Detecting long-lasting transients of earthquake activity on a fault system by monitoring apparent stress, ground motion and clustering.

Damaging earthquakes result from the evolution of stress in the brittle upper-crust, but the understanding of the mechanics of faulting cannot be achieved by only studying the large ones, which are rare. Considering a fault as a complex system, microearthquakes allow to set a benchmark in the system evolution. Here, we investigate the possibility to detect when a fault system starts deviating from a predefined benchmark behavior by monitoring the temporal and spatial variability of different micro-and-small magnitude earthquakes properties. We follow the temporal evolution of the apparent stress and of the event-specific residuals of ground shaking. Temporal and spatial clustering properties of microearthquakes are monitored as well. We focus on a fault system located in Southern Italy, where the Mw 6.9 Irpinia earthquake occurred in 1980. Following the temporal evolution of earthquakes parameters and their time-space distribution, we can identify two long-lasting phases in the seismicity patterns that are likely related to high pressure fluids in the shallow crust, which were otherwise impossible to decipher. Monitoring temporal and spatial variability of micro-to-small earthquakes source parameters at near fault observatories can have high potential as tool for providing us with new understanding of how the machine generating large earthquakes works.

The shallow structure of Solfatara Volcano, Italy, revealed by dense, wide-aperture seismic profiling.

Two active-source, high-resolution seismic profiles were acquired in the Solfatara tuff cone in May and November 2014, with dense, wide-aperture arrays. Common Receiver Surface processing was crucial in improving signal-to-noise ratio and reflector continuity. These surveys provide, for the first time, high-resolution seismic images of the Solfatara crater, depicting a ~400 m deep asymmetrical crater filled by volcanoclastic sediments and rocks and carved within an overall non-reflective pre-eruptive basement showing features consistent with the emplacement of shallow intrusive bodies. Seismic reflection data were interpreted using the trace complex attributes and clearly display several steep and segmented collapse faults, generally having normal kinematics and dipping toward the crater centre. Fault/fracture planes are imaged as sudden amplitude drops that generate narrow low-similarity and high-dip attributes. Uprising fluids degassed by a magmatic source are the most probable cause of the small-scale amplitude reduction. Seismic data also support the interpretation of the shallow structure of the Solfatara crater as a maar. Our results provides a solid framework to constrain the near-surface geological interpretation of such a complex area, which improves our understanding of the temporal changes of the structure in relation with other geophysical and geochemical measurements.

3D ultra-high resolution seismic imaging of shallow Solfatara crater in Campi Flegrei (Italy): New insights on deep hydrothermal fluid circulation processes.

Seismic tomography can be used to image the spatial variation of rock properties within complex geological media such as volcanoes. Solfatara is a volcano located within the Campi Flegrei, a still active caldera, so it is of major importance to characterize its level of activity and potential danger. In this light, a 3D tomographic high-resolution P-wave velocity image of the shallow central part of Solfatara crater is obtained using first arrival times and a multiscale approach. The retrieved images, integrated with the resistivity section and temperature and the CO2 flux measurements, define the following characteristics: 1. A depth-dependent P-wave velocity layer down to 14 m, with Vp < 700 m/s typical of poorly-consolidated tephra and affected by CO2 degassing; 2. An intermediate layer, deepening towards the mineralized liquid-saturated area (Fangaia), interpreted as permeable deposits saturated with condensed water; 3. A deep, confined high velocity anomaly associated with a CO 2 reservoir. These features are expression of an area located between the Fangaia, water saturated and replenished from deep aquifers, and the main fumaroles, superficial relief of the deep rising CO2 flux. Therefore, the changes in the outgassing rate greatly affect the shallow hydrothermal system, which can be used as a "mirror" of fluid migration processes occurring at depth.

Twin ruptures grew to build up the giant 2011 Tohoku, Japan, earthquake.

The 2011 Tohoku megathrust earthquake had an unexpected size for the region. To image the earthquake rupture in detail, we applied a novel backprojection technique to waveforms from local accelerometer networks. The earthquake began as a small-size twin rupture, slowly propagating mainly updip and triggering the break of a larger-size asperity at shallower depths, resulting in up to 50 m slip and causing high-amplitude tsunami waves. For a long time the rupture remained in a 100-150 km wide slab segment delimited by oceanic fractures, before propagating further to the southwest. The occurrence of large slip at shallow depths likely favored the propagation across contiguous slab segments and contributed to build up a giant earthquake. The lateral variations in the slab geometry may act as geometrical or mechanical barriers finally controlling the earthquake rupture nucleation, evolution and arrest.

A first-principle study of the adsorption of 1-amino-3-cyclopentene on the (100) silicon surface.

The adsorption of 1-amino-3-cyclopentene on the (100) silicon surface has been studied by methods rooted in the density-functional theory using both delocalized (plane waves, PWs) and localized (Gaussian-type orbitals, GTOs) basis functions. The results obtained by modeling the surface by silicon clusters of different sizes are quite similar, thus confirming that the reaction is quite localized. Furthermore, PW and GTO computations give comparable results, provided that the same density functional and carefully chosen computational parameters (contraction of GTO, pseudopotentials, etc.) are used. Slab computations performed in the PW framework show that the cluster results are retrieved when low-coverage adsorption on the surface is considered. On these grounds, we are quite confident that reaction parameters obtained by the more reliable hybrid density functional (PBE0) are essentially converged, our best estimates of reaction and activation free energies are thus -40 and 6 kcal/mol, respectively.