RESUMO
In the study of colloidal glasses, crystallization is often suppressed by leveraging size polydispersity, ranging from systems where particle sizes exhibit a continuous distribution to systems composed of particles of two or more distinct sizes. The effects of the disparities in size of the particles on the colloidal glass transition are not yet completely understood. Especially, the question of the existence of a decoupled glass transition between the large and small population remains. In order to measure colloidal dynamics on very long time scales and to disentangle the dynamics of the two populations, we employ contrast variation multispeckle diffusing wave spectroscopy. With this method, we aim to analyze the effect of size ratio, a = rPS/ rpNIPAM, on particle dynamics near the glass transition of a binary colloidal system. We find that both for long-time (α-) and short-time (ß-) relaxation, the dynamics of the small particles either completely decouple from the large ones ( a = 0.2), moving freely through a glassy matrix, or are identical to the dynamics of the larger-sized population ( a = 0.37 and 1.44). For a size ratio of 0.37, we find a single-glass transition for both particle populations. The postulated double-glass transition in simulations and theory is not observed.
RESUMO
Stresses well below the critical fracture stress can lead to highly unpredictable delayed fracture after a long period of seemingly quiescent stability. Delayed fracture is a major threat to the lifetime of materials, and its unpredictability makes it difficult to prevent. This is exacerbated by the lack of consensus on the microscopic mechanisms at its origin because unambiguous experimental proof of these mechanisms remains absent. We present an experimental approach to measure, with high spatial and temporal resolution, the local deformations that precipitate crack nucleation. We apply this method to study delayed fracture in an elastomer and find that a delocalized zone of very small strains emerges as a consequence of strongly localized damage processes. This prefracture deformation zone grows exponentially in space and time, ultimately culminating in the nucleation of a crack and failure of the material as a whole. Our results paint a microscopic picture of the elusive origins of delayed fracture and open the way to detect damage well before it manifests macroscopically.
RESUMO
Recent advances in microfluidics have enabled the controlled production of multiple-emulsion drops with onion-like topology. The multiple-emulsion drops possess an intrinsic core-shell geometry, which makes them useful as templates to create microcapsules with a solid membrane. High flexibility in the selection of materials and hierarchical order, achieved by microfluidic technologies, has provided versatility in the membrane properties and microcapsule functions. The microcapsules are now designed not just for storage and release of encapsulants but for sensing microenvironments, developing structural colours, and many other uses. This article reviews the current state of the art in the microfluidic-based production of multiple-emulsion drops and functional microcapsules. The three main sections of this paper discuss distinct microfluidic techniques developed for the generation of multiple emulsions, four representative methods used for solid membrane formation, and various applications of functional microcapsules. Finally, we outline the current limitations and future perspectives of microfluidics and microcapsules.
