrane for Super-antifouling Oil/Water Emulsion Separation.

Membrane fouling is a persistent and crippling challenge for oily wastewater treatment due to the high susceptibility of membranes to contamination. A feasible strategy is to design a robust and stable hydration layer on the membrane surface to prevent contaminates. A hydrogel illustrates a distinct category of materials with outstanding antifouling performance but is limited by its weak mechanical property. In this research, we report a reinforced hydrogel on a membrane by in situ growing ultrasmall hydrophilic Cu3(PO4)2 nanoparticles in a copper alginate (CuAlg) layer via metal-ion-coordination-mediated mineralization. The embeddedness of hydrophilic Cu3(PO4)2 nanoparticle with a size of 3-5 nm endows the CuAlg/Cu3(PO4)2 composite hydrogel with enhanced mechanical property as well as reinforced hydrate ability. The as-prepared CuAlg/Cu3(PO4)2 modified membrane exhibits a superior oil-repulsive property and achieves a nearly zero flux decline for separating surfactant stabilized oil-in-water emulsions with a high permeate flux up to ∼1330 L m-2 h-1 bar-1. Notably, it is capable of keeping similar permeate flux for both pure water and oil-in-water emulsions during filtration, which is superior to the currently reported membranes, indicating its super-antifouling properties.

Developing experimental skills: A hands-on course in acoustical measurement techniques at the Norwegian University of Science and Technology.

The course "Acoustical Measurement Techniques TTT4250," offered by the Acoustics Group at the Department of Electronic Systems, Norwegian University of Science and Technology, is a fourth-year course in the specialization of acoustics in the five-year master program "Electronics Systems Design and Innovation" or MTELSYS, and the two-year international master program "Electronic Systems Design" or MSELSYS. It is one of the four required courses for MTELSYS and one of the two required courses for MSELSYS. It offers a hands-on approach to acoustics. This paper outlines the topics covered in this course and the involvement of several academic staff members, as well as invited industry and research institute guest speakers, as teachers. The assessment of laboratory reports is described, and general lecture topics, including measurement uncertainty and statistics, the introduction of standards, and programming, are also described. All aspects of the course aim to maximize students' experience with a broad range of acoustic measurements and their interest in acoustics.

Physics-based characterization of soft marine sediments using vector sensors.

In a 2007 experiment conducted in the northern North Sea, observations of a low-frequency seismo-acoustic wave field with a linear horizontal array of vector sensors located on the seafloor revealed a strong, narrow peak around 38 Hz in the power spectra and a presence of multi-mode horizontally and vertically polarized interface waves with phase speeds between 45 and 350 m/s. Dispersion curves of the interface waves exhibit piece-wise linear dependences between the logarithm of phase speed and logarithm of frequency with distinct slopes at large and small phase speeds, which suggests a seabed with a power-law shear speed dependence in two distinct sediment layers. The power spectrum peak is interpreted as a manifestation of a seismo-acoustic resonance. A simple geoacoustic model with a few free parameters is derived that quantitatively reproduces the key features of the observations. This article's approach to the inverse problem is guided by a theoretical analysis of interface wave dispersion and resonance reflection of compressional waves in soft marine sediments containing two or more layers of different composition. Combining data from various channels of the vector sensors is critical for separating waves of different polarizations and helps to identify various arrivals, check consistency of inversions, and evaluate sediment density.

Measurements of underwater noise radiated by commercial ships at a cabled ocean observatory.

Measurements of underwater noise radiated under ship normal operations are presented. The acoustic data, from the cabled ocean observatory, are analyzed under each identified ship passage, which was obtained by the Automatic Identification System. Under each passage, sound pressure level is calculated to observe local noise variations due to shipping noise. This paper emphasizes the study of noise variations at the observatory, presents the noise measurements under identified ship passages in the last several years, and provides references for predictive models of underwater noise pollution from commercial ship traffic. From the passages of one ship to the passages of 26 ships, the measurements reveal similar variation patterns when the ships traveled at similar courses, but different patterns when they traveled at different courses. When evaluating the noise variations due to ship traffics, it is important to consider the shipping noise propagation as well as ship movement.

Effects of Water Column Variations on Sound Propagation and Underwater Acoustic Communications.

Underwater sound propagation is very sensitive to geometric and environmental variations. The geometric variations are the motion of the source and/or receiver, while the environmental variations are due to surface motion and water column variations. In order to reduce the effects of these variations, it is necessary to understand their effects on sound propagation. In this paper, some water column variations are reported, and their effect on the underwater sound propagation is studied. These water column variations were observed during an experiment in the TrondheimFjord on 22 September 2016. Strong amplitude variations were observed in the channel impulse response during the experiment. The Doppler analysis was performed on the channel impulse response, which showed strong Doppler variations. The amplitude and Doppler variations suggested the presence of water column variations. To demonstrate the performance of the communication system, the time reversal combiner was implemented. The system performance was demonstrated by computing the mean squared error between the transmitted signal and the output of the combiner. The performance of the combiner degraded by ~2.5 dB in the presence of water column variations. Due to these variations, the amplitudes of the arrivals changed rapidly, which posed a great challenge for the time reversal combiner. These amplitude variations affected the focusing of the combiner and hence induced intersymbol interference and performance degradation. This work provides an insight into the effects of water column variations on underwater sound propagation and underwater acoustic communications.

