Structural Formation of Alkali-Activated Materials Based on Thermally Treated Marl and Na2SiO3.

Modern materials science is aimed towards abandoning Portland cement in the production of building materials. The scientific novelty of this study lies in its being the first time a comprehensive study of the structure formation of alkali-activated materials (AAM) based on thermally treated marl and Na2SiO3 is carried out. The tasks for achieving this goal were to characterize the thermally treated marl as a new binder, and to comprehensively research the microstructure, fresh, physical, and mechanical properties of the AAM based on the binder. Received active particles of marl with a smaller size than Portland cement have a specific surface area of 580-590 m2/kg. The mineral composition of heat-treated marl is characterized by calcium silicates, which guarantee good binding properties. The results of X-ray diffraction analysis of the samples based on the clinker-free binder of alkaline activation using opoka-like marl confirmed the presence of calcite, quartz, and feldspar close to albite, micas, and zeolites. The obtained products of the chemical interaction of the components of the binder confirm the effectiveness of the newly developed AAM. As a result of comparing several binders, it was found that the binder "thermally treated marl-Na2SiO3" is the most effective, since for specimens based on it, a maximum compressive strength of 42.6 MPa, a flexural strength of 4.6 MPa, and minimum setting time were obtained (start 26 min, end 32 min) as well as a water absorption of 10.2 wt.%. The research results will be of interest to specialists in the construction industry, since the proposed recipes for clinker-free cements are an alternative to expensive and energy-intensive Portland cement and provide the creation of strong and durable concrete and reinforced concrete composites.

Coal Ash Enrichment with Its Full Use in Various Areas.

Increasing the percentage of recycling of various industrial waste is an important step towards caring for the environment. Coal ash is one of the most large-tonnage wastes, which is formed as a result of the operation of thermal power plants. The aim of this work is to develop a technology for the complex processing of coal ash. The tasks to achieve this aim are to develop a technology for the complex enrichment and separation of coal ash into components, with the possibility of their use in various applications, in particular: processing the aluminosilicate part as a pozzolanic additive to cement; carbon underburning for fuel briquettes; the iron-containing part for metallurgy and fertilizers. Complex enrichment and separation into components of coal ash were carried out according to the author's technology, which includes six stages: disintegration, flotation, two-stage magnetic separation, grinding, and drying. The aluminosilicate component has a fairly constant granulometric composition with a mode of 13.56 µm, a specific surface area of 1597.2 m2/kg, and a bulk density of 900 kg/m3. The compressive strength for seven and twenty-eight daily samples when Portland cement is replaced by 15% with an aluminosilicate additive, increases to 30-35%. According to the developed technology, high-calorie fuel briquettes are obtained from underburnt with a density of 1000-1200 kg/m3, a calorific value of 19.5-20 MJ/kg, and an ash content of 0.5-1.5%. The iron-containing component, recovered by two-stage magnetic separation, has the potential to be used in metallurgy as a coking additive, in particular for the production of iron and steel. In addition, an effective micro-fertilizer was obtained from the iron-containing component, which: is an excellent source of minerals; improves the quality of acidic soil; helps soil microorganisms decompose organic matter faster, turning it into elements available to plants; promotes rooting of seedlings; helps to more effectively deal with many pests and diseases. As a result, the complete utilization of coal ash in various applications has been achieved.

Recycling of Cement Industry Waste for Alkali-Activated Materials Production.

