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1.
Chemosphere ; 292: 133389, 2022 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-34953878

RESUMO

Sustainable management of low fertile arid soils using carbon-rich organic amendments such as biochar and compost is of great concern from both agricultural and environmental points of view. The impact of pyrolysis, composting, and co-composting processes of different feedstocks on carbon loss and emissions, soil properties, and plant growth in arid soils with low organic matter content has not been sufficiently explored yet. Consequently, the aim of this work was to 1) investigate the effects of the pyrolysis, composting, and co-composting processes on the properties of the produced biochar, compost, and co-composted biochar from rice straw (RS) and sugarcane bagasse (SB), and 2) examine the impact of addition of RB biochar (RSB), SB biochar (SBB), RS compost (RSC), SB compost (SBC), co-composted RS biochar (RSCB), and co-composted SB biochar (SBCB) at an application dose of 10 ton/hectare on soil properties, carbon emission, and growth of zucchini (Cucurbita pepo) in a sandy arid soil. Carbon loss (kg C kg-1 feedstock) was significantly (P < 0.05) lower during the preparation of the compost (90.36 in RSC, 220.00 in SBC) and co-composted-biochar (146.35 in RSCB, 125.20 in SBCB) than in biochar (176.5 in RSB, 305.6 in SBB). The C/N ratios of the compost and co-composted biochar (11-28.5) were narrower than the corresponding values of biochars (48-90). All amendments increased significantly soil organic carbon content (2.5 in RSC to 5.5 g kg-1 in RSCB), as compared to the non-amended control (1.2 g kg-1). All amendments, particularly RSCB, increased significantly (P < 0.05) the zucchini seed vigor index, dry weight, total chlorophyll content, and root and shoot length, as compared to the control. Moreover, RSCB was the only amendment that showed a positive soil carbon balance. The modified integrated two-way ecological model data also indicated that the co-composted biochar, particularly RSCB, is a promising amendment to improve soil quality and plant growth in sandy arid soils. However, those data should be verified under field conditions.


Assuntos
Compostagem , Oryza , Saccharum , Carbono , Celulose , Carvão Vegetal , Areia , Solo
2.
Environ Sci Pollut Res Int ; 27(8): 8188-8198, 2020 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-31900766

RESUMO

The current research aimed at collecting detailed information about the consequences of cropping history on the accumulation of soil organic carbon (SOC) within different soil depths, i.e., 0-10, 10-20, 20-30 and 30-60 cm. The study site is located at El Gabal El Asfar area (Egypt) whose soils were irrigated with raw sewage effluent as a sole source of irrigation for different periods extended up to 80 years. SOC increased progressively with increasing cropping time, and on the other hand, decreased noticeably with increasing soil depth. The increases significantly correlated with both of the silt and clay contents in soils which increased with time. Soil bulk density and the hydraulic conductivity significantly and negatively correlated with SOC, respectively. Fractions of SOC, i.e., water soluble C, hot water C and soil biomass C in the surface soil layer (0-10 cm), increased progressively with increasing time of land use. Such pools significantly correlated with SOC on one hand and with each other on the other hand. Active (labile) organic carbon fraction increased with time. This fraction also significantly correlated with the different C pools. In conclusion, the hypothesis that SOC is physically protected against soil microbes within the soil requires more investigations to clarify such results obtained herein because this study highlighted the presence of a dynamic equilibrium among the different fractions or pools of the SOC.


Assuntos
Carbono , Solo , Carbono/química , Egito , Esgotos , Água
3.
Ecotoxicol Environ Saf ; 183: 109529, 2019 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-31416013

RESUMO

Radioactive cesium (Cs) is more likely to be trans-located via rainfall into surrounding environments. Upon Cs-contaminated water reaching soil, Cs is retained on soil components, mainly organic matter and clay fraction. This study aims are i) comparing the relative ability of five arid soils, differing in their textural and chemical properties, to accumulate Cs when subjected to Cs-artificially contaminated rain droplets and ii) testing whether K fertilizer can decrease the uptake of Cs and its translocation within plants or not. A lab experiment was then conducted to simulate artificial rain droplets contaminated with 1000 becquerel (Bq) of 134Cs L-1 precipitated on soil columns each of 10.5 cm inner diameter at a rate of 1.15 mL cm-2 over a period of 2-months. At least 89% of 134Cs accumulated within the uppermost 5-cm layer of these soils. Another greenhouse experiment was set to test the hypothesis which indicates that Cs uptake increases unexpectedly by supplying plants with K-fertilizers. In this experiment, canola (Brassica napus L.) seeds were cultivated into three K-deficient soils (Typic Haplotorrent, Typic Haplocalcid, and Typic Torripsamment) which were contaminated with 100 mg Cs kg-1 soil (stable-Cs was used instead of radioactive-Cs to designate its behavior on the long run). Canola plants were fertilized with 0, 80 and 120 mg K2SO4 kg-1 soil. Results carried on Typic Haplotorrent soil confirmed the aforementioned assumption as K-addition increased Cd-uptake up to 40.1%. Contradictory results were achieved in the other two soils where Cs-uptake decreased by 21.5 and 15.3% in Typic Haplocalcid and Typic Torripsamment soils, respectively due to the application of the aforementioned dose of K. In the K non-amended soils, Cs shoot-root translocation factor was >1; yet, it was <1 in response to K addition, regardless of its application rate.


Assuntos
Brassica napus/efeitos dos fármacos , Césio/toxicidade , Fertilizantes/análise , Potássio/análise , Poluentes Radioativos do Solo/toxicidade , Solo/química , Brassica napus/crescimento & desenvolvimento , Césio/análise , Radioisótopos de Césio/análise , Clima Desértico , Egito , Chuva/química , Poluentes Radioativos do Solo/análise
4.
Ecotoxicol Environ Saf ; 175: 173-180, 2019 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-30897416

RESUMO

Proper and economical treatments of wastewater are among the important and potential solutions to increase the water budget. Although mineral ores are barriers of potentially toxic metal contaminants; however to what extent, can these ores stand successfully for decontaminating waters polluted with Cs or Sr is the question of the current study. Therefore a trial was carried out on some of these ores i.e. kaolinite, montmorillonite, and illite, to investigate their effects as decontaminants for waters polluted with either 50 µg Cs L-1 or 50 µg Sr L-1. Results showed that sorption of Cs and Sr increased with decreasing the ratio of the applied sorbents to the quantities of contaminated waters. Such a finding was more obvious when the rate of the sorbent: water was only 1 g L-1. The highest sorption was attained by montmorillonite followed by kaolinite, then Illite. Thus, montmorillonite was selected to complete the sorption studies at a rate of 1 g L-1. Sorption of both Cs and Sr and consequently their removal efficiencies increased with increasing the pH of the sorbents-contaminated waters suspensions up to 7 beyond which significant reductions occurred. Also, increasing the temperature of the suspension resulted in significant increases in the removal efficiencies of the investigated sorbents. Only 120 min were enough to attain the highest removal efficiency. Moreover, Ca-salts could successfully substitute sorbed Cs and Sr on surfaces of the montmorillonite used previously for decontamination of these elements from waters. Accordingly, this mineral ore can be reused successively for further decontamination processes.


Assuntos
Bentonita , Césio , Minerais , Estrôncio , Águas Residuárias/química , Poluentes da Água , Purificação da Água/métodos , Adsorção , Caulim , Poluição da Água
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