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1.
J Clin Med ; 12(9)2023 May 05.
Artigo em Inglês | MEDLINE | ID: mdl-37176736

RESUMO

BACKGROUND: Studies on the biomechanical mechanisms of an anterior cruciate ligament (ACL) injury have been extensively studied, but studies on the neuromuscular control-related risk factors for an ACL injury in specific maneuvers have not been reported for badminton players. STUDY DESIGN: Controlled laboratory study. METHODS: Sixteen badminton players (8 male, 8 female) performed a single-leg badminton ball landing task, and lower limb muscle activity, kinematic data, and ground reaction force were measured during this procedure using marker-based movement analysis, force plates, and electromyography (EMG). Gender differences in the lower limb kinematic data, mean values of normalized lower limb muscle activation (MVC%), and co-contraction values during the landing preparation phase (100 ms before initial contact) were analyzed using MANOVA. RESULTS: In the badminton landing task, the knee valgus angle was greater in females than in males (6.27 ± 2.75 vs. 1.72 ± 3.20) in the pre-landing preparation position. Compared to male badminton players, females exhibited greater gluteus maximus (44.92 ± 18.00 vs. 20.34 ± 11.64), rectus femoris (41.56 ± 9.84 vs. 26.14 ± 10.46), and medial gastrocnemius (37.39 ± 17.31 vs. 19.11 ± 11.17) lateral gastrocnemius (36.86 ± 17.82 vs. 13.59 ± 2.71) muscle activity (MVC%). CONCLUSION: Female badminton players exhibit neuromuscular control strategies that may be inadequate for ACL protection and may be a potential risk factor for a high incidence of ACL injury In the future, when devising injury prevention plans for female badminton players, optimizing neuromuscular control during the pre-landing phase can be targeted.

2.
Int J Mol Sci ; 23(23)2022 Nov 28.
Artigo em Inglês | MEDLINE | ID: mdl-36499190

RESUMO

The exploration of functional films using sustainable cellulose-based materials to replace plastics has been of much interest. In this work, two kinds of lignin nanoparticles (LNPs) were mixed with cellulose nanofibrils (CNFs) for the fabrication of composite films with biodegradable, flexible and ultraviolet blocking performances. LNPs isolated from p-toluenesulfonic acid hydrolysis was easily recondensed and deposited on the surface of composite film, resulting in a more uneven surface; however, the composite film consisting of CNFs and LNPs isolated from maleic acid hydrolysis exhibited a homogeneous surface. Compared to pure CNF film, the composite CNF/LNP films exhibited higher physical properties (tensile strength of 164 MPa and Young's modulus of 8.0 GPa), a higher maximal weight loss temperature of 310 °C, and a perfect UVB blocking performance of 95.2%. Meanwhile, the composite film had a lower environmental impact as it could be rapidly biodegraded in soil and manmade seawater. Overall, our results open new avenues for the utilization of lignin nanoparticles in biopolymer composites to produce functional and biodegradable film as a promising alternative to petrochemical plastics.


Assuntos
Nanofibras , Nanopartículas , Lignina/química , Nanofibras/química , Celulose/química , Nanopartículas/química , Resistência à Tração
3.
Nanotechnology ; 33(26)2022 Apr 07.
Artigo em Inglês | MEDLINE | ID: mdl-35313297

RESUMO

Aqueous Zn-iodine redox flow batteries have aroused great interest for the features of high capacity, excellent stability, low cost, and high safety, yet the dissatisfying energy efficiency still limits their future advancement. In this work, three-dimensional semiconductor BiVO4nanoparticles decorated hierarchical TiO2/SnO2arrays (BiVO4@TiO2/SnO2) were applied as photocathode in Zn-iodine redox flow batteries (ZIRFBs) for the realization of efficient photo-assisted charge/discharge process. The photogenerated carriers at the solid/liquid interfaces boosted the oxidation process of I-, and thus contributed to a significant elevation in energy efficiency of 14.9% (@0.5 mA cm-2). A volumetric discharge capacity was extended by 79.6% under light illumination, owing to a reduced polarization. The photocathode also exhibited an excellent durability, leading to a stable operation for over 80 h with a maintained high energy efficiency of ∼90% @0.2 mA cm-2. The research offers a feasible approach for the realization of high-energy-efficiency aqueous Zn-iodine batteries towards high-efficiency energy conversion and utilization.

