Chemometric appraisal of water quality for domestic and agricultural purposes: a case study from establishing Rooppur Nuclear Power Plant (NPP) area, Pabna District, Bangladesh.

Water is the main sources for domestic purposes and as well as for both farming and industrial activities. Therefore, this study investigated the quality of groundwater at Ishwardi, Pabna district of Bangladesh. This study showed that the heavy metals such as Pb, Cd, Cr, As, Ni, Cu, Zn, and Fe were remaining in trace amount. The groundwater quality index (GWQI), heavy metal evaluation index (HEI), heavy metal pollution index (HPI), and degree of contamination (Cd) revealed that all of the groundwater samples belonged to good quality condition for drinking purposes. Nevertheless, Cd provided better index than other indices. Subsequently, hazard quotient (HQ) and hazard index (HI) values for heavy metals indicated that there was no significant noncarcinogenic health risk due to oral ingestion of groundwater except three sites. However, the paired student t-test ([Formula: see text]) revealed that child was found to be more exposed compared to adult for noncarcinogenic health risk due to oral ingestion of the same groundwater samples. This study revealed that pH, EC, TDS, salinity, Na+, K+, Mg2+, Ca2+, Cl-, SO42-, PO43-, and NO3- values in water samples are in tolerable limit according to Bangladesh (DoE) and international standards (WHO, IS, FAO, USEPA, UCCC). Subsequently, combined approaches of numerous irrigation water quality indices, sodium adsorption ratio (SAR), soluble sodium percentage (SSP), total hardness (TH), residual sodium carbonate (RSC), and Kelley's ratio (KR), were applied to appraise the appropriateness of water for farming purposes. The irrigation water quality index (IWQI) revealed that majority of the groundwater samples were suitable for agricultural purposes. Classification based on Wilcox and US salinity hazard diagram indicated a consistent conclusion, which indicated that the water quality was in good condition for farming in the study area.

Characterization of groundwater hydrogeochemistry, quality, and associated health hazards to the residents of southwestern Bangladesh.

In this research, we intended to appraise the hydrogeochemistry and human health risks of groundwater (GW) in southwestern Bangladesh, applying hydrogeochemical techniques, GW quality index (GWQI), several pollution indices, and mathematical health risk models. The trace elements (TEs) and ionic composition of GW samples were analyzed by atomic absorption spectroscopy and ion chromatography (AAS-IC) technique. The evaporate dissolution, silicate weathering, and ionic exchange processes control the hydrogeochemistry in GW. The GWQI revealed that 34% of samples were poor to very poor quality for drinking purposes, whereas irrigation water quality indices suggested moderate suitability of GW. The mean hazard quotient (HQ) and hazard index (HI) exceeded the tolerable level for adults and children, making substantial chronic health impacts on humans. The estimated carcinogenic risk of As and Pb surpassed the upper level of 1 × 10-4 for both aged populations. Overall, the results indicate that the local inhabitants have detrimental health risks; hence, effective regulation and proper measures should be concentrated for continuous monitoring, assessment, and remediation of As, Mn, Pb, and Hg in the study area.

Variability of water quality and metal pollution index in the Ganges River, Bangladesh.

The Ganges River is one of the biggest transboundary streams in the Indian sub-continent. The significant part of this waterway channel drains one of the most densely populated areas on the planet so it is unequivocally influenced by human activities. Unprecedented high-temporal-resolution samples were collected for investigating the seasonal variability of water quality. Water quality index (WQI) reveals large seasonal variation among three major seasons and also indicates that the river water is not suitable for drinking and other household uses. The dominant water facies is bicarbonate (HCO3-). The water quality indices, %Na, Kelley's ratio (KR), sodium adsorption ratio (SAR), and magnesium adsorption ratio (MAR), reveal that the water is appropriate for irrigation. The permeability index (PI) indicated that the water is moderate to poorly useable for agricultural purposes. Heavy metals concentrations demonstrated significant seasonal variations with high concentrations during the monsoon due to flushing of pollutants from catchment areas by intense monsoonal precipitations. In addition, local activities such as oil spills from the boat, vehicle washing water, and agricultural runoff may also added pollutants. The single-factor pollution index (Ii) and Nemerow pollution index (Ni) exhibits minor pollution. The values of heavy metal pollution index (HPI) are far below than the critical limit (100) for the studied month, although relatively higher HPI values found for April, August, and November than other months might come from domestic wastes and agricultural activities. The heavy metal evaluation index (HEI) values of all the months indicated a low degree of pollution. Even though the river water pollution level is low, the authority should take proper management and monitoring strategy for sustainable use.

Groundwater salinization and associated co-contamination risk increase severe drinking water vulnerabilities in the southwestern coast of Bangladesh.

Household drinking water security is one of the major issues among coastal communities in Bangladesh. To examine the groundwater quality and social consequences, groundwater samples and household questionnaires were administered across the study area. Instrumental and statistical tools were used to analyze the water quality and social survey data. The average concentrations of electrical conductivity (EC) (7135.67 µS/cm), total dissolved solids (TDS) (3691 mg/L), Na+ (1569.51 mg/L), Ca2+ (289.5 mg/L), Mg2+ (340.51 mg/L), Cl- (2940.78 mg/L), F- (11.85 mg/L), NO3- (54.44 mg/L), NO2- (162.95 mg/L), PO43- (105.19 mg/L), Fe (4.9 mg/L), Mn (1.22 mg/L), As (16.55 µg/L), B (833.28 µg/L), and Pb (34.22 µg/L) were observed in groundwater, and exceeded the drinking water standards from 30% to 100% depending on the sampling location. Thus, the remarkably high contents of EC, TDS, Cl-, and Na+ represented possible saltwater intrusion along the coastal aquifer. The positive correlations between EC and trace and toxic elements indicated the potential influence of groundwater salinization on the dissolution of more chemical contaminants in the aquifer. These results showed that 100% of samples were unsuitable for drinking purposes. Severe drinking water scarcity is a serious issue, and local people have been affected by water-related diseases owing to the long-term consumption of contaminated water. Salinity problems in drinking water and related health diseases have increased significantly in the past several years. In addition, climate change and its associated hazards, including sea-level rise, cyclonic storm surges, flooding, and resulting inundation problems, have intensified the drinking water scarcity and health problems at the community level. To ensure household water security, environmental exposure, hydrogeology, and anthropogenic interventions must be considered to determine future sustainable water policies.