A versatile stable platform for multifunctional applications: synthesis of a nitroDOPA-PEO-alkyne scaffold for iron oxide nanoparticles.

Contemporary magnetic nanoparticle composites are individually designed for specific biomedical applications. We describe the syntheses and characterization of a heterobifunctional polyethylene oxide (PEO) using nitroDOPA as a robust anchoring group on one end and an alkyne as the reactive surface for additional application specific modification.

Polymer microstructured fibers by one-step extrusion.

For the first time to our knowledge, polymer-based microstructured fibers with complex cross-sections are directly produced via melt extrusion. Two principal types of fibers were fabricated: a microstructured fiber of a single polymer with a hexagonal array of air holes and a bicomponent fiber consisting of approximately 60 coaxial rings. From the latter, strong visible iridescence was observed and is shown to exhibit a mechanochromic response. This approach, the mainstay of the textile trade for decades, offers a means of continuous high-volume low-cost manufacturing of polymer (and conceivably soft-glass) fibers. For example, in the present effort, 128 coaxially microstructured fibers were fabricated simultaneously at rates exceeding 1200 m/min from industrially mainstream polymers. This approach offers an important step forward towards commoditizing microstructured fibers and open new doors for optical engineering in fashion, marking/identification, and numerous military applications.

Robust polymer colloidal crystal photonic bandgap structures.

New polymeric matrices are presented that embed organic colloidal crystalline arrays (CCA's) into mechanically stable photonic bandgap structures. We achieved these new matrices either by dispersing polystyrene CCA's with high molecular weight hydrophilic polymer [poly(ethylene glycol); (PEG)] or through in situ polymerization of hydrophilic monomers (acrylamide and acrylate functional PEG variants) about the CCA. CCA-dispersed PEG matrices exhibited strong red opalescence with a narrow peak at 614 nm and were sufficiently rigid to withstand repeated mechanical deformation. Visible photonic bandgaps also were observed from free-standing CCA composites with cross-linked poly(N, N-dimethylacrylamide) matrices. The results demonstrate the technological potential for robust organic photonic crystals.