The cement industry is recognized as an environmental nuisance, and so there is a need to not only minimizes the consumption of cement, but also to completely recycle the waste of the cement industry. This paper's originality lies in the fact that, for the first time, a comprehensive study of the structure formation of alkali-activated materials (AAM) based on aspiration dust and clinker dust has been carried out. The tasks for achieving this goal were to characterize cement production waste as a new binder and comprehensively research the microstructure, fresh, physical, and mechanical properties of alkali-activated material based on a cement-free binder. Grains of cement production waste are represented by coarse volumetric particles with pronounced cleavage, and a clear presence of minerals is observed. The mineral composition of cement production waste is characterized by calcium silicates, which guarantee good binding properties. The results of the X-ray diffraction analysis of the samples (based on the alkaline-activated cement-free binder using clinker dust and aspiration dust) confirmed the presence of calcite, quartz, feldspar close to albite, micas, and zeolites. The obtained products of the chemical interaction of the binder components confirm the effectiveness of the newly developed AAM. As a result of comparing several binders, it was found that the binder based on aspiration dust with Na2SiO3 and Na2SiF6 was the most effective, since, for specimens based on it, a density of 1.8 g/cm3, maximum compressive strength of 50.7 MPa, flexural strength of 5.6 MPa, minimum setting time (starting at 24 min and ending at 36 min), and water absorption of 12.8 wt. % were obtained. The research results will be of interest to specialists in the construction industry since the proposed recipes for eco-friendly, alkali-activated materials are an alternative to expensive and energy-intensive Portland cement, and they provide for the creation of strong and durable concrete and reinforced concrete composites.

Thermodynamic Simulation of Environmental and Population Protection by Utilization of Technogenic Tailings of Enrichment.

During mining, only 4-8% is converted to final products, and the rest is accumulated in landfills. There is a lack of research on the study of various patterns and mechanisms of the formation of cement clinker minerals during the simultaneous distillation of zinc. This paper presents studies of thermodynamic stimulation of environmental and population protection by utilization of technogenic enrichment waste as secondary raw materials for clinker production and zinc extraction. In particular, a comparison of the Gibbs energy (ΔG) of clinker formation under standard chemical equations and under non-standard chemical equations is given. According to the results of the study, using thermodynamic simulation, the temperature intervals of mineral formation, the dependence of the Gibbs energy on temperature (ΔGT°), and the approximation equations were found; it was established that the presence of zinc ferrite contributes to the intensification of the formation of clinker minerals and the extraction of Zn to gas.

Recyclable Materials for Ecofriendly Technology.

This Special Issue (SI), "Recyclable Materials for Ecofriendly Technology", has been proposed and organized as a means to present recent developments in the field of environmentally friendly designed construction and building materials. For this purpose, dozens of articles were included or considered for inclusion in this SI, covering various aspects of the topic. A comparison of these articles with other modern articles on this topic is carried out, which proves the prospects and relevance of this SI. Furthermore, per the editorial board's journal suggestion, the second volume of this successful SI is being organized, in which authors from various countries and organizations are invited to publish their new and unpublished research work.

Porous Fly Ash/Aluminosilicate Microspheres-Based Composites Containing Lightweight Granules Using Liquid Glass as Binder.

The modern energy-saving vector of development in building materials science is being implemented in a complex way through the development of new heat-insulating materials with the simultaneous exclusion of low-ecological cement from them. This article presents the results of the development of resource-saving technology for a heat-insulating composite material. The research is devoted to the development of scientific ideas about the technology and properties of effective cementless lightweight concretes. The aim of the work is to create a heat-insulating composite material based on porous granules and a matrix from mixtures of liquid glass and thermal energy waste. The novelty of the work lies in establishing the patterns of formation of a stable structure of a porous material during thermal curing of liquid glass with technogenic fillers. Studies of liquid glass mixtures with different contents of fly ash and aluminosilicate microspheres revealed the possibility of controlling the properties of molding masses in a wide range. To obtain a granular material, liquid glass mixtures of plastic consistency with a predominance of aluminosilicate microspheres are proposed. The matrix of composite materials is formed by a mobile mixture of liquid glass and a combined filler, in which fly ash predominates. The parameters of heat treatment of granular and composite materials are established to ensure the formation of a strong porous waterproof structure. The possibility of regulating the structure of composite materials due to different degrees of filling the liquid glass matrix with porous granules is shown. A heat-insulating concrete based on porous aggregate has been developed, characterized by the genetic commonality of the matrix and the granular component, density of 380-650 kg/m3, thermal conductivity of 0.095-0.100 W/(m °C) and strength of 3.5-9.0 MPa, resistance under conditions of variable values of humidity and temperature. A basic technological scheme for the joint production of granular and composite materials from liquid glass mixtures is proposed.

