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1.
Environ Sci Technol ; 46(6): 3149-54, 2012 Mar 20.
Artigo em Inglês | MEDLINE | ID: mdl-22313190

RESUMO

Platinum, palladium, and rhodium are emitted from vehicle catalytic converters. Until now, the form of precious metal particles in road dust and urban waste has not been identified. This study has located, imaged, and analyzed these particles in road dust and gully waste. Two fragments of catalytic converter have been observed in road dust. They are 40-80 µm in size and covered in many minute particles (<0.3 µm) of either platinum with minor rhodium or palladium. One fragment identified in gully sediment is smaller, 25 µm in diameter, hosting only one attached particle of palladium with minor rhodium. As fragments are washed off roads they begin to disintegrate and the precious metals become detached. Also precious metal-bearing particles have been located in incinerated sewage ash including a 20 µm diameter cluster of <3 µm sized platinum particles that may be the remains of a catalytic converter fragment that has survived incineration. The form of these precious metal-bearing particles described here reveals that as they are dispersed from roads they are likely to be present predominantly as two particle sizes. Either they are attached to larger fragments of catalytic converter or they are released as individual detached tiny <0.3 µm to nanoparticle sizes.


Assuntos
Poluentes Atmosféricos/análise , Paládio/análise , Platina/análise , Ródio/análise , Monitoramento Ambiental , Tamanho da Partícula , Emissões de Veículos
2.
J Urol ; 175(4): 1439-43, 2006 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-16516016

RESUMO

PURPOSE: Despite the popularity of hand assisted laparoscopic donor nephrectomy published experience is less than that with standard laparoscopic donor nephrectomy and few critical assessments of operative maneuvers have been described. MATERIALS AND METHODS: We describe the impact of changes in operative technique made by a single surgeon during 200 hand assisted laparoscopic donor nephrectomies. RESULTS: With a mean operative time of 229 minutes and hospital stay of 1.9 days the rates of conversion to open surgery, intraoperative complications and major postoperative complications were 1%, 1.5% and 6%, respectively. Lasting changes in technique were dissection of a ureteral/gonadal packet, bipolar cautery use on gonadal/adrenal/lumbar veins and resting the kidney before removal. The incidence of ureteral complications decreased from 8% to 5.1% with dissection of the ureter in conjunction with the gonadal vein rather than isolating it. Warm ischemia time decreased from a mean of 186 to 143 seconds with bipolar electrocautery instead of clips to control gonadal/adrenal/lumbar veins. After starting to rest the kidney before removal the incidence of primary graft nonfunction and delayed function decreased from 6.7% to 0% and 30% to 11.8%, respectively, with a corresponding improvement in 2-year graft survival from 83% to 95%. CONCLUSIONS: This large series of hand assisted donor laparoscopic nephrectomies with a mean followup approaching 3 years demonstrates that the procedure is safe for the donor and procures a good specimen. Decreases in ureteral complications, warm ischemia time and graft dysfunction might be attributable to specific changes in our operative technique.


Assuntos
Laparoscopia , Doadores Vivos , Nefrectomia/métodos , Nefrectomia/estatística & dados numéricos , Adulto , Idoso , Humanos , Pessoa de Meia-Idade , Estudos Retrospectivos , Resultado do Tratamento
3.
Can J Urol ; 11(5): 2393-5, 2004 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-15576005

RESUMO

Scrotal masses are common findings on genitourinary exam. The majority of these masses are benign and can be identified via history and physical exam alone. Question as to the origin of these masses merits additional evaluation that typically consists of an imaging study (e.g., ultrasound) and possibly serum tumor markers (e.g., HCG and AFP). In the end, surgical exploration may be necessary. Herein, the authors describe a rare case of benign paratesticular Schwannoma and discuss the clinical presentation and treatment of scrotal masses.


Assuntos
Neurilemoma/diagnóstico , Neoplasias Testiculares/diagnóstico , Humanos , Masculino , Pessoa de Meia-Idade
4.
J Urol ; 171(5): 1903-4, 2004 May.
Artigo em Inglês | MEDLINE | ID: mdl-15076305

RESUMO

PURPOSE: Counterclockwise penile torsion is a frequently noted congenital deformity. Previously proposed techniques of torsion repair are ineffective or pose significant operative risks. We introduce a novel technique using dorsal dartos flap rotation. MATERIALS AND METHODS: The penis is first degloved completely and a broad based dartos flap is mobilized from the dorsal penile skin. The flap is rotated around the right side of the penile shaft and attached to the ventral aspect, causing clockwise penile rotation. Final slight adjustments are made during skin closure. We applied this technique in 8 patients undergoing circumcision (2), chordee (4) or hypospadias (2) repair. RESULTS: This technique was effective for correcting penile torsion in all patients. At a mean followup of 8.3 months the cosmetic outcome was satisfactory with the complete correction of penile torsion. CONCLUSIONS: Rotational repositioning of a dorsal dartos flap is an effective technique for correcting penile torsion and it is easily applicable with other penile reconstruction procedures.


Assuntos
Doenças do Pênis/cirurgia , Retalhos Cirúrgicos , Pré-Escolar , Seguimentos , Humanos , Lactente , Masculino , Anormalidade Torcional/cirurgia , Procedimentos Cirúrgicos Urológicos Masculinos/métodos
5.
Urology ; 63(1): 175-6, 2004 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-14751379

RESUMO

Displacement of the bladder outside of the pelvis by way of the inguinal canal represents an infrequent presentation of an inguinal hernia that rarely causes urinary tract obstruction. However, bladder hernias can become bothersome, painful, and potentially dangerous. We report a 56-year-old man with a chronic bladder hernia who became acutely unable to empty his bladder from its position in the right hemiscrotum after a motor vehicle accident. At hernia repair, bladder and ischemic bowel were discovered, mandating significant small bowel resection. This case presents interesting considerations and potential pitfalls when evaluating a patient with a bladder hernia.


Assuntos
Hérnia Inguinal/diagnóstico , Intestino Delgado/irrigação sanguínea , Isquemia/diagnóstico , Síndrome da Artéria Mesentérica Superior/diagnóstico , Bexiga Urinária/patologia , Retenção Urinária/etiologia , Acidentes de Trânsito , Hérnia Inguinal/etiologia , Humanos , Intestino Delgado/cirurgia , Isquemia/cirurgia , Masculino , Pessoa de Meia-Idade , Necrose , Obesidade/complicações , Escroto , Síndrome do Intestino Curto/etiologia , Síndrome da Artéria Mesentérica Superior/etiologia , Síndrome da Artéria Mesentérica Superior/cirurgia
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