4.
Bioresour Technol ; 337: 125379, 2021 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-34111629

RESUMO

Developing low-cost and sustainable fractionation technology is the key to achieve the maximal utilization of lignocellulosic biomass. This study reported benzenesulfonic acid (BA) as a green hydrotrope for efficient lignocellulose conversion into two fractions at atmospheric pressure: (1) a primarily cellulosic solid residue that can be utilized to produce high-value building blocks (lignocellulosic nanomaterials or sugars), and (2) the collected spent acid liquor that can be diluted with anti-solvent to easily obtain lignin nanoparticles. BA hydrotropic method exhibited greater reaction selectivity to solubilize lignin, where approximately 80% lignin were removed at only 80 °C in 20 min. The lower lignin content substrates resulted in relatively higher enzymatic hydrolysis efficiency of 80% and less entangled lignocellulosic nanofibrils (LCNF). Furthermore, the separated lignin particles size can be easily adjusted by the initial acid concentration. Overall, this work presented a promising and simple technology in achieving lignocellulose separation and utilization under mild conditions.


Assuntos
Benzenossulfonatos , Lignina , Biomassa , Hidrólise
5.
Chemosphere ; 272: 129932, 2021 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-35534978

RESUMO

The method of quenching was adopted to reduce the emission of PCDD/Fs from a pilot scrap preheated EAF. Because quenching can effectively inhibit the de novo synthesis of dioxins. Meanwhile the temperatures at the inlet and outlet of the quenching part of EAF off-gas were measured to investigate the quenching effect. The results show that the temperatures of the off-gas are quenched from about 1300 °C to about 250 °C in the whole tap-to-tap cycle of EAF, which attains the expected cooling effect. The dioxin Toxic Equivalent Quantity (TEQ) concentrations and congener distributions of off-gas and three kinds of sampling ash were analyzed. The results indicate that the TEQ concentration of PCDD/Fs is 0.13 ng-I-TEQ/Nm3 at the outlet of the chimney A (D4), which is far below the dioxin emission limit for EAFs (0.5 ng-I-TEQ/Nm3) in China. At the same time the fingerprint suggests that the quenching effectively restrains the de novo synthesis, and dioxins de novo synthesize in the following flue and bag filter to some extent.


Assuntos
Poluentes Atmosféricos , Benzofuranos , Dioxinas , Dibenzodioxinas Policloradas , Poluentes Atmosféricos/análise , Benzofuranos/análise , Dibenzofuranos , Dibenzofuranos Policlorados/análise , Dioxinas/análise , Monitoramento Ambiental , Incineração , Dibenzodioxinas Policloradas/análise
6.
Int J Biol Macromol ; 166: 1578-1585, 2021 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-33181218

RESUMO

Due to the current state of ozone layer depletion and potential risk of skin cancer, researches on sustainable cellulose-based films with ultraviolet (UV) blocking capabilities has attracted widespread attention. However, pure cellulose-based film required UV absorbent to be incorporated because of its poor UV blocking ability. In this work, natural lignocellulosic nanofibril (LCNF) film was fabricated by vacuum filtration and pressing process without any complex chemical modification or adding UV absorbers. The residual lignin retained in LCNF was found to act as natural macro-molecular UV absorber. LCNF film with lignin content of 4.89-15.68% exhibited excellent thermal stability, and their UVA and UVB blocking were in the range of 81.4-99.5% and 96.7-100%, respectively. Moreover, LCNF film exhibited stable UV shielding performance under high temperature, UV irradiation, acidic or alkaline conditions, providing LCNF film with a long-term use capacity. Overall, LCNF film is more environmentally friendly and harmless, which shows high potentials in anti-counterfeiting materials, UV protection, and windshields for vehicles.


Assuntos
Lignina/química , Nanofibras/química , Protetores Solares/química , Raios Ultravioleta , Absorção de Radiação
7.
Bioresour Technol ; 293: 122171, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31558340

RESUMO

In this work, lignocellulosic nanofibrils (LCNF) produced from mechanical fibrillation with mixed enzymatic pretreatment or post-treatment were compared and the chemical composition, water retention value (WRV), average-number height and crystallinity for the obtained LCNF were evaluated. Compared to pure mechanical fibrillation, both mixed enzymatic pretreatment and post-treatment could efficiently facilitate cellulose nanofibrillation. Moreover, mixed enzymatic pretreatment was more suitable for LCNF production, resulting in a relatively higher WRV of 909% and smaller average-number height of 15 nm. These discoveries provide new insights into a more efficient biological method for the production and application of cellulose nanomaterials.


Assuntos
Celulose , Nanoestruturas
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