Determination of perfluorinated alkylated substances in sediments and sediment core from the Gulf of Gdansk, Baltic Sea.

Perfluorinated alkylated substances (PFAS) have been determined in surface sediments and sediment core from Gulf of Gdansk, Baltic Sea. Perfluorooctanesulphonate (PFOS), perfluorohexanesulphonate (PFHxS), perfluorodecanoate (PFDA), perfluoronanoate (PFNA), perfluorooctanoate (PFOA), perfluoroheptanoate (PFHpA), perfluoroundecanote (PFUnDA), perfluorododecanoate (PFDoDA) and perfluorohexanoate (PFHxA) were quantified after isotopic dilution ((13)C(4) PFOS and (13)C(4) PFOA), liquid-liquid extractions by methanol and acetonitrile, cleanup by Envi-Carb, OasisWAX and Envi-Carb and final measurement by HPLC-MS/MS. PFOS, PFHxS, PFUnDA, PFDA, PFNA and PFOA were found in Baltic Sea sediments in concentrations exceeding the method limit of quantification (LOQ) of 2 pg/g. PFOS was detected in concentration up to 0.896 ng/g dry weight and PFHxS up to 0.326 ng/g dw, which shows on a weak pollution. PFOS (48-74%) or PFHxS (45-56%) dominated in PFAS composition of sediments surveyed. Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of Environmental Science and Health, Part A to view the free supplemental file.

Survey of perfluorinated compounds (PFCs) in surface waters of Poland.

Perfluorochemicals (PFCs) are wide-spread contaminants on a global scale. There is an increasingly growing number of data on environmental occurrence, sources and risk of PFCs to humans and aquatic biota in highly industrialised countries but inadequate information exists for less industrialised regions. In the present study, concentrations and profiles of PFCs were examined in surface waters (rivers, lakes, streams, coastal region of the Baltic Sea) of Poland. PFOS was the dominant compound found in water at most of the sites surveyed and its concentration varied between < 0.5 and 150 ng/L and next was PFHxS with < 0.25 to 110 ng/L, while at much smaller concentration of < 0.5 to 18 ng/L occurred PFOA. The long-chain carboxylates (C11-C16) could be found only in water of a drainage ditch near to the Sarzyna site, i.e., PFUnDA occurred at 0.17 ng/L, PFTeDA of 0.06 ng/L, PFDoDA at 0.1 ng/L and PFHxDA at 0.12 ng/L. PFDA was found at several locations in the Gulf of Gdansk and its concentration varied between < 0.01 and 0.07 ng/L. The profile of PFCs in surface water at several sites of Poland with PFOS as a major compound, followed by PFOA is similar to that reported for other countries in Europe as well as for India, while this is different from that of Korea, Japan and the USA, where PFOA was the predominant contaminant.

Some mineral constituents of Parasol Mushroom (Macrolepiota procera).

This article reports background concentrations of Ag, Ba, Cd, Co, Cr, Cs, Cu, Ga, Hg, Mn, Mo, Pb, Rb, Sb, Sr, Se, Tl, V and Zn in caps and stalks of M. procera collected from four spatially distant sites across Poland. The elements were determined using inductively coupled plasma-mass spectrometry (ICP-MS), hydride generation atomic absorption spectrometry (HG-AAS) or a cold vapor atomic absorption spectrometry (CV-AAS). Copper, zinc, rubidium, selenium, chromium and cobalt were the most abundant amongst elements determined in this mushroom. Some elements (Cu, Zn, Rb, Se, Pb, Hg, Cd, Mo) occurred at greater concentrations in the caps than stalks of M. procera and some (Ag, Ba, Sr, V, Tl) dominated in the stalks, while for some other this proportion was similar or varied (Mn, Cr, Co, Ga, Sb, Cs) depending on the sampling site. For elements such as copper, zinc, rubidium as well as selenium some spatial similarity in distribution and/or concentration values both in caps and stalks was noted. Cadmium and lead content in caps of M. procera was usually below the European Union tolerance limit value of 2.0 and 3.0 microg/g dw set for cultivated mushrooms, respectively. These two toxic metals have been found in elevated concentration in M. procera from unpolluted stands outside of Poland as reported by some authors, which implies the possibility of relatively high background levels in this species.

Selected elements in Brown Birch Scaber Stalk Leccinum scabrum.

A survey of 26 metallic elements and metalloids such as Ag, Al, Ba, Ca, Cd, Co, Cr, Cs, Cu, Fe, Ga, Hg, K, Mg, Mn, Mo, Na, Ni, Pb, Rb, Sb, Se, Sr, Tl, V and Zn was carried out using ICP-MS, ICP-OES, HG-AAS and CV-AAS in the caps and stalks of edible mushroom Brown Birch Scaber Stalk collected from two lowland and one mountain sites in Poland. Ag, Al, Cd, Cr, Cs, Cu, Fe, Hg, K, Mg, Mo, Pb, Rb, Se, V and Zn occurred in greater concentration in the caps than stalks of Brown Birch Scaber Stalk, and opposite situation was for Tl and Na. Brown Birch Scaber Stalk collected from the site in Sudety Mountains did contain Al, Ba, Cs, Fe, Ga, Ni, Pb, Sr and V in significantly greater concentration when compared to specimens collected from the lowland sites, and what imply on significance of geological origin and/or soil substrate pollution impacting on mineral composition of this mushroom species. The results provide useful environmental and nutritional baseline level information on mineral composition of Brown Birch Scaber Stalk from unpolluted sites.