1.
Chem Commun (Camb)
; 51(39): 8280-3, 2015 May 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25877133
RESUMO
A visible light mediated, but photocatalyst-free method for the oxidative α-CH functionalization of tertiary amines with a broad scope of carbon- and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light triggered activation of polyhalomethanes offers mild conditions for efficient Kharasch-type additions onto non-activated olefins. Preliminary mechanistic studies are reported.