Hierarchical Engineering of Sorption-Based Atmospheric Water Harvesters.

Harvesting water from air in sorption-based devices is a promising solution to decentralized water production, aiming for providing potable water anywhere, anytime. This technology involves a series of coupled processes occurring at distinct length scales, ranging from nanometer to meter and even larger, including water sorption/desorption at the nanoscale, condensation at the mesoscale, device development at the macroscale and water scarcity assessment at the global scale. Comprehensive understanding and bespoke designs at every scale are thus needed to improve the water-harvesting performance. For this purpose, a brief introduction of the global water crisis and its key characteristics is provided to clarify the impact potential and design criteria of water harvesters. Next the latest molecular-level optimizations of sorbents for efficient moisture capture and release are discussed. Then, novel microstructuring of surfaces to enhance dropwise condensation, which is favorable for atmospheric water generation, is shown. After that, system-level optimizations of sorbent-assisted water harvesters to achieve high-yield, energy-efficient, and low-cost water harvesting are highlighted. Finally, future directions toward practical sorption-based atmospheric water harvesting are outlined.

Complementary behaviour of EDL and HER activity in functionalized graphene nanoplatelets.

Green hydrogen production is a vital requirement of the upcoming hydrogen fuel-based locomotion and economy. Water electrolysis facilitated by electricity derived from renewable sources and direct solar-to-hydrogen conversion centred on photochemical and photoelectrochemical water splitting is a promising pathway for sustainable hydrogen production. All these methods require a highly active noble metal catalyst to make the water-splitting process more energy-efficient and in order to make it economical, metal-free hydrogen evolution catalysts such as graphene nanoplatelets (GNPs) are essential. Herein, we report the effect of a range of functionalizations on the catalytic properties of graphene nanoplatelets (GNPs) for the hydrogen evolution reaction (HER). We also account for the effect of functionalization on the strength of the electrical double layer formation on the surface of functionalized GNPs. It is observed that the catalytic activity and the electrical double layer strength are inversely related to each other. Our first-principles-based density functional theoretical (DFT) modelling unravels the origin of the observed electrocatalytic activity and its trend and the strength of the electrical double layers in terms of free energy changes during the ion absorption/desorption events on the electrode surface. Based on our observations, minimizing the electrical double layer strength is identified as an approach to improve the catalytic performance of the catalysts.

Highly enhanced durability of a graphitic carbon layer decorated PtNi3 alloy electrocatalyst toward the oxygen reduction reaction.

The durability issue of a carbon supported PtNi3 alloy catalyst (PtNi3/C) under acidic conditions has been solved by introducing an N-doped graphitic carbon (NGC) layer to coat the surface of the PtNi3/C catalyst. The as-prepared PtNi3/C@NGC catalyst exhibits superior durability, being able to undergo 10 000 voltage cycles with negligible activity decay.