Fabrication and Characterization of Eco-Friendly Thin Films as Potential Optical Absorbers for Efficient Multi-Functional Opto-(Electronic) and Solar Cell Applications.

The necessity for reliable and efficient multifunctional optical and optoelectronic devices is always calling for the exploration of new fertile materials for this purpose. This study leverages the exploitation of dyed environmentally friendly biopolymeric thin films as a potential optical absorber in the development of multifunctional opto-(electronic) and solar cell applications. Uniform, stable thin films of dyed chitosan were prepared using a spin-coating approach. The molecular interactivity between the chitosan matrix and all the additive organic dyes was evaluated using FTIR measurements. The color variations were assessed using chromaticity (CIE) measurements. The optical properties of films were inspected using the measured UV-vis-NIR transmission and reflection spectra. The values of the energy gap and Urbach energy as well as the electronic parameters and nonlinear optical parameters of films were estimated. The prepared films were exploited for laser shielding as an attenuated laser cut-off material. In addition, the performance of the prepared thin films as an absorbing organic layer with silicon in an organic/inorganic heterojunction architecture for photosensing and solar energy conversion applicability was studied. The current-voltage relation under dark and illumination declared the suitability of this architecture in terms of responsivity and specific detectivity values for efficient light sensing applications. The suitability of such films for solar cell fabrications is due to some dyed films achieving open-circuit voltage and short-circuit current values, where Saf-dyed films achieved the highest Voc (302 mV) while MV-dyed films achieved the highest Jsc (0.005 mA/cm2). Finally, based on all the obtained characterization results, the engineered natural cost-effective dyed films are considered potential active materials for a wide range of optical and optoelectronic applications.

Structural, spectroscopic and electrical investigations of novel organic thin films bearing push-pull azo - Phenol dye for UV photodetection applications.

In the current study, novel thin films of a phenol-based push-pull azo dye, 2-acetyl-4-(4-chloro-phenylazo) phenol (ACAP), with tunable optical and electronic properties were designed, synthesized and characterized for UV photodetection applications. The crystalline structure and morphological features of the thermally evaporated ACAP thin films are investigated. The fabricated thin films exhibit an amorphous-like structure with low-intensity crystalline regions of average crystallite size of about 29.51 nm and a smooth surface with nanostructured sheets formation. The optical transmittance, reflectance, and absorption of ACAP thin films are measured in the spectral range UV-vis-NIR. A significant high UV absorption extending from 190 nm to 385 nm is observed with semi-transparency nature in the visible region. Furthermore, a good agreement is obtained between the estimated value of the direct energy gap that is obtained experimentally (3.62 eV) and that calculated from the theoretical DFT approach (3.74 eV). The dispersion behavior is analyzed in terms of the single oscillator model and is employed to estimate the dispersion parameters. Finally, an organic/inorganic heterojunction device based on Au/ACAP/n-Si/Al for UV photodetection is successfully fabricated. The current-voltage relations of the manufactured photodetector showed significant stability and sensitivity to the incident UV illumination. The fabricated UV photodetector exhibits responsivity ~25.7 mA/W, specific detectivity ~2 × 109 Jones, efficiency ~16.74%, a fast and reproducible ON/OFF switching behavior with 480 ms and 218 ms rise and fall time, respectively.

Influence of post-deposition annealing on structural, morphological and optical properties of copper (II) acetylacetonate thin films.

In this study, the effect of thermal annealing under vacuum conditions on structural, morphological and optical properties of thermally evaporated copper (II) acetylacetonate, cu(acac)2, thin films were investigated. The copper (II) acetylacetonate thin films were deposited using thermal evaporation technique at vacuum pressure ~1 × 10-5 mbar. The deposited films were thermally annealed at 323, 373, 423, and 473 K for 2 h in vacuum. The thermogravimetric analysis of cu(acac)2 powder indicated a thermal stability of cu(acac)2 up to 423 K. The effects of thermal annealing on the structural properties of cu(acac)2 were evaluated employing X-ray diffraction method and the analysis showed a polycrystalline nature of the as-deposited and annealed films with a preferred orientation in [1¯01] direction. Fourier transformation infrared (FTIR) technique was used to negate the decomposition of copper (II) acetylacetonate during preparation or/and annealing up to 423 K. The surface morphology of the prepared films was characterized by means of field emission scanning electron microscopy (FESEM). A significant enhancement of the morphological properties of cu(acac)2 thin films was obtained till the annealing temperature reaches 423 K. The variation of optical constants that estimated from spectrophotometric measurements of the prepared thin films was investigated as a function of annealing temperature. The annealing process presented significantly impacted the nonlinear optical properties such as third-order optical susceptibility χ(3) and nonlinear refractive index n2 of cu(acac)2 thin films.

Plasma impact on structural, morphological and optical properties of copper acetylacetonate thin films.

The influence of plasma exposure on structural, morphological and optical properties of copper (II) acetylacetonate thin films deposited by thermal evaporation technique was investigated. Copper (II) acetylacetonate as-grown thin films were exposed to the atmospheric plasma for different times. The exposure of as-grown cu(acac)2 thin film to atmospheric plasma for 5min modified its structural, morphological and optical properties. The effect of plasma exposure on structure and roughness of cu(acac)2 thin films was evaluated by XRD and AFM techniques, respectively. The XRD results showed an increment in crystallinity due to exposure for 5min, but, when the exposure time reaches 10min, the film was transformed to an amorphous state. The AFM results revealed a strong modification of films roughness when the average roughness decreased from 63.35nm to ~1nm as a result of interaction with plasma. The optical properties of as-grown and plasma exposured cu(acac)2 thin films were studied using spectrophotometric method. The exposure of cu(acac)2 thin films to plasma produced the indirect energy gap decrease from 3.20eV to 2.67eV for 10min exposure time. The dispersion parameters were evaluated in terms of single oscillator model for as-grown and plasma exposured thin films. The influence of plasma exposure on third order optical susceptibility was studied.