Influence of different stalks on the metallization degree of FeCl3-derived magnetic biochar through pyrolysis behavior and compositional differences.

To investigate the effect of stalk type on the metallization degrees in FeCl3-derived magnetic biochar (MBC), MBC was synthesized via an impregnation-pyrolysis method using six different stalks. The Fe0 content in MBC significantly influenced its magnetic properties and ostensibly governed its catalytic capabilities. Analysis of the interaction between stalks and FeCl3 revealed that the variation in metallization degrees, resulting from FeCl2 decomposition (6.1%) and stalk-mediated reduction (20.7%), was directly responsible for the observed differences in MBC metallization. The presence of oxygen-containing functional groups and fixed carbon appeared to promote metallization in MBC induced by reduction. A series of statistical analyses indicated that the cellulose, lignin, and hemicellulose content of the stalks were key factors contributing to differences in MBC metallization degrees. Further exploration revealed that hemicellulose and cellulose were more effective than lignin in enhancing metallization through FeCl2 decomposition and reduction. Constructing stalk models demonstrated that the variance in the content of these three biomass components across the six stalk types could lead to differences in the metallization degree attributable to reduction and FeCl2 decomposition, thereby affecting the overall metallization degree of MBC. A prediction model for MBC metallization degree was developed based on these findings. Moreover, the elevated Si content in some stalks facilitated the formation of Fe2(SiO4), which subsequently impeded the reduction process. This study provides a theoretical foundation for the informed selection of stalk feedstocks in the production of FeCl3-derived MBC.

Influence mechanisms of different stalks on iron species type of magnetic biochar prepared from Fe2O3.

The current selection of biomass feedstock for magnetic biochar (MBC) catalysts is highly blind. Consequently, this study delves into understanding how the types of biomass influence the iron species present in MBC catalysts. The process involved the creation of MBC through simulated impregnation-pyrolysis, utilizing six types of stalks and Fe2O3. The type of iron species significantly impacted magnetic properties and likely influenced catalytic properties of MBC. MBC's iron species type was shaped by the reduction effects of the diverse stalks on Fe2O3. During the pyrolysis, discrepancies were observed in the release of reducing gases and direct reduction for the different stalks. These differences in reduction behavior directly accounted for the distinct reduction effects. To delve deeper, the reduction behavior and effect of the main components of the stalk (hemicellulose, cellulose, and lignin) on Fe2O3 were analyzed, highlighting lignin as the most effective. Nonetheless, the absolute values of Pearson's r between lignin content in the stalk and reduction behavior/effect ranged only from 0.078 to 0.421. In contrast, the values for K, Ca, and Si content in the stalks and their influence on reduction behavior and MBC's reduction/metallization degree ranged from 0.410 to 0.910. The catalytic impacts of K and Ca were confirmed through their incorporation into cotton and reed stalks. The disparities in K, Ca, and Si content among the six stalks appeared to be the primary driver behind the diverse iron species in MBC. This work provides a scientific basis for the rational selection of biomass feedstock for MBC catalysts.

The advanced treatment of textile printing and dyeing wastewater by hydrodynamic cavitation and ozone: Degradation, mechanism, and transformation of dissolved organic matter.

The emission standards for textile printing and dyeing wastewater are stricter due to serious environmental issues. A novel technology, hydrodynamic cavitation combined with ozone (HC + O3), has attracted wide attention in wastewater advanced treatment, whereas the contaminants removal mechanism and transformation of dissolved organic matter (DOM) were rarely reported. This study investigated the removal efficiency and mechanism of HC + O3. The maximum removal rates of UV254, chrominance, CODCr, and TOC were 64.99%, 91.90%, 32.30%, and 36.67% in 60 min, respectively, at the inlet pressure of 0.15 MPa and O3 dosage of 6.25 mmol/L. The synergetic coefficient of HC + O3 was 2.77. The removal of contaminants was the synergy of 1O2, ·OH and ·O2-, and high molecular weight and strong aromaticity organic matters were degraded effectively. The main components in DOM were tryptophan-like and tyrosine-like, which were effectively removed after HC + O3. Meanwhile, most DOM had decreased to low apparent relative molecular weight (LARMW) compounds. Additionally, the HC + O3 effluent can reach the emission standard in 60 min for 8.07 USD/m3. It can be concluded that HC + O3 is an effective technology for the advanced treatment of industrial wastewater. This study will provide suggestions for the engineering application of HC + O3.

Impact of water matrices on oxidation effects and mechanisms of pharmaceuticals by ultraviolet-based advanced oxidation technologies: A review.

