Experimental Investigation of Phase Equilibria of the Ho-Ir-O Ternary System at 1073 K.

An experimental study of the phase equilibria of the Ho-rich part of the Ho-Ir-O ternary system at 1073 K by means of x-ray diffraction, differential scanning calorimetry, and scanning electron microscopy has been carried out. Ho-hcp and four binary compounds, namely Ho3Ir, Ho5Ir2, Ho5Ir3, and Ho2O3, were identified in the Ho-Ir-O model alloys after long-term annealing (350-1220 h). No solubility of iridium in Ho2O3 oxide and Ho-hcp was observed. No ternary phase was found. Based on the experimental results, an isothermal section of the Ho-rich part of the Ho-Ir-O system at 1073 K was constructed. In addition, the microstructure of as-cast alloys was studied. An irregular eutectic consisting of faceted Ho-phase in Ho3Ir phase was observed in the alloys with Ho-hcp + Ho3Ir + Ho2O3 phase composition, and the temperature of the eutectic reaction Ho-hcp + Ho3Ir ↔ liquid was determined.

Analysis of the Reasons for the Tearing of Strips of High-Strength Electrical Steels in Tandem Cold Rolling.

High-strength non-oriented electro-technical steels with a low thickness possess excellent isotropy of electromagnetic and mechanical properties which is highly required in the production of high-efficiency electric motors. The manufacturing process of this type of steel includes very important and technologically complex routes such as hot rolling, cold rolling, temper rolling, or final heat treatment. The final thickness is responsible for the decrease in eddy-current losses and is effectively achieved during cold rolling by the tandem rolling mill. Industrial production of thin sheets of high-strength silicon steels in high-speed tandem rolling mills is a rather demanding technological operation due to the increased material brittleness that is mainly caused by the intensive solid solution and deformation strengthening processes, making the dislocation motion more complex. The main objective of this work was to investigate the distribution of local mechanical strains through the thickness of high silicon steel hot bands, generated during the cold rolling. The experimental samples were analysed by means of electron back-scattered diffraction and scanning electron microscopy. From the performed analyses, the correlation between the material workability and the nucleation of cracks causing the observed steel strip failure during the tandem cold rolling was characterized. Specifically, the microstructural, textural, misorientation, and fractographic analyses clearly show that the investigated hot band was characterized by a bimodal distribution of ferrite grains and the formation of intergranular cracks took place only between the grains with recrystallized and deformed structures.

The Effects of Various Conditions of Short-Term Rejuvenation Heat Treatment on Room-Temperature Mechanical Properties of Thermally Aged P92 Boiler Steel.

In this work, the effects of various conditions of short-term rejuvenation heat treatment on room-temperature mechanical properties of long-term aged P92 boiler steel were investigated. Normalized and tempered P92 steel pipe was thermally exposed at 600 °C for time durations up to 5000 h in order to simulate high-temperature material degradation, as also occurring in service conditions. Thus, thermally embrittled material states of P92 steel were prepared, showing tempered martensitic microstructures with coarsened secondary phase precipitates of Cr23C6-based carbides and Fe2W-based Laves phase. Compared with the initial normalized and tempered material condition, thermally aged materials exhibited a slight decrease in strength properties (i.e., yield stress and ultimate tensile strength) and deformation properties (i.e., total elongation and reduction of area). The hardness values were almost unaffected, whereas the impact toughness values showed a steep decrease after long-term ageing. An idea for designing the rejuvenation heat treatments for restoration of impact toughness was based on tuning the material properties by short-term annealing effects at various selected temperatures somewhat above the long-term ageing temperature of P92 material. Specifically, the proposed heat treatments were performed within the temperature range between 680 °C and 740 °C, employing variable heating up and cooling down conditions. It was revealed that short-term annealing at 740 °C for 1 h with subsequent rapid cooling into water represents the most efficient rejuvenation heat treatment procedure of thermally aged P92 steel for full restoration of impact toughness up to original values of normalized and tempered material state. Microstructural observations clearly indicated partial dissolution of the Laves phase precipitates to be the crucial phenomenon that played a key role in restoring the impact toughness.

The Effect of Electrolytic Hydrogenation on Mechanical Properties of T92 Steel Weldments under Different PWHT Conditions.

In the present work, the effects of electrolytic hydrogen charging of T92 steel weldments on their room-temperature tensile properties were investigated. Two circumferential weldments between the T92 grade tubes were produced by gas tungsten arc welding using the matching Thermanit MTS 616 filler material. The produced weldments were individually subjected to considerably differing post-welding heat treatment (PWHT) procedures. The first-produced weldment was conventionally tempered (i.e., short-term annealed below the Ac1 critical transformation temperature of the T92 steel), whereas the second one was subjected to its full renormalization (i.e., appropriate reaustenitization well above the T92 steel Ac3 critical transformation temperature and subsequent air cooling), followed by its conventional subcritical tempering. From both weldments, cylindrical tensile specimens of cross-weld configuration were machined. The room-temperature tensile tests were performed for the individual welds' PWHT states in both hydrogen-free and electrolytically hydrogen-charged conditions. The results indicated higher hydrogen embrittlement susceptibility for the renormalized-and-tempered weldments, compared to the conventionally tempered ones. The obtained findings were correlated with performed microstructural and fractographic observations.

