Flame retardant cotton fabrics with ultra-fast and long-term fire early warning response.

Smart textiles with flame retardant and fire-warning functions have received more and more attention. However, improving the fire-warning response sensitivity and long-term responsiveness of the smart textiles is a top priority. In this research, flame retardant and fire-warning cotton fabrics were prepared by layer-by-layer assembly composite coating consisting of bio-based flame retardants composed of chitosan (CS) and phytic acid (PA) and carbon-based nanomaterials composed of carbon nanotubes (CNTs) and graphene oxide (GO). The PA-GO/CS-CNTs coated cotton fabric showed excellent flame retardancy with a limiting oxygen index (LOI) value of 31 %, and the coated fabrics could self-extinguish rapidly when the flame was removed. The fire hazard of the coated fabric was significantly reduced by reducing the 45.77 % of peak heat release rate, 29.69 % of total heat release and 81.9 % of total smoke production. The PA-GO/CS-CNTs coated cotton fabric showed ultra-fast fire warning response with the response time of 1.0 s. And the fire-warning response time of the coated cotton fabric could last longer than 600 s revealing it possessed the continuous fire warning response property. This research provides a new strategy to prepare the smart fireproof textiles with flame retardant and fire-warning functions to broaden its application in early fire-warning.

Multi-functionalization of cotton fabrics with excellent flame retardant, antibacterial and superhydrophobic properties.

Cotton fabric is widely used in many fields for its excellent comfortability, breathability and hygroscopicity. However, the development of multifunctional cotton fabrics to meet the requirements of different scenarios is a top priority. In this study, multifunctional coating was constructed through facile layer-by-layer assembly phytic acid and chitosan, and spraying divalent copper ion and polydimethylsiloxane (PDMS) on cotton fabrics, anticipating to endow them with flame retardancy, antibacterial and superhydrophobic properties simultaneously. The treated cotton fabric achieved a limiting oxygen index (LOI) value of 32 %, with the char length reducing to 10.7 cm revealing excellent flame retardancy. The water contact angle of multifunctional treated cotton fabric was above 150°, demonstrating it had superhydrophobicity. The antibacterial rates of multifunctional cotton fabrics against E. coli and S. aureus reached to higher than 99 %, indicating that the excellent antibacterial properties. Combined with the thermal stability of cotton fabrics and their char residues analysis, these results demonstrated that the multifunctional coating could act through intumescent flame retardant mechanism to flame retardant cotton fabrics. This research provides a facile way to prepare multifunctional cotton fabrics to broaden the application prospect.

Preparation of Bismuth Tungstate/Preoxidized Acrylonitrile/Acrylic Acid Copolymer Composite Nanofiber Membrane and Its Photocatalytic Properties.

BACKGROUND: In this patent article, a novel bismuth tungstate/preoxidized acrylonitrile/ acrylic acid (AN/AA) copolymer composite nanofiber membrane was prepared, which was used as the visible light catalyst. METHODS: AN/AA copolymer was synthesized, which was electrospun with bismuth nitrate and sodium tungstate to prepare the composite nanofiber. Then the composite nanofiber was preoxidized to prepare the bismuth tungstate/preoxidized AN/AA composite nanofiber membrane containing adsorption moiety and photocatalytic active moiety. RESULTS: The photocatalytic activity of bismuth tungstate/preoxidized AN/AA composite nanofiber membrane with different preoxidized temperature, heating rate, and holding time by catalytic degradation of methylene blue was investigated. The optimal preoxidized conditions were as follows: the preoxidized temperature was heated to 200 °C with the heating rate of 1°C/min and the holding time at this temperature was 12 h. The chemical structure and morphology of the composite nanofiber membrane were characterized by FTIR, XRD, and SEM. CONCLUSION: The bismuth tungstate/preoxidized AN/AA composite nanofiber membrane obtained good photocatalytic properties and reusability under visible light. The degradation rate of methylene blue by this visible light catalyst could reach 90.24% for 4.5 h, and the degradation rate remained 81.53% for 4.5 h after 5 reuses.

Pyrolysis of Precious Chinese Xuan Paper Containing Ammonium Phytate as a Flame Retardant.

