Aggregation-Dependent Dielectric Permittivity in 2D Molecular Crystals.

The functionality of 2D molecular crystal-based devices crucially depends on their intrinsic properties, such as molecular energy levels, light absorption efficiency, and dielectric permittivity, which are highly sensitive to molecular aggregation. Here, it is demonstrated that the dielectric permittivity of the 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8 -BTBT) molecular crystals on monolayer WS2 substrates can be tuned from 4.62 in the wetting layer to 2.25 in the second layer. Its origin lies in the different molecular orientations in the wetting layer (lying-down) and in the subsequently stacked layers (standing-up), which lead to a positive Coulomb coupling (JCoup ) value (H-aggregation) and a negative JCoup value (J-aggregation), respectively. Polarized optical contrast spectroscopy reveals that the permittivity of C8 -BTBT is anisotropic, and its direction is related to the underlying substrate. The study offers guidelines for future manipulation of the permittivity of 2D molecular crystals, which may promote their applications toward various electronic and optoelectronic devices.

Modelling and simulation of photosystem II chlorophyll fluorescence transition from dark-adapted state to light-adapted state.

Green houses play a vital role in modern agriculture. Artificial light illumination is very important in a green house. While light is necessary for plant growth, excessive light in a green house may not bring more profit and even damages plants. Developing a plant-physiology-based light control strategy in a green house is important, which implies that a state-space model on photosynthetic activities is very useful because modern control theories and techniques are usually developed according to model structures in the state space. In this work, a simplified model structure on photosystem II activities was developed with seven state variables and chlorophyll fluorescence (ChlF) as the observable variable. Experiments on ChlF were performed. The Levenberg-Marquardt algorithm was used to estimate model parameters from experimental data. The model structure can fit experimental data with a small relative error (<2%). ChlF under different light intensities were simulated to show the effect of light intensity on ChlF emission. A simplified model structure with fewer state variables and model parameters will be more robust to perturbations and model parameter estimation. The model structure is thus expected useful in future green-house light control strategy development.