Porous carbon materials derived from olive kernels: application in adsorption of organic pollutants.

Adsorption of organic pollutants (OPs), bisphenol A, and diuron, from aqueous solutions onto porous carbon materials (CMs) prepared from olive kernels, have been investigated. The effects of initial pH, initial OP concentration, temperature, and contact time on the adsorption capacity were studied. The adsorption of bisphenol A and diuron onto CMs was found to be optimal at pH 5.6 and 6.9, respectively. It was noticed that the adsorption of those organic pollutants from aqueous solution declined with increasing temperature and the process is exothermic. The rate of adsorption followed the second order kinetic equation. The equilibrium results showed that Langmuir model fits well with the data. The maximum adsorption capacities obtained using the best CM were 476 and 434 mg g-1 for BPA and diuron, respectively. The results showed that CMs made from olive kernels are an excellent and inexpensive biomass waste-derived sorbent. Graphical abstract.

Steam activation of waste biomass: highly microporous carbon, optimization of bisphenol A, and diuron adsorption by response surface methodology.

Highly microporous carbons were prepared from argan nut shell (ANS) using steam activation method. The carbons prepared (ANS@H2O-30, ANS@H2O-90, and ANS@H2O-120) were characterized using X-ray diffraction, scanning electron microscopy, Fourier-transform infrared, nitrogen adsorption, total X-ray fluorescence, and temperature-programmed desorption (TPD). The ANS@H2O-120 was found to have a high surface area of 2853 m2/g. The adsorption of bisphenol A and diuron on ANS@H2O-120 was investigated. The isotherm data were fitted using Langmuir and Freundlich models. Langmuir isotherm model presented the best fit to the experimental data suggesting micropore filling of ANS@H2O-120. The ANS@H2O-120 adsorbent demonstrated high monolayer adsorption capacity of 1408 and 1087 mg/g for bisphenol A and diuron, respectively. The efficiency of the adsorption was linked to the porous structure and to the availability of the surface adsorption sites on ANS@H2O-120. Response surface method was used to optimize the removal efficiency of bisphenol A and diuron on ANS@H2O-120 from aqueous solution. Graphical abstract ᅟ.