Effects of sound exposure from a seismic airgun on heart rate, acceleration and depth use in free-swimming Atlantic cod and saithe.

Airguns used for offshore seismic exploration by the oil and gas industry contribute to globally increasing anthropogenic noise levels in the marine environment. There is concern that the omnidirectional, high intensity sound pulses created by airguns may alter fish physiology and behaviour. A controlled short-term field experiment was performed to investigate the effects of sound exposure from a seismic airgun on the physiology and behaviour of two socioeconomically and ecologically important marine fishes: the Atlantic cod (Gadus morhua) and saithe (Pollachius virens). Biologgers recording heart rate and body temperature and acoustic transmitters recording locomotory activity (i.e. acceleration) and depth were used to monitor free-swimming individuals during experimental sound exposures (18-60 dB above ambient). Fish were held in a large sea cage (50 m diameter; 25 m depth) and exposed to sound exposure trials over a 3-day period. Concurrently, the behaviour of untagged cod and saithe was monitored using video recording. The cod exhibited reduced heart rate (bradycardia) in response to the particle motion component of the sound from the airgun, indicative of an initial flight response. No behavioural startle response to the airgun was observed; both cod and saithe changed both swimming depth and horizontal position more frequently during sound production. The saithe became more dispersed in response to the elevated sound levels. The fish seemed to habituate both physiologically and behaviourally with repeated exposure. In conclusion, the sound exposures induced over the time frames used in this study appear unlikely to be associated with long-term alterations in physiology or behaviour. However, additional research is needed to fully understand the ecological consequences of airgun use in marine ecosystems.

Estimation of seabed shear-wave velocity profiles using shear-wave source data.

This paper estimates seabed shear-wave velocity profiles and their uncertainties using interface-wave dispersion curves extracted from data generated by a shear-wave source. The shear-wave source generated a seismic signature over a frequency range between 2 and 60 Hz and was polarized in both in-line and cross-line orientations. Low-frequency Scholte- and Love-waves were recorded. Dispersion curves of the Scholte- and Love-waves for the fundamental mode and higher-order modes are extracted by three time-frequency analysis methods. Both the vertically and horizontally polarized shear-wave velocity profiles in the sediment are estimated by the Scholte- and Love-wave dispersion curves, respectively. A Bayesian approach is utilized for the inversion. Differential evolution, a global search algorithm is applied to estimate the most-probable shear-velocity models. Marginal posterior probability profiles are computed by Metropolis-Hastings sampling. The estimated vertically and horizontally polarized shear-wave velocity profiles fit well with the core and in situ measurements.

Experimental assessment of different receiver structures for underwater acoustic communications over multipath channels.

Underwater communication channels are often complicated, and in particular multipath propagation may cause intersymbol interference (ISI). This paper addresses how to remove ISI, and evaluates the performance of three different receiver structures and their implementations. Using real data collected in a high-frequency (10-14 kHz) field experiment, the receiver structures are evaluated by off-line data processing. The three structures are multichannel decision feedback equalizer (DFE), passive time reversal receiver (passive-phase conjugation (PPC) with a single channel DFE), and the joint PPC with multichannel DFE. In sparse channels, dominant arrivals represent the channel information, and the matching pursuit (MP) algorithm which exploits the channel sparseness has been investigated for PPC processing. In the assessment, it is found that: (1) it is advantageous to obtain spatial gain using the adaptive multichannel combining scheme; and (2) the MP algorithm improves the performance of communications using PPC processing.

Estimation of seismic velocities of upper oceanic crust from ocean bottom reflection loss data.

This paper describes a Bayesian inversion of acoustic reflection loss versus angle measurements to estimate the compressional and shear wave velocities in young uppermost oceanic crust, Layer 2A. The data were obtained in an experiment on the thinly sedimented western flank of the Endeavor segment of the Juan de Fuca Ridge, using a towed horizontal hydrophone array and small explosive charges as sound sources. Measurements were made at three sites at increasing distance from the ridge spreading center to determine the effect of age of the crust on seismic velocities. The inversion used reflection loss data in a 1/3-octave band centered at 16 Hz. The compressional and shear wave velocities of the basalt were highly sensitive parameters in the inversion. The compressional wave velocity increased from 2547 + or - 30 to 2710 + or - 18 m/s over an age span of 1.4 million years (Ma) from the spreading center, an increase of 4.5 + or - 1.0%/Ma. The basalt shear wave velocity increased by nearly a factor of 2, from approximately 725 to 1320 m/s over the same age span. These results show a decreasing trend of Poisson's ratio with age, from a value of 0.46 at the youngest site closest to the ridge axis.