Xuan paper with outstanding cultural and artistic values is one of the most precious Chinese handmade papers and is widely used in traditional calligraphy and painting. However, the highly combustible cellulosic raw materials of Xuan paper present potential fire hazards. Ammonium phytate (AP) originating from biosourced phytic acid has been used for the flame-retardant treatment of Chinese Xuan paper by facile spray coating. The limiting oxygen index value of the treated Xuan paper increased to higher than 40%, demonstrating that the flammability of Xuan paper was greatly reduced by this treatment. The excellent flame retardancy afforded by this treatment was confirmed by cone calorimetry. TGA was used to demonstrate that the presence of AP changed the thermal decomposition process to promote char formation during the degradation of Xuan paper. The flame-retardant mode of action of phytate-coated Xuan paper was investigated using TG-FTIR, SEM, and XPS spectra. A P-N cooperative effect was proposed to account for both the condensed phase and gas-phase flame-retardant actions. The phosphorus component promotes char formation in the condensed phase, while the nitrogen component releases inert species to dilute the fuel load in the gas phase. The ink-wetting property of the coated Xuan paper was influenced negligibly by the coating process. The development of fire-resistant Xuan paper using ecofriendly flame retardants through simple and convenient spray coating has been demonstrated.

Structural Coloration of Polyester Fabrics with High Colorfastness by Copolymer Photonic Crystals Containing Reactive Epoxy Groups.

Structural color as a revolutionary coloration strategy has been proposed to replace the traditional dyeing and printing process. However, the poor colorfastness and easy crack formation of structural colors on textile fabrics restrict their practical application at present. In this study, poly (tert-butyl acrylate-co-glycidyl methacrylate) (P(t-BA-co-GMA)) copolymers containing reactive epoxy groups with different mass ratios of tert-butyl acrylate (t-BA) and glycidyl methacrylate (GMA) were successfully synthesized, which were used to create structural colors on black polyester fabrics. The results showed that P(t-BA-co-GMA) nanospheres could form crack-free structural colors on polyester fabrics, and the colors vary with the mass ratio of t-BA and GMA to obtain five different colors. The different particle sizes of the different P(t-BA-co-GMA) nanospheres with different refractive indexes and the arrangement of short-range ordered and long-range disordered in microstructures may be the reason of different angle-independent structural colors on polyester fabrics. The P(t-BA-co-GMA) nanosphere structural colors on polyester fabrics possess good abrasion and washing colorfastness. This research provides the experimental basis for the development of crack-free amorphous photonic crystal structural color on fabrics with high colorfastness to promote the practical application of structural color in textile coloration.

Eco-friendly flame retardant and dripping-resistant of polyester/cotton blend fabrics through layer-by-layer assembly fully bio-based chitosan/phytic acid coating.

Polyester/cotton blend fabrics are widely used in clothing and household textiles which combine the comfort of cotton and excellent mechanical strength of polyester. However, their high flammability due to the special "wick effect" resulting from the different thermal decomposition process of cotton and polyester causes greatly potential fire hazards. In this study, fully bio-based intumescent flame retardant (IFR) coating of chitosan/phytic acid (CS/PA) was layer-by-layer (LBL) assembly constructed on polyester/cotton blend fabrics. The LOI value of polyester/cotton blend fabric which was LBL assembly coated by 20 bilayers CS/PA reached 29.2%. And the dripping of coated fabric was eliminated. The results of cone calorimetry test confirmed CS/PA coating greatly improved the flame retardancy of polyester/cotton blend fabrics. Thermogravimetric analysis (TGA) results showed CS/PA coating changed the thermal decomposition process to promote the char formation of polyester/cotton blend fabrics. CS/PA coating on fabric could form the IFR system which acts through both condensed phase action by the catalysis dehydration reaction to forming stable char and gas phase action by the blowing effect. This research provides a new strategy to eco-friendly flame retardant and dripping-resistant for polyester/cotton blend fabrics by bio-based IFR system through facile LBL assembly method.

Electrospun polyurethane/phytic acid nanofibrous membrane for high efficient removal of heavy metal ions.

Polyurethane (PU) nanofibers possess large specific surface area and excellent mechanical properties which have been used as the matrix for many applications. Phytic acid is the biocompatible and environment-friendly organic acid with excellent chelating ability of heavy metal ions due to it contains 6 phosphate groups. In this study, the PU/phytic acid nanofibrous membrane has been successfully produced by electrospinning which was used for Pb2+ removal. Though phytic acid would improve the hydrophilicity and reduce the mechanical properties to a certain extent, the phytic acid-modified PU nanofibrous membrane still possessed excellent mechanical properties. The PU/phytic acid nanofibrous membrane achieved the highest adsorption capacity (136.52 mg/g) of Pb2+ under the condition of the pH of Pb2+ solution was 6 and the adsorption temperature and time were 20°C and 10 h which was over 6 times higher the unmodified one's (21.06 mg/g). These results demonstrated that the electrospun PU/phytic acid nanofibrous membrane could obtain high adsorption capacity of Pb2+ and it would achieve the potential application in the fields of the removal of heavy metal ions.

