Analytical study of 226Ra activity concentration in market consuming foodstuffs of Ramsar, Iran.

BACKGROUND: Ramsar, a city of Iran located on the coast of the Caspian Sea, has been considered to be enormously important due to its high natural radioactivity levels. People living in High Level Natural Radiation Areas (HLNRAs) have been exposed by several sources, one of which could be foodstuff. However, many studies have been carried out to measure the environmental radioactivity in Ramsar, but no survey has been conducted in all stapled consumed foods yet. This study was dedicated to determine 226Ra activity concentration in the daily diets of Ramsar residents as a probable exposure. METHODS: Approximately 70 different market samples were collected during the four seasons based on the daily consumption patterns of residents which have the highest consumption and their availability in the seasons. All samples, after washing, drying and pretreatment, were analyzed for 226Ra radionuclide determination by α-spectrometry. RESULTS: The mean radioactivity concentration of 226Ra ranged between 7 ± 1 mBq Kg-1 wet weight in meat, and 318 ± 118 mBq Kg-1 for tea dry leaves. The 226Ra activity concentrations in collected samples varied from below the minimum detectable activity up to 530 ± 30 mBq Kg-1. To compare the results with United Nations Scientific Committee on Effects of Atomic Radiation (UNSCEAR) reference values, the 226Ra activity concentrations concluded from the results appear to be higher in milk, chicken and eggs and less in grain products, vegetables, fruits and fish products. These results indicate that no significant 226Ra contamination is present in market foodstuffs and provide reference values for the foodstuffs in Ramsar. CONCLUSIONS: Of the total daily dietary 226Ra exposure from market consuming foodstuffs for adults in Ramsar, the largest percentage was from wheat. The residents consuming wheat and manufacturing wheat products such as bread, pasta, porridge, crackers, biscuits, pancakes, pies, pastries, cakes, cookies, muffins, rolls, doughnuts, breakfast cereals and so on may receive an elevated dose in the diet. In conclusion, with regards to presence of 226Ra in foodstuffs it is necessary to monitor regularly the activity of 226Ra in foodstuffs including market and local foods.

Radon exhalation rate and natural radionuclide content in building materials of high background areas of Ramsar, Iran.

Radon exhalation rates from building materials used in high background radiation areas (HBRA) of Ramsar were measured using an active radon gas analyzer with an emanation container. Radon exhalation rates from these samples varied from below the lower detection limit up to 384 Bq.m(-2) h(-1). The (226)Ra, (232)Th and (40)K contents were also measured using a high resolution HPGe gamma- ray spectrometer system. The activity concentration of (226)Ra, (232)Th and (40)K content varied from below the minimum detection limit up to 86,400 Bq kg(-1), 187 Bq kg(-1) and 1350 Bq kg(-1), respectively. The linear correlation coefficient between radon exhalation rate and radium concentration was 0.90. The result of this survey shows that radon exhalation rate and radium content in some local stones used as basements are extremely high and these samples are main sources of indoor radon emanation as well as external gamma radiation from uranium series.

Estimates of the occupational exposure to tenorm in the phosphoric acid production plant in Iran.

Phosphate rock is used world wide for manufacturing phosphoric acid and several chemical fertilisers. It is known that the phosphate rock contains various concentrations of uranium, thorium, radium and their daughters. The subject of this study is the evaluation of the radiation exposure to workers in the phosphoric acid production plant due to technologically enhanced naturally occurring radioactive materials that can result from the presence of naturally occurring radioactive materials in phosphate ores used in the manufacturing of phosphoric acid. Radiation exposure due to direct gamma radiation, dust inhalation and radon gas has been investigated and external and internal doses of exposed workers have been calculated. Natural radioactivity due to (40)K, (226)Ra and (232)Th have been measured in phosphate rock, phosphogypsum, chemical fertilisers and other samples by gamma spectrometry system with a high-purity germanium. The average concentrations of (226)Ra and (40)K observed in the phosphate rock are 760 and 80 Bq kg(-1), respectively. Annual effective dose from external radiation had a mean value of ∼0.673 mSv y(-1). Dust sampling revealed greatest values in the storage area. The annual average effective dose from inhalation of long-lived airborne was 0.113 mSv y(-1). Radon gas concentrations in the processing plant and storage area were found to be of the same value as the background. In this study the estimated annual effective doses to workers were below 1 mSv y(-1).