Demolition Waste Potential for Completely Cement-Free Binders.

Due to renovation and fighting in the world, a huge accumulation of construction and demolition waste is formed. These materials are effectively used as aggregates, but there is very little information about the use of scrap concrete to create cementless binders. The purpose of the work is to be a comprehensive study of the composition and properties of concrete wastes of various fractions with the aim of their rational use as cementless binders. The scientific novelty lies in the fact that the nature of the processes of structure formation of a cementless binder based on sandy fractions of the screening of fragments of destroyed buildings and structures, as a complex polyfunctional system, has been theoretically substantiated and experimentally confirmed. Different percentages of non-hydrated clinker minerals in concrete scrap were determined. In the smallest fraction (less than 0.16 mm), more than 20% of alite and belite are present. Waste of the old cement paste is more susceptible to crushing compared to the large aggregate embedded in it, therefore, particles of the old cement paste and fine aggregate predominate in the finer fractions of the waste. Comprehensive microstructural studies have been carried out on the possibility of using concrete scrap as a completely cementless binder using scanning electron microscopy, X-ray diffraction analysis, and differential thermal analysis. It has been established that for cementless samples prepared from the smallest fractions (less than 0.315 mm), the compressive strength is 1.5-2 times higher than for samples from larger fractions. This is due to the increased content of clinker minerals in their composition. The compressive strength of the cementless binder after 28 days (7.8 MPa), as well as the early compressive strength at the age of 1 day after steaming (5.9 MPa), make it possible to effectively use these materials for enclosing building structures.

Analysis of Stress-Strain State for a Cylindrical Tank Wall Defected Zone.

In the study, experimental and theoretical studies were carried out to assess the influence of the shapes of dents in the tank wall on the stress-strain state of the defect zone. By testing fragments of a cylindrical tank, it was found that the most appropriate expression is (5), which could take into account the leaching of the tank wall, resulting in a decrease in the stress concentration index. At the same time, during theoretical studies in this paper, it was found that polynomials determined the stress concentration coefficient, where the obtained analytical expression data were compared with the data determined numerically in the ANSYS program, and it was found that the spread was from 2% to 10%. According to the results of a numerical study of the stress-strain state of the dent zone in the tank wall, graphical dependences of the stress concentration coefficient on the dimensionless depth of the dent for various values of the dimensionless radius of the dents and do not exceed 2% of the indicators that are obtained. At the conclusion of the experimental and numerical studies, a conclusion was made about the degree of influence of the geometric dimensions of the dents on the stress concentration index.

Cementitious Grouts for Semi-Flexible Pavement Surfaces-A Review.

The hybrid type of pavement called semi-flexible or grouted macadam has gained popularity over the last few decades in various countries, as it provides significant advantages over both rigid and conventional flexible pavements. The semi-flexible pavement surface consists of an open-graded asphalt mixture with high percentage voids into which flowable cementitious slurry is allowed to penetrate due to gravitational effect. Several researchers have conducted laboratory, as well as field, experiments on evaluating the performance of semi-flexible layers using different compositions of cementitious grouts. The composition of grouts (i.e., water/cement ratio, superplasticizer, polymers, admixtures, and other supplementary materials) has a significant effect on the performance of grouts and semi-flexible mixtures. A comprehensive review of cementitious grouts and their effect on the performance of semi-flexible layers are presented and summarized in this review study. The effect of byproducts and other admixtures/additives on the mechanical properties of grouts are also discussed. Finally, recommendations on the composition of cementitious grouts have been suggested.

