Emerging mercury and methylmercury contamination from new artisanal and small-scale gold mining along the Nile Valley, Egypt.

The past decade witnessed the initiation and boom of the Artisanal and Small-scale Gold Mining (ASGM) activities in the hyper-arid southern Egypt. The ores are mined in the Eastern Desert and then transported to the densely populated farming communities in the Nile Valley, where the river provides the water resources needed for ore processing. In search for economic benefits, the poorly educated farmers with limited technical resources transformed their cultivated lands into ASGM operations, exposing themselves, their families, the residents, and the Nile ecosystems to several environmental and occupational health problems. Using integrated remote sensing, field, geochemical, and isotopic analyses, we report the first inventory of ASGM-related total mercury (THg) and methylmercury (MeHg) levels in tailings, amalgamation-tailing ponds, and surface and groundwater with emphasis on the Edfu city and its surroundings. The field and remote sensing-based mapping of ASGM activities reveals clustering around the Nile waterways and suggests interaction of Hg contamination sources with their surrounding receptors. Common ASGM practices include release of contaminated water from unlined amalgamation-tailing ponds into irrigation and drainage canals, and spreading of tailings over cultivated soils. In a short period (10 years), the released Hg contaminated multiple media, including the surface water, the shallow and deep aquifers, and possibly the soil, crops, and livestock. THg levels in amalgamation-tailing ponds (1200-8470 ng/L) are fourfold higher than US EPA and eightfold the WHO thresholds. The contaminated waters released from amalgamation-tailing ponds raised THg levels in surface water (irrigation canals: 50-100 ng/L; drainage canals: THg: > 200 ng/L) and groundwater (shallow and deep aquifers: 80-500 ng/L). Our findings highlight the need to extend the adopted approach to cover the entire length of the Nile River and its valley and the importance of conducting awareness campaigns to educate residents and health care providers about potential ASGM-related environmental and health hazards.

Integrated studies to identify site-specific parameters for environmentally benign mining operations: A case study from the Sukari Gold Mine, Egypt.

This study integrates observations from field and remote sensing data, along with geochemical and isotopic analyses, to assess the environmental impacts of cyanidation and mining activities in the Sukari gold mine (SGM), Eastern Desert, Egypt, in particular, and the orogenic gold deposits of the Arabian-Nubian Shield (ANS) in general. Our findings indicate: (1) groundwater flows south to north in the highly fractured basement aquifer related to the brittle deformation associated with the Najd Fault System; (2) massive gabbroic bodies separate the fractured basement aquifer into east and west conduits; (3) the tailings storage facility (TSF) pond and leach pad were constructed over the west conduit; and (4) cyanide-rich wastewater has leaked downward through tears and cuts in the lining of the TSF pond into the fractured aquifer and cyanide contaminants have migrated northward along the west conduit. Evidence for the latter includes: (1) toxic concentrations of cyanide (total: 0.018-9.4 mg/L; free weak-acid dissociable: 0.003-0.7 mg/L) were observed in groundwater samples north of the TSF pond; (2) similarities in electrical conductivity (EC) values and chloride/bromide (Cl-/Br-) ratios between groundwater north of the pond (EC: 88.8 mS/cm; Cl-/Br-: 346 to 363) and those of the TSF pond water (mean EC: 99 mS/cm; Cl-/Br-: 242 to 383) were observed; (3) the geochemical (e.g., sodium [Na+], Cl-) and isotopic compositions (δ18O and δ2H values) of groundwater are consistent with mixing of groundwater upgradient from the SGM with isotopically enriched pond water; and (4) cyanide contamination could not have resulted from an overflow of the TSF pond during flash flood events, given that rainfall is negligible and effective flood control systems are in place. Our findings show that the international codes/regulations do not fully address site-specific characteristics and highlight the importance of considering these parameters in mining of orogenic gold deposits in the ANS.