Integration of a Bismuth-Based Tris-Mononuclear Complex with 2D Functional Materials for Highly Efficient and Durable Aqueous Electrocatalytic Hydrogen Evolution.

The eminence of transitioning from traditional fossil fuel-based energy resources to renewable and sustainable energy sources is most evidently crucial. The potential of hydrogen as an alternative energy source has specifically focuses the electrocatalytic water splitting (EWS) as a promising technique for generating hydrogen. Development of efficient electrocatalysts to facilitate the EWS process while rationalizing the limitations of noble metal catalysts like platinum has become one of the daunting tasks. Consequently, porous functional materials such as metal complexes (MCs) and graphene oxide (GO) can act as potential catalysts for EWS. Therefore, a composite of GO and a mononuclear bismuth metal complex is synthesized through in situ facile synthesis, which is further utilized as an efficient electrocatalyst for the hydrogen evolution reaction (HER). Several potential electrocatalytic MC@GO composite (BMGO-3,5,7) materials were prepared with compositional variation of GO (3, 5, and 7 wt %). The experimental results demonstrate that the BMGO5 composite exhibits excellent HER activity with a low overpotential value of 105 mV at 10 mA cm-2 and a low Tafel slope of 44 mV dec-1 in 1 M KOH solution. Furthermore, a comprehensive investigation on the potentiality of the BMC-GO composite for hydrogen evolution from river water splitting was performed in order to address the issue of freshwater depletion. Inclusion of a mononuclear MC for facile synthesis of functional GO-based efficient electrocatalyst material is very scanty in the literature. This unique approach could assist future research endeavors toward designing efficient electrocatalysts for sustainable renewable energy generation. This is one of the first of its kind, where mononuclear MCs were utilized to develop GO-based functional composite materials for efficient electrocatalysis toward sustainable renewable energy generation.

Tm3+; Yb3+:Zn2TiO4 near infrared to blue upconversion phosphors for anti-counterfeit applications.

Tm3+; Yb3+:Zn2TiO4 samples have been synthesized using a solid state reaction route. The phase, lattice parameters, crystallite size has been examined using X-ray Diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). An intense peak of Yb3+ codoped samples is observed near ∼957 nm due to the 2F7/2 → 2F5/2 transition in diffuse reflectance spectra (DRS), which confirms the presence of Yb3+ ion in the prepared compound. The optical band gap of Yb3+ codoped samples has been calculated using Kubelka-Munk function. The Raman spectra corresponds to incorporation of Tm3+/Yb3+ at the octahedral and tetrahedral site of the spinel host. The emission spectra recorded by using 370 nm excitation wavelength shows intense blue colour band corresponding to the 1G4 → 3H6 transition of Tm3+ ion. The upconversion (UC) emission spectra recorded by using 980 nm laser excitation source shows emission bands due to the 1G4 → 3H6, 1G4 → 3F4 and 3H4 → 3H6 transitions of Tm3+ ion in the host matrix lying in the blue, red and NIR regions respectively. There is effective enhancement of about ∼35 times in the blue UC emission intensity with incorporation of Yb3+ at 3% doping concentration in the prepared sample. The anti-counterfeit application of the optimized upconverting phosphor has been successfully demonstrated.

Zirconia based Ho3+-Yb3+ codoped upconverting nanophosphors for green light emitting devices applications.

Photoluminescence study of the Ho3+-Yb3+ codoped ZrO, AlZrO and YZrO nanophosphors, synthesized by chemical co-precipitation method, upon excitation at 450 and 980 nm radiations have been performed. An improvement of about ∼4.5 times in the downconversion emission intensity of green band corresponding to the 5F4, 5S2 â†’ 5I8 transition for codoped YZrO nanophosphors compared to ZrO codoped nanophosphors has been observed. On varying the pump power density upon 980 nm excitation the colour tunability in the codoped YZrO nanophosphors has been observed. UC emission intensity of the green band arising from the Ho3+ ion in the codoped YZrO nanophosphors is enhanced about ∼22 times compared to that of the codoped ZrO nanophosphors. The absorption and UC emission study for the codoped YZrO nanophosphors dispersed in different biologically compatible solvents viz. water, methanol, ethanol and dimethyl sulfoxide (DMSO) has been performed. The green UC emission intensity of about ∼1.3 and ∼1.7 times for the efficient codoped YZrO nanophosphors dispersed in methanol compared to that dispersed in water and DMSO respectively has been observed. The absorption spectra of an efficient upconverting YZrO nanophosphors dispersed in methanol exhibit no change with the passage of time.

An uncommon initial presentation of snake bite-subarachnoid hemorrhage: A case report with literature review.

Snake bites are very common in India, particularly in West Bengal. Snake bite can cause various hematological, neuromyopathical complications. It can be very fatal if not detected and treated early. Timely intervention can save the patient. We are reporting a case of hematotoxic Russell viper snake bite presented with subarachnoid hemorrhage. Patient was successfully treated with antivenom serum (AVS) along with other conservative management. Subarachnoid hemorrhage as an initial presentation in viper bite is very rare and we discuss the case with proper literature review.