RESUMO
The recent pandemic increased attention to the need for appropriated ventilation and good air quality as efficient measures to achieve safe and healthy indoor air. This work provides a novel methodology for continuously evaluating ventilation in public areas using modern rapid response sensors (RRS). This methodology innovatively assesses the ventilation of a space by combining a quantitative estimation of the real air exchange in the space-obtained from CO2 experimental RRS measurements and the characteristics of and activity in the space-and indoor and outdoor RRS measurements of other pollutants, with healthy recommendations from different organisations. The methodology allows space managers to easily evaluate, in a continuous form, the appropriateness of their ventilation strategy, thanks to modern RRS measurements and direct calculations (implemented here in a web app), even in situations of full activity. The methodology improves on the existing standards, which imply the release of tracer gases and expert intervention, and could also be used to set a control system that measures continuously and adapts the ventilation to changes in indoor occupancy and activity, guaranteeing safe and healthy air in an energy-efficient way. Sample public concurrence spaces with different conditions are used to illustrate the methodology.
RESUMO
The adsorption of the thermoresponsive positively charged copolymer poly(N-isopropylacrylamide)-block-poly(3-acrylamidopropyl)trimethylammonium chloride, PNIPAAM48-b-PAMPTMA6(+), onto negatively charged gold nanoparticles can provide stability to the nanoparticles and make the emerging structure tunable by temperature. In this work, we characterize the nanocomposite formed by gold nanoparticles and copolymer chains and study the influence of the copolymer on the expected aggregation process that undergoes those nanoparticles at high ionic strength. We also determine the lower critical solution temperature (LCST) of the copolymer (around 42 °C) and evaluate the influence of the temperature on the nanocomposite. For those purposes, we use dynamic light scattering, UV-vis spectroscopy and transmission electron microscopy. At the working PNIPAAM48-b-PAMPTMA6(+) concentration, we observe the existence of copolymer structures that trap the gold nanoparticles and avoid the formation of nanoparticles aggregates. Finally, we discuss how these structures can be useful in catalysis and nanoparticles recovery.
