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[This corrects the article DOI: 10.1155/2017/1029702.].
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A thorough analysis of the fatty acid profiles of stipe and blade from the kelp species Laminaria hyperborea is presented. Lipid extracts were fractionated into neutral lipids, free fatty acids, and polar lipids, prior to derivatization and GC-MS analysis. A total of 42 fatty acids were identified and quantified, including the n-3 fatty acids α-linolenic acid, stearidonic acid, and eicosapentaenoic acid. The fatty acid amounts are higher in blade than in stipe (7.42 mg/g dry weight and 2.57 mg/g dry weight, resp.). The highest amounts of n-3 fatty acids are found within the neutral lipid fractions with 590.6 ug/g dry weight and 100.9 ug/g dry weight for blade and stipe, respectively. The amounts of polyunsaturated fatty acids are 3.4 times higher in blade than stipe. The blade had the highest PUFA/SFA ratio compared to stipe (1.02 versus 0.76) and the lowest n-6/n-3 ratio (0.8 versus 3.5). This study highlights the compositional differences between the lipid fractions of stipe and blade from L. hyperborea. The amount of polyunsaturated fatty acids compared to saturated- and monounsaturated fatty acids is known to influence human health. In the pharmaceutical, food, and feed industries, this can be of importance for production of different health products.
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Nitramines are potentially carcinogens that form from the amines used in post-combustion CO2 capture (PCCC). The soil sorption characteristics of monoethanol (MEA)- and dimethyl (DMA)-nitramines have been assessed using a batch experimental setup, and defined indirectly by measuring loss of nitramine (LC-MS/MS) from the aqueous phase (0.01 M CaCl2 and 0.1% NaN3) after equilibrium had been established with the soil (24 h). Nitramine soil sorption was found to be strongly dependent on the content of organic matter in the soil (r2 = 0.72 and 0.95, p < 0.05). Soil sorption of MEA-nitramine was further influenced by the quality of the organic matter (Abs254 nm, r2 = 0.93, p < 0.05). This is hypothesized to be due to the hydroxyl group on the MEA-nitramine, capable of forming hydrogen bonds with acidic functional groups on the soil organic matter. Estimated organic carbon normalized soil-water distribution coefficients (KOC) are relatively low, and within the same range as for simple amines. Nevertheless, considering the high content of organic matter commonly found in the top layer of a forest soil, this is where most of the nitramines will be retained. Presented data can be used to estimate final concentrations of nitramines in the environment following emissions from amine-based PCCC plants.