Structural Formation of Soil Concretes Based on Loam and Fly Ash, Modified with a Stabilizing Polymer Additive.

Finding new ways of recycling production waste to improve the characteristics of various building materials is an urgent scientific task. This article substantiates the possibility of the disposal of fly ash in the composition of soil concrete, which is used in the construction of the structural layers of road pavements, foundations of buildings and structures, as well as sites for various purposes. The scientific novelty lies in the fact that the structure formation of soil concretes based on loam and fly ash and modified with a stabilizing additive is being studied for the first time. It was found that the investigated fly ash, according to its hydraulic properties, is classified as latent active and can be introduced into the compositions of road soil concrete modified with additives of various resources. The effectiveness of the complex method of stabilization, due to changes in soil properties as a result of the use of the binding and stabilizing additives of polymer nature "Kriogelit", is shown. It was found that the optimal content of binder and fly ash in the samples was 8 and 10 wt.%, respectively. It was established that the use of the stabilizing additive "Kriogelit" makes it possible to obtain soil concrete with the highest strength (compressive strength 2.5 MPa, flexural strength 0.5 MPa) and frost resistance of at least F15. The microstructure, the degree of dehydration and carbonization, and the phase composition of the initial raw mixtures and soil concretes stabilized with the addition of "Kriogelit" were studied by methods of scanning electron microscopy, X-ray diffraction analysis, differential scanning calorimetry, thermogravimetry, and infrared spectroscopy. It was shown that organo-mineral complexes, with the participation of polymer and montmorillonite, are formed in stabilized soil concrete. It was revealed that structure formation is accompanied by the physical adsorption of the polymer on active centers of silicate minerals, carbonization, and hydration-dehydration processes. It was found that the reason for the increase in the strength of stabilized soil concretes is the hydrophobization of the porous structure of minerals, as well as the formation of calcium oxide silicate and dicalcium hydrated silicate. By the method of performing biotests with the test objects Daphnia magna Straus and Chlorella vulgaris Beijer, it was proven that the developed road concretes modified with the stabilizing additive "Kriogelit" do not have an acute toxic effect on the test objects and are safe for the environment and human health.

Development of a Thermomechanical Treatment Mode for Stainless-Steel Rings.

This article describes a technology for the thermomechanical treatment of stainless-steel piston rings. This technology makes it possible to obtain rings with an optimal combination of plastic and strength properties that is essential for piston rings. The following thermomechanical treatment is suggested for piston rings manufacturing: quenching at 1050 °C, holding for 30 min and cooling in water, then straining by the HPT method for eight cycles at cryogenic temperature and annealing at a temperature up to 600 °C. The resulting microstructure consisted of fine austenite grains sized 0.3 µm and evenly distributed carbide particles. Annealing above this temperature led to the formation of ferrite in the structure; however, preserving the maximum fraction of austenitic component is very important, since the reduction of austenite in the structure will cause a deterioration of corrosion resistance. The strength properties of steel after such treatment increased by almost two times compared with the initial ones: microhardness increased from 980 MPa to 2425 MPa, relative elongation increased by 20%. The proposed technology will improve the strength and performance characteristics of piston rings, as well as increase their service life, which will lead to significant savings in the cost of repair, replacement and downtime.

Experimental Analysis of the Stress State of a Prestressed Cylindrical Shell with Various Structural Parameters.