The binding between water components (dissolved organic matters, anions and cations) and pharmaceuticals influences the migration and transformation of pollutants. Herein, the impact of water matrices on drug degradation, as well as the electrical energy demands during UV, UV/catalysts, UV/O3, UV/H2O2-based, UV/persulfate and UV/chlorine processes were systemically evaluated. The enhancement effects of water constituents are due to the powerful reactive species formation, the recombination reduction of electrons and holes of catalyst and the catalyst regeneration; the inhibition results from the light attenuation, quenching effects of the excited states of target pollutants and reactive species, the stable complexations generation and the catalyst deactivation. The transformation pathways of the same pollutant in various AOPs have high similarities. At the same time, each oxidant also can act as a special nucleophile or electrophile, depending on the functional groups of the target compound. The electrical energy per order (EEO) of drugs degradation may follow the order of EEOUV > EEOUV/catalyst > EEOUV/H2O2 > EEOUV/PS > EEOUV/chlorine or EEOUV/O3. Meanwhile, it is crucial to balance the cost-benefit assessment and toxic by-products formation, and the comparison of the contaminant degradation pathways and productions in the presence of different water matrices is still lacking.

Application of external carbon source in heterotrophic denitrification of domestic sewage: A review.

The carbon source is essential as an electron donor in the heterotrophic denitrification process. When there is a lack of organic carbon sources in the system, an external carbon source is needed to improve denitrification efficiency. This review compiles the effects of liquid, solid and gaseous carbon sources on denitrification. Sodium acetate has better denitrification efficiency and is usually the first choice for external carbon sources. Fermentation by-products have been demonstrated to have the same denitrification efficiency as sodium acetate. Compared with cellulose-rich materials, biodegradable polymers have better and more stable denitrification performance in solid-phase nitrification, but their price is higher than the former. Methane as a gaseous carbon source is studied mainly by aerobic methane oxidation coupled with denitrification, which is feasible using methane as a carbon source. Liquid carbon sources are better controlled and utilized than solid carbon sources and gaseous carbon sources. In addition, high carbon to nitrogen ratio and hydraulic retention time can promote denitrification, while high dissolved oxygen (DO>2.0 mg L-1) will inhibit the denitrification process. At the same time, high temperature is conducive to the decomposition of carbon sources by microorganisms. This review also considers the advantages and disadvantages of different carbon sources and cost analysis to provide a reference for looking for more economical and effective external carbon sources in the future.

Preparation of magnetic biochar and its application in catalytic degradation of organic pollutants: A review.

In recent years, magnetic biochar (MBC) has been greatly concerned because of its magnetic separation characteristics, and has been successfully used as a catalyst in the catalytic degradation of organic pollutants. However, there is currently a lack of a more systematic summary of MBC preparation methods, and no detailed overview of the catalytic mechanism of MBC catalysts for the degradation of organic pollutants. Therefore, we carry out this work to fill the above gaps. At first, we summarize the raw materials, preparation methods, and types of MBC in detail, and emphasize the MBC prepared by iron-containing sludge. Then, the catalytic mechanisms of MBC in peroxydisulfate, peroxymonosulfate, Fenton-like, photocatalysis, and NaBH4 systems are carefully summarized, highlighting the contribution of various parts of MBC in catalysis. The degradation efficiency of organic pollutants in the above systems is evaluated. Finally, the stability and reusability of MBC catalysts are evaluated. In conclusion, this review contributes a meager force to the future development of MBC.

Preparation, characterization, and application of magnetic activated carbon for treatment of biologically treated papermaking wastewater.

In view of the urgent need for tertiary treatment of papermaking wastewater and the difficulty in separating powdered activated carbon (PAC) from water, the magnetic activated carbon (33%-MPAC, 50%-MPAC and 67%-MPAC) were prepared by chemical coprecipitation method for adsorption of biologically treated papermaking wastewater (BTPW). A series of characterization of MPAC and PAC were carried out and show that the content of iron oxides is negatively related to the proportion of micropores in MPAC. The loaded iron oxides is mainly the mixture of magnetite and maghemite, and the maximum saturation magnetization of MPAC can reach 29.68 emu/g. Batch mode experiments were performed, and found that the adsorption effect of MPAC is slightly worse than that of PAC, the adsorption capacity of COD in MPAC can reach about 65 mg/g, and pH = 2 and 10 °C are more favorable for adsorption. The adsorption isotherms and kinetics were well fitted by the Freundlich model and pseudo-second-order kinetic model, respectively. The selective adsorption was studied by using the excitation emission matrix (EEM) fluorescence spectrum and high-performance size exclusion chromatography (HPSEC). It is concluded that all adsorbents are preferred to adsorb humic acid-like substances (HA). And all adsorbents are preferred to adsorb low apparent molecular weight substances (LAMW, AMW < 1500 Da), with the increase of iron oxides content, the phenomenon of MPAC preferentially adsorbed LAMW became less obvious.