The Influence of Laser Surface Remelting on the Tribological Behavior of the ECAP-Processed AZ61 Mg Alloy and AZ61-Al2O3 Metal Matrix Composite.

This paper deals with the tribological study of the laser remelted surfaces of the ECAP-processed AZ61 magnesium alloy and AZ61-Al2O3 metal matrix composite with 10 wt.% addition of Al2O3 nanoparticles. The study included the experimental optimization of the laser surface remelting conditions for the investigated materials by employing a 400 W continual wave fiber laser source. Tribological tests were performed in a conventional "ball-on-disc" configuration with a ceramic ZrO2 ball under a 5 N normal load and a sliding speed of 100 mm/s. The results showed that both the incorporation of Al2O3 nanoparticles and the applied laser treatments led to recognizable improvements in the tribological properties of the studied AZ61-Al2O3 composites in comparison with the reference AZ61 alloy. Thus, the best improvement has been obtained for the laser modified AZ61-10 wt.% Al2O3 nanocomposite showing about a 48% decrease in the specific wear rate compared to the laser untreated AZ61 base material.

Evolution of Power Losses in Bending Rolled Fully Finished NO Electrical Steel Treated under Unconventional Annealing Conditions.

Currently, the non-oriented (NO) iron-silicon steels are extensively used as the core materials in various electrical devises due to excellent combination of their mechanical and soft magnetic properties. The present study introduces a fairly innovative technological approach applicable for fully finished NO electrical steel before punching the laminations. It is based on specific mechanical processing by bending and rolling in combination with subsequent annealing under dynamic heating conditions. It has been revealed that the proposed unconventional treatment clearly led to effective improvement of the steel magnetic properties thanks to its beneficial effects involving additional grain growth with appropriate crystallographic orientation and residual stress relief. The philosophy of the proposed processing was based on employing the phenomena of selective grain growth by strain-induced grain boundary migration and a steep temperature gradient through the cross-section of heat treated specimens at dynamic heating conditions. The stored deformation energy necessary for the grain growth was provided by plastic deformation induced within the studied specimens during the bending and rolling process. The magnetic measurements clearly show that the specimens treated according to our approach exhibited more than 17% decrease in watt losses in comparison with the specimens treated by conventional heat treatment leading only to stress relief without additional grain growth.

Microstructure and Abrasive Wear Resistance of Various Alloy Hardfacings for Application on Heavy-Duty Chipper Tools in Forestry Shredding and Mulching Operations.

Five different alloy hardfacings on 16MnCr5 grade low-carbon ferritic-pearlitic steel were investigated in terms of their abrasive wear resistance in laboratory testing conditions. The selected hardfacing materials, namely "E520 RB", "RD 571", "LNM 420FM", "E DUR 600", and "Weartrode 62", were individually deposited onto plain ground-finish surfaces of 10 mm thick steel plate samples. The studied hardfacings were fabricated using several different welding methods and process parameters proposed by their industrial manufacturers. In the present comparative study, the results obtained from laboratory abrasive wear tests of the investigated hardfacings were analyzed and discussed in relation to their microstructure, hardness, and wear mechanism characteristics. Regardless of great variety in microstructure and chemical composition of individual hardfacing materials, the results clearly indicated the governing factor for the wear resistance improvement to be the overall carbon content of the used hardfacing material. Thus it has been shown that the "E520 RB" hardfacing exhibited the highest abrasive wear resistance thanks to its appropriate hardness and beneficial "ledeburite-type" eutectic microstructure.

Improving the Magnetic Properties of Non-Oriented Electrical Steels by Secondary Recrystallization Using Dynamic Heating Conditions.

In the present work, we have used unconventional short-term secondary recrystallization heat treatment employing extraordinary high heating rate to develop coarse-grained microstructure with enhanced intensity of rotating cube texture {100}<011> in semi-finish vacuum degassed non-oriented electrical steels. The soft magnetic properties were improved through the increase of grains size with favourable cube crystallographic orientation. The appropriate final textural state of the treated experimental steels was achieved by strain-induced grain boundary migration mechanism, activated by gradient of accumulated stored deformation energy between neighbouring grains after the application of soft cold work, combined with steep temperature gradient during subsequent heat treatment under dynamic heating conditions. The materials in our experimentally prepared material states were mounted on the stator and rotor segments of electrical motors and examined for their efficiency in real operational conditions. Moreover, conventionally long-term heat treated materials, prepared in industrial conditions, were also tested for reference. The results show that the electrical motor containing the segments treated by our innovative approach, exhibits more than 1.2% higher efficiency, compared to the motor containing conventionally heat treated materials. The obtained efficiency enhancement can be directly related to the improved microstructural and textural characteristics of our unconventionally heat treated materials, specifically the homogenous coarse grained microstructure and the high intensity of cube and Goss crystallographic texture.