Evaluation of occupational exposure to naturally occurring radioactive materials in the Iranian ceramics industry.

Zircon contains small amounts of uranium, thorium and radium in its crystalline structure. The ceramic industry is one of the major consumers of zirconium compounds that are used as an ingredient at ∼10-20 % by weight in glaze. In this study, seven different ceramic factories have been investigated regarding the presence of radioactive elements with focus on natural radioactivity. The overall objective of this investigation is to provide information regarding the radiation exposure to workers in the ceramic industry due to naturally occurring radioactive materials. This objective is met by collecting existing radiological data specific to glaze production and generating new data from sampling activities. The sampling effort involves the whole process of glaze production. External exposures are monitored using a portable gamma-ray spectrometer and environmental thermoluminescence dosimeters, by placing them for 6 months in some workplaces. Internal routes of exposure (mainly inhalation) are studied using air sampling, and gross alpha and beta counting. Measurement of radon gas and its progeny is performed by continuous radon gas monitors that use pulse ionisation chambers. Natural radioactivity due to the presence of ²³8U, ²³²Th and 4°K in zirconium compounds, glazes and other samples is measured by a gamma-ray spectrometry system with a high-purity germanium detector. The average concentrations of ²³8U and ²³²Th observed in the zirconium compounds are >3300 and >550 Bq kg⁻¹, respectively. The specific activities of other samples are much lower than in zirconium compounds. The annual effective dose from external radiation had a mean value of ∼0.13 mSv y⁻¹. Dust sampling revealed the greatest values in the process at the powdering site and hand weighing places. In these plants, the annual average effective dose from inhalation of long-lived airborne radionuclides was 0.226 mSv. ²²²Rn gas concentrations in the glaze production plant and storage warehouse were found to range from 10 to 213 Bq m⁻³. In this study, the estimated annual effective doses to exposed workers were <1 mSv y⁻¹.

Miners' exposure to radon and its decay products in some Iranian non-uranium underground mines.

Measurements of radon, radon decay products and gamma exposure rate in 12 non-uranium underground mines have been carried out in order to estimate the occupational radiation exposure of miners. Continuous measurements of radon using pulse ionisation chambers and scintillation cell techniques were employed for these studies. Progenies of radon were collected on filter paper, and then a three-count procedure was used for the measurement. The equilibrium state between radon and its decay products has been determined. Concentrations of natural radionuclides ((226)Ra, (232)Th and (40)K) in ore and soil samples taken from various locations in each mine have been measured using a Canberra High Purity Germanium detector. Based on these measurements two ranges of dose were evident. Doses ranged from 0.1 to 1.52 mSv y(-1) for nine mines and from 10 to 31 mSv y(-1) for the other three mines. A separate grouping of the mines was recognised from radon concentrations, which varied from 2 Bq m(-3) to 10 kBq m(-3). In three of these mines, working level (WL) concentrations of the order of 36-1771 mWL were determined in different working areas. In all other mines, the concentrations were observed to be <45 mWL.

Exposure to 222Rn in ten underground mines in Iran.

Concentrations of 222Rn were measured in ten non-uranium underground mines in Iran, including three metal mines and seven coal mines. Two active techniques were applied for these measurements (1) activated charcoal and (2) scintillation cell. A maximum mean concentration of 1.33 kBq.m(-3) was found in the Robat-Karim manganese mine with a hot spot of 12 kBq.M(-3), while the concentration in the Venarge-Qom manganese mine was less than 10 Bq.m(-3), leading to annual effective dose equivalents of 8.3 mSv and (0.06 mSv respectively. The mean concentration levels of 222Rn in coal mines were found to be almost 500 Bq.m(-3), leading to annual effective dose equivalent of 3 mSv.