Bio-inspired fabrication of nacre-mimetic hybrid nanocoating for eco-friendly fire-resistant precious cellulosic Chinese Xuan paper.

Nacre-mimetic materials possess excellent thermostability and barrier performance which provide novel idea for high efficient flame retardant strategy. In this study, we propose an eco-friendly approach to fabricate fire-resistant cellulosic Chinese Xuan paper by layer-by-layer (LBL) assembly chitosan (CH) and montmorillonite (MMT). The flame retardancy of Xuan paper was greatly improved after the LBL assembly coated CH/MMT, it achieved excellent flame retardancy when the CH/MMT bilayer was over 10 BL with the LOI value higher than of 35 %. The results of thermal stability of treated Xuan paper revealed the nacre-mimetic CH/MMT nanocoating on Xuan paper would promote the formation of compact and dense char which will be beneficial to inhibit the heat transmission and combustible gas diffusion. The ink wetting performance was also investigated in this study. This research would provide experimental basis for the development of fire-resisting paper using bio-mimetic method to construct nacre-mimetic organic/inorganic hybrid flame retardant system.

Surface modification of bacterial cellulose aerogels by ARGET ATRP.

INTRODUCTION: Bacterial cellulose (BC) aerogels have received more and more attention due to their renewability, biodegradability and other excellent properties in recent years. Modification of BC aerogels using different methods would expand their applications. However, many problems exist for these modifications, such as a low grafting ratio, the larger dosage of metal catalyst required and so on. Activator regeneration by electron transfer (ARGET) for atom transfer radical polymerization (ATRP) is a novel ATRP method which could significantly reduce the amount of metal catalyst required and achieve a high grafting ratio. METHODS: Novel nanostructured BC aerogels containing epoxy groups were prepared by the ARGET ATRP method. BC aerogels were functionalized with initiating sites by reaction with 2-bromoisobutyryl bromide (BiBBr), and followed by ARGET ATRP reaction with glycidyl methacrylate (GMA) which was catalyzed by copper(II) bromide (CuBr2) and N,N,N',N,'N"-pentamethyldiethylenetriamine (PMDETA), and then reduced by vitamin C. BC aerogels containing epoxy groups (BC-g-PGMA) were obtained after freeze-drying. The influence factors of the solvent ratio of N,N-dimethyl formamide (DMF)/toluene, monomer concentration, the concentration of CuBr2, the molar ratio of vitamin C (Vc)/CuBr2,reaction temperature and time on the grafting ratio were investigated. RESULTS: The results showed that the optimal DMF and toluene volume ratio was 2:1, the optimal monomer and CuBr2 concentration were 2 mol/l and 1.5 mmol/l. The optimal molar ratio of PMDETA/CuBr2 and Vc/CuBr2 were 4:1 and 1:1. The optimal reaction temperature and time were 60°C and 9 h. Scanning electron microscopy (SEM) images showed that GMA was strongly adhered onto the surface and inside of the BC pellicle. CONCLUSIONS: GMA was self-grown on the BC surface and achieved the high grafting ratio of 1052.7% under optimal conditions. The BC-g-PGMA aerogels containing the epoxy groups will provide wider application prospects in drug release, enzyme fixed, functional materials and other fields.

Electrospun epoxy-based nanofibrous membrane containing biocompatible feather polypeptide for highly stable and active covalent immobilization of lipase.

In this study, a novel poly (glycidyl methacrylate-co-methylacrylate)/feather polypeptide (P(GMA-co-MA)/FP) nanofibrous membrane containing reactive epoxy groups and biocompatible feather polypeptide (FP) was fabricated by electrospinning which was the first time used for the covalent immobilization of lipase. The results of FTIR spectra and SEM images of nanofibrous membrane before and after immobilization demonstrated that lipase has been successfully covalently immobilized on the nanofibrous membrane. FP was beneficial for the stabilization of the enzyme conformation which would promote the improvement of enzyme activity and stability. The P(GMA-co-MA)/FP-Lipase possesses a wide pH tolerance and high thermal stability, good reuse and organic solvent stability. The residual relative activity of immobilized lipase was about 38% which was treated under 70 °C for 3 h. The residual relative activity of immobilized lipase was 62% after 7 reuses and nearly 75% after being treated in methanol for 12 h. This study revealed that the biocompatible FP could be used as an additive to improve the enzyme activity and stability of immobilized enzyme on nanofibrous membranes.