The paper presents the results of experimental studies of the features of the operation of prestressed shells, taking into account the various structural parameters of the prestress. It is established that when the winding angle changes from perpendicular to the shell axis to 75° and 65°, the circumferential stresses decrease 1.4 times and 1.2 times, respectively, and the axial stresses increase five and three times, which are two and four times lower than the circumferential, from which it can be concluded that the reduction in the winding angle to the longitudinal the axis of the shell has a positive effect on the stress state of the structure. The study also found that with an increase in the diameter of the winding wire from 1 to 2 mm and a change in the winding angle, the same nature of the stress distribution is observed, but the values of the stress state parameter change, so the efficiency increases up to 25% due to an increase in the winding thickness, depending on the pitch, angle and thickness of the winding, which favorably affects the strength and the bearing capacity of the structure as a whole by increasing the value of the stress state parameter. Thus, the results of the analysis will allow us to use in more detail the possibility of controlling the stress-strain state of the prestressed shell by changing the design parameters, and the results obtained can be used in design or construction, as well as when increasing the strength characteristics of the structure, which allows us to create a high-tech design optimal for these operating conditions, which can positively complement the studies conducted earlier in this direction.

Mechanical Feasibility Study of Pressed and Burned Red Ceramic Blocks as Structural and Sealing Masonry.

In the search for better constructive efficiency and a reduction of the waste of construction materials, several researches have been performed in the last years around the world. Red ceramic blocks are artifacts widely used in civil construction around the world, and they result in a great consumption of raw materials and energy. The great innovation of this research was the development of ceramic blocks through an innovative method of pressing and dosing materials, replacing the traditional stage of extrusion in the manufacture of ceramics. In such a sense, a new manufacturing technology for ceramic blocks was proposed through the pressing process, adapting the soil-cement brick press machine, thus attaining more even pieces with greater compliance to the dimensions and preset geometry. In this work, the physical and mechanical features of the pressed and burned blocks (PBB) are produced in a partnership with Arte Cerâmica Sardinha, a traditional ceramic industry in the region of Campos dos Goytacazes, RJ, Brazil. It was sought to set the quality parameters for the blocks, to set their mechanical compressive strength, deformation modules and the Poisson coefficient. The blocks were tested in use by means of three layers of prism and small wall samples, and it was checked the fragile-type failure of the PBB. Results indicate that the blocks can be employed in small-sized construction works, as the characteristic compressive strength to block measured was 3.62 N/mm2 for average water absorption of 20.84%.

Technogenic Fiber Wastes for Optimizing Concrete.

A promising method of obtaining mineral fiber fillers for dry building mixtures is the processing of waste that comes from the production of technogenic fibrous materials (TFM). The novelty of the work lies in the fact that, for the first time, basalt production wastes were studied not only as reinforcing components, but also as binder ones involved in concrete structure formation. The purpose of the article is to study the physical and mechanical properties of waste technogenic fibrous materials as additives for optimizing the composition of raw concrete mixes. To assess the possibility of using wastes from the complex processing of TFM that were ground for 5 and 10 min as an active mineral additive to concrete, their chemical, mineralogical, and granulometric compositions, as well as the microstructure and physical and mechanical characteristics of the created concretes, were studied. It is established that the grinding of TFM for 10 min leads to the grinding of not only fibers, but also pellets, the fragments of which are noticeable in the total mass of the substance. The presence of quartz in the amorphous phase of TFM makes it possible to synthesize low-basic calcium silicate hydrates in a targeted manner. At 90 days age, at 10-20% of the content of TFM, the strength indicators increase (above 40 MPa), and at 30% of the additive content, they approach the values of the control composition without additives (above 35 MPa). For all ages, the ratio of flexural and compressive strengths is at the level of 0.2, which characterizes a high reinforcing effect. Analysis of the results suggests the possibility of using waste milled for 10 min as an active mineral additive, as well as to give better formability to the mixture and its micro-reinforcement to obtain fiber-reinforced concrete.

Recent Trends in Advanced Radiation Shielding Concrete for Construction of Facilities: Materials and Properties.

