The Electrochemical and Structural Changes of Phosphorus-Doped TiO2 through In Situ Raman and In Situ X-Ray Diffraction Analysis.

Doping is a widely employed technique to enhance the functionality of lithium-ion battery materials, tailoring their performance for specific applications. In our study, we employed in situ Raman and in situ X-ray diffraction (XRD) spectroscopic techniques to examine the structural alterations and electrochemical behavior of phosphorus-doped titanium dioxide (TiO2) nanoparticles. This investigation revealed several notable changes: an increase in structural defects, enhanced ionic and electronic conductivity, and a reduction in crystallite size. These alterations facilitated higher lithiation rates and led to the first observed appearance of LiTiO2 in the Raman spectra due to anatase lithiation, resulting in a reversible double-phase transition during the charging and discharging processes. Furthermore, doping with 2, 5, and 10 wt % phosphorus resulted in an initial increase in specific capacity compared to undoped TiO2. However, higher doping levels were associated with diminished capacity retention, pinpointing an optimal doping level for phosphorus. These results underscore the critical role of in situ characterization techniques in understanding doping effects, thereby advancing the performance of anode materials, particularly TiO2, in lithium-ion batteries.

Hydrolysis of Hemicellulose and Derivatives-A Review of Recent Advances in the Production of Furfural.

Biobased production of furfural has been known for decades. Nevertheless, bioeconomy and circular economy concepts is much more recent and has motivated a regain of interest of dedicated research to improve production modes and expand potential uses. Accordingly, this review paper aims essentially at outlining recent breakthroughs obtained in the field of furfural production from sugars and polysaccharides feedstocks. The review discusses advances obtained in major production pathways recently explored splitting in the following categories: (i) non-catalytic routes like use of critical solvents or hot water pretreatment, (ii) use of various homogeneous catalysts like mineral or organic acids, metal salts or ionic liquids, (iii) feedstock dehydration making use of various solid acid catalysts; (iv) feedstock dehydration making use of supported catalysts, (v) other heterogeneous catalytic routes. The paper also briefly overviews current understanding of furfural chemical synthesis and its underpinning mechanism as well as safety issues pertaining to the substance. Eventually, some remaining research topics are put in perspective for further optimization of biobased furfural production.