Utilizing Low-Cost Sensors to Monitor Indoor Air Quality in Mongolian Gers.

Air quality has important climate and health effects. There is a need, therefore, to monitor air quality both indoors and outdoors. Methods of measuring air quality should be cost-effective if they are to be used widely, and one such method is low-cost sensors (LCS). This study reports on the use of LCSs in Ulaanbataar, Mongolia to measure PM2.5 concentrations inside yurts or "gers". Some of these gers were part of a non-government agency (NGO) initiative to improve insulating properties of these housing structures. The goal of the NGO was to decrease particulate emissions inside the gers; a secondary result was to lower the use of coal and other biomass material. LCSs were installed in gers heated primarily by coal, and interior air quality was measured. Gers that were modified by increasing their insulating capacities showed a 17.5% reduction in PM2.5 concentrations, but this is still higher than recommended by health organizations. Gers that were insulated and used a combination of both coal and electricity showed a 19.1% reduction in PM2.5 concentrations. Insulated gers that used electricity for both heating and cooking showed a 48% reduction in PM2.5 but still had higher concentrations of PM2.5 that were 6.4 times higher than recommended by the World Health Organization (WHO). Nighttime and daytime trends followed similar patterns and trends in PM2.5 concentrations with slight variations. It was found that at nighttime the outside PM2.5 concentrations were generally higher than the inside concentrations of the gers in this study, meaning that PM2.5 would flow into the ger whenever the doors were opened, causing spikes in PM2.5 concentrations.

Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) Coupled with an Interferometer for On-Band and Off-Band Detection of Glyoxal.

Glyoxal (CHOCHO) is a trace gas in the atmosphere, often used as an indicator of biogenic emissions. It is frequently compared to formaldehyde concentrations, which serve as indicators of anthropogenic emissions, to gain insights into the characteristics of the environmental source. This study employed broadband cavity-enhanced absorption spectroscopy to detect gaseous CHOCHO, methylglyoxal, and NO2. Two different detection methods are compared. Spectrograph and CCD Detection: This approach involves coupling the system to a spectrograph with a charge-coupled device (CCD) detector. It achieved a 1 min 1-σ detection limit of 2.5 × 108 molecules/cm3, or 10 parts per trillion (ppt). Methylglyoxal and NO2 achieved 1 min 1-σ detection limits of 34 ppt and 22 ppt, respectively. Interferometer and PMT Detection: In this method, an interferometer is used in conjunction with a photomultiplier tube (PMT) detector. It resulted in a 2 min 1-σ detection limit of 1.5 × 1010 molecules/cm3, or 600 ppt. The NO2 2 min 1-σ detection limit was determined to be 900 ppt. Concentrations of methylglyoxal were difficult to determine using this method, as they appeared to be below the detection limit of the instrument. This study discusses the advantages and limitations of each of these detection methods.

Detection of Sulfur Dioxide by Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS).

Sulfur dioxide (SO2) is an important precursor for the formation of atmospheric sulfate aerosol and acid rain. We present an instrument using Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) for the measurement of SO2 with a minimum limit of detection of 0.75 ppbv (3-σ) using the spectral range 305.5-312 nm and an averaging time of 5 min. The instrument consists of high-reflectivity mirrors (0.9985 at 310 nm) and a deep UV light source (Light Emitting Diode). The effective absorption path length of the instrument is 610 m with a 0.966 m base length. Published reference absorption cross sections were used to fit and retrieve the SO2 concentrations and were compared to fluorescence standard measurements for SO2. The comparison was well correlated, R2 = 0.9998 with a correlation slope of 1.04. Interferences for fluorescence measurements were tested and the BBCEAS showed no interference, while ambient measurements responded similarly to standard measurement techniques.

Enhanced Fluorescence in a Scattering Medium.

Often only small amounts of sample are available for spectroscopic analytical determinations. This work investigates the enhancement of signal in columns packed with silica particles. We propose that silica particles cause the light to scatter through the column, effectively increasing optical path length. Packed columns are shown to be effective with fluorescence spectroscopy, but results were inconclusive with absorbance spectroscopy.