Nuclear energy offers a wide range of applications, which include power generation, X-ray imaging, and non-destructive tests, in many economic sectors. However, such applications come with the risk of harmful radiation, thereby requiring shielding to prevent harmful effects on the surrounding environment and users. Concrete has long been used as part of structures in nuclear power plants, X-ray imaging rooms, and radioactive storage. The direction of recent research is headed toward concrete's ability in attenuating harmful energy radiated from nuclear sources through various alterations to its composition. Radiation shielding concrete (RSC) is a composite-based concrete that was developed in the last few years with heavy natural aggregates such as magnetite or barites. RSC is deemed a superior alternative to many types of traditional normal concrete in terms of shielding against the harmful radiation, and being economical and moldable. Given the merits of RSCs, this article presents a comprehensive review on the subject, considering the classifications, alternative materials, design additives, and type of heavy aggregates used. This literature review also provides critical reviews on RSC performance in terms of radiation shielding characteristics, mechanical strength, and durability. In addition, this work extensively reviews the trends of development research toward a broad understanding of the application possibilities of RSC as an advanced concrete product for producing a robust and green concrete composite for the construction of radiation shielding facilities as a better solution for protection from sources of radiation. Furthermore, this critical review provides a view of the progress made on RSCs and proposes avenues for future research on this hotspot research topic.

Destructive and Non-Destructive Testing of the Performance of Copper Slag Fiber-Reinforced Concrete.

Concrete technology is adopted worldwide in construction due to its effectiveness, performance, and price benefits. Subsequently, it needs to be an eco-friendly, sustainable, and energy-efficient material. This is achieved by replacing or adding energy-efficient concrete materials from industries, such as ground granulated blast furnace slag, steel slag, fly ash, bottom ash, rice husk ash, etc. Likewise, copper slag is a waste material produced as molten slag from the copper industry, which can be used in concrete production. Copper slag can perform roles similar to pozzolans in the hydration process. This paper extends the comparative study of copper slag concrete with polypropylene fiber (PPF) subjected to destructive and non-destructive testing. Under destructive testing, compressive strength of concrete cubes, compressive strength of mortar cubes, splitting tensile tests on cylindrical specimens, and flexural tests on plain cement concrete were conducted and analysed. Ultrasonic pulse velocity and rebound hammer tests were performed on the samples as per IS13311-Part 1-1992 for non-destructive testing. The 100% replacement of copper slag exhibited a very high workability of 105 mm, while the addition of 0.8% PPF decreased the flowability of the concrete. Hence, the workability of concrete decreases as the fiber content increases. The density of the concrete was found to be increased in the range of 5% to 10%. Furthermore, it was found that, for all volume fractions of fiber, there was no reduction in compressive strength of up to 80% of copper slag concrete compared to control concrete. The 40% copper slag concrete was the best mix proportion for increasing compressive strength. However, for cement mortar applications, 80% copper slag is recommended. The findings of non-destructive testing show that, except for 100% copper slag, all mixes were of good quality compared to other mixes. Linear relationships were developed to predict compressive strength from UPV and rebound hammer test values. This relationship shows better prediction among dependent and independent values. It is concluded that copper slag has a pozzolanic composition, and is compatible with PPF, resulting in good mechanical characteristics.

Hardening of Bimetallic Wires from Secondary Materials Used in the Construction of Power Lines.

Copper-sheathed steel wires combine the conductivity of copper and the traction resistance of steel, which makes a bimetallic wire an ideal material for the construction of power lines. Currently, there is a small number of studies devoted to the change in the microstructure of steel-copper wire during its strain. Since steel and copper have different mechanical properties, these metals at the interface can be deformed in different ways. Therefore, the present research is devoted to the study of ECAP-drawing process impacts on the properties of bimetallic steel-copper wire. During the conducted studies, the possibility and efficiency of using the combined strain technology for the formation of ultrafine grained structure and increased strength properties of steel-copper wire have been proved.

Effects of Admixtures on Energy Consumption in the Process of Ready-Mixed Concrete Mixing.

