Imaging of THz Photonic Modes by Scattering Scanning Near-Field Optical Microscopy.

We investigated the near-field distribution associated to the photonic mode of terahertz photonic micro-resonators by scattering scanning near-field optical microscopy. Probing individual THz micro-resonators concentrating electric fields is important for high-sensitivity chemical and biochemical sensing and fundamental light-matter interactions studies at the nanoscale. We imaged both electric field concentration predicted by numerical simulations and unexpected patterns that deviate from intuitive assumptions. We propose a scenario based on the combination of the near-field with the far-field pattern of the probe/resonator ensemble that is in excellent agreement with the experimental data and propose an image analysis procedure to recover the near-field of such structures.

High-resolution THz gain measurements in optically pumped ammonia.

This study is aimed at the evaluation of THz gain properties in an optically pumped NH3 gas. NH3 molecules undergo rotational-vibrational excitation by mid-infrared (MIR) optical pumping provided by a MIR quantum cascade laser (QCL) which enables precise tuning to the NH3 infrared transition around 10.3 µm. Pure inversion transitions, (J = 3, K = 3) at 1.073 THz and (J = 4, K = 4) at 1.083 THz were selected. The THz measurements were performed using a THz frequency multiplier chain. The results show line profiles with and without optical pumping at different NH3 pressures, and with different MIR tuning. The highest gain at room temperature under the best conditions obtained during single pass on the (3,3) line was 10.1 dB×m-1 at 26 µbar with a pumping power of 40 mW. The (4,4) line showed lower gain of 6.4 dB×m-1 at 34 µbar with a pumping power of 62 mW. To our knowledge these THz gains are the highest measured in a continuous-wave MIR pumped gas.

Theoretical and experimental studies of CH3X-Y2 rotational line shapes for atmospheric spectra modelling: application to room-temperature CH3Cl-O2.

The case of symmetric tops CH(3)X (X = Br, Cl, F, …) perturbed by non-polar diatoms Y(2) (Y = N(2), O(2), …) is analysed from the viewpoint of theoretical collisional broadening of their rotational lines observed in atmospheric spectra. A semi-classical approach involving an exponential representation of the scattering operator and exact trajectories governed by the isotropic potential is presented. For the first time the active molecule is strictly treated as a symmetric top and the atom-atom interactions are included in the intermolecular potential model. It is shown for the CH(3)Cl-O(2) system that these interactions contribute significantly to the line width for all values of the rotational quantum numbers J and K. Additional testing of modifications required in the semi-classical formalism for a correct application of the cumulant expansion is performed and it is shown that the use of the cumulant average on the rotational states of the perturbing molecule leads to entirely negligible effects for the not very strongly interacting CH(3)Cl-O(2) system. In order to check the theoretical predictions and to extend the scarce experimental data available in the literature to higher values of the rotational quantum numbers, new measurements of room-temperature O(2)-broadened CH(3)Cl rotational lines are carried out by a photomixing continuous-wave terahertz spectrometer. The experimental line widths extracted with a Voigt profile model demonstrate an excellent agreement with theoretical results up to very high J-values (J = 31, 37, 40, 45, 50).