Flocculation monitoring of wastewater by using impedance spectroscopy.

The aim of the present work is to monitor the flocculation process using the analysis of the electric and dielectric properties. Therefore the dielectric and electrical characteristics of wastewater with different cationic polymer concentrations were investigated via the impedance spectroscopy (IS) method. Impedance measurements were carried at different concentration of cationic polymer in the frequency range from 0.1 Hz to 100 kHz. The analysis of complex permittivity spectra was described by the superposition of a power law at a low frequency related to the diffusion process and Cole-Cole relaxation behavior at high frequency. Moreover, an equivalent circuit model was developed in order to analyze the experimental data and to further investigate both processes. The variation of the parameters extracted from the equivalent circuit with the increase of cationic polymer concentrations has shown a net transition at 10 mg/l. This behavior could reflect the flocculation of dispersed particles at 10 mg/l. The findings in this work could draw new attention toward the monitoring of the coagulation-flocculation process using impedance spectroscopy and could be extended to other kinds.

Dielectric and electric properties as a tool to investigate the coagulation mechanism during sludge treatment.

The analysis of the complex permittivity, electrical complex modulus and the hopping conductivity have been employed in order to investigate the impacts of calcium oxide during sludge treatment in textile such as coagulation process. In this context, impedance measurement was performed on five samples, including raw sludge and four compositions containing different amounts of calcium oxide: 2%, 3%, 4% and 5% (w/w). The dielectric spectra of each composition were described by the summation of a power law and a Cole-Cole relaxation model. The relaxation time and the magnitude of the dielectric relaxation obtained from the analysis of dielectric properties showed an increase up to 3% of these parameters with the addition of calcium oxide. Above this critical value, both parameters showed a very small change, suggesting that the aggregation became more stable. In addition, the evolution of the hopping conductivity reached a minimum value at this critical amount (3%). This evolution was well described by a double power law, which allowed us to estimate the optimal amount of the calcium oxide to achieve coagulation process. The analysis of the dielectric properties was found useful in monitoring aggregation processes that occur during the coagulation mechanism in textile sludge.

Rheological and electrical properties used to investigate the coagulation process during sludge treatment.

Analyses of rheological properties and electrical conductivity (σdc) at direct current have been employed in order to investigate the effects of calcium oxide on the coagulation process during sludge treatment in the textile industry. In this context, rheological and electrical measurements were performed on five samples - one that contained raw sludge and the other four that were prepared from the raw sludge and different amounts of calcium oxide: 2, 3, 4, 5% (w/w). Rheological behavior of these samples was analyzed using the Herschel-Bulkley modified model. The influence of calcium oxide content on the rheological parameters such as infinite viscosity, the yield stress, the consistency coefficient, and the consistency index, are presented and discussed. The impact of the calcium oxide content on pH and conductivity were also examined. Similar behaviors have been seen in the evolution of conductivity and infinite viscosity as a function of the calcium oxide content. These latter characteristics were modeled by an equation using two power laws. This equation was able to fit very well the evolution of electrical conductivity and also the viscosity versus the percentage of calcium oxide to predict the optimal amount of calcium oxide (3%) to achieve the coagulation step during sludge treatment.