The production and utilization of concrete and concrete-based products have drastically increased with the surge of construction activities over the last decade, especially in countries such as China and India. Consequently, this has resulted in a corresponding increase in the energy used for the production of ready-mixed concrete. One approach to reduce the cost of concrete manufacturing is to reduce the energy required for the manufacturing process. The main hypothesis of this study is that the power required for mixing the concrete can be reduced through the use of mineral admixtures in the mix design. Optimization of energy consumption during mixing using admixtures in concrete manufacturing is the predominant focus of this article. To achieve this objective, power consumption data were measured and analyzed throughout the concrete mixing process. The power consumption curve is the only source to distinguish the behavior of the different materials used in the concrete in a closed chamber. In the current research, fly ash and ground granulated blast-furnace slag (GGBS) were used as mineral admixtures to produce ready-mixed concrete. The experimental study focused on the influence of GGBS and fly ash on power consumption during concrete mixing. The results indicated that the use of a higher content of GGBS is more beneficial in comparison to the use of fly ash in the mix due to the lower mixing time required to achieve homogeneity in the mixing process. It was found that the amount of energy required for mixing is directly related to the mixing time for the mix to achieve homogeneity.

Effect of Steel Fiber on the Strength and Flexural Characteristics of Coconut Shell Concrete Partially Blended with Fly Ash.

The construction industry relies heavily on concrete as a building material. The coarse aggregate makes up a substantial portion of the volume of concrete. However, the continued exploitation of granite rock for coarse aggregate results in an increase in the future generations' demand for natural resources. In this investigation, coconut shell was used in the place of conventional aggregate to produce coconut shell lightweight concrete. Class F fly ash was used as a partial substitute for cement to reduce the high cement content of lightweight concrete. The impact of steel fiber addition on the compressive strength and flexural features of sustainable concrete was investigated. A 10% weight replacement of class F fly ash was used in the place of cement. Steel fiber was added at 0.25, 0.5, 0.75, and 1.0% of the concrete volume. The results revealed that the addition of steel fibers enhanced the compressive strength by up to 39%. The addition of steel fiber to reinforced coconut shell concrete beams increased the ultimate moment capacity by 5-14%. Flexural toughness was increased by up to 45%. The span/deflection ratio of all fiber-reinforced coconut shell concrete beams met the IS456 and BS 8110 requirements. Branson's and the finite element models developed in this study agreed well with the experimental results. As a result, coconut shell concrete with steel fiber could be considered as a viable and environmentally-friendly construction material.

Influence of Impurities on the Process of Obtaining Calcium Carbonate during the Processing of Phosphogypsum.

The article is devoted to the study of the influence of residual sulfuric and phosphoric acids on the process of processing large-tonnage phosphogypsum (PG) waste into calcium carbonate. In the Russian Federation, about 10 percent of existing phosphogypsum waste is processed into construction materials. Acidic impurities (phosphoric and sulfuric acids) in their composition are an obstacle to the use of phosphogypsum for the production of binders. This study finds that impurities also reduce the chemical activity of phosphogypsum. At the same time, the paper focuses on the potential of phosphogypsum for the production of calcium carbonate. This article investigated the amount of impurities in phosphogypsum. The results show that during automatic washing of phosphogypsum, losses are approximately 30-35 wt. %. It was also found that phosphogypsum by 22% consists of impurities of phosphoric and sulfuric acid. These acids are characteristic waste products of extraction phosphoric acid (EPA) production. By ASTM C471M-20ae1, the content of calcium sulfate dehydrate and hemihydrate before and after washing was determined. A thermodynamic calculation of the proposed interaction of phosphogypsum with carbonates showed that the characteristic reaction is possible. The conversion process of phosphogypsum to get the corresponding calcium carbonate was carried out at 70 °C. Data on the chemical composition of the reaction products, obtained by X-ray fluorescence analysis on a Shimadzu EDX-7000 spectrometer, showed that some reactions proceed incompletely and need the selection of optimal conditions. The potential commercial benefits of processing phosphogypsum by carbonization were defined for products such as calcium carbonate or its derivatives.