Mercury evasion from a boreal peatland shortens the timeline for recovery from legacy pollution.

Peatlands are a major source of methylmercury that contaminates downstream aquatic food webs. The large store of mercury (Hg) in peatlands could be a source of Hg for over a century even if deposition is dramatically reduced. However, the reliability of Hg mass balances can be questioned due to missing long-term land-atmosphere flux measurements. We used a novel micrometeorological system for continuous measurement of Hg peatland-atmosphere exchange to derive the first annual Hg budget for a peatland. The evasion of Hg (9.4 µg m-2 yr-1) over the course of a year was seven times greater than stream Hg export, and over two times greater than wet bulk deposition to the boreal peatland. Measurements of dissolved gaseous Hg in the peat pore water also indicate Hg evasion. The net efflux may result from recent declines in atmospheric Hg concentrations that have turned the peatland from a net sink into a source of atmospheric Hg. This net Hg loss suggests that open boreal peatlands and downstream ecosystems can recover more rapidly from past atmospheric Hg deposition than previously assumed. This has important implications for future levels of methylmercury in boreal freshwater fish and the estimation of historical Hg accumulation rates from peat profiles.

The biological precedents for medieval impetus theory and its Aristotelian character.

While the impetus theory is often regarded as a non-Aristotelian theory that could not have emerged within the development of Aristotelianism, I argue that it is essentially Aristotelian. Given the state of the theories of body, movement and sexual reproduction and the development of the theory of the four elements in the Latin West at the end of the thirteenth century, the impetus theory was probably developed as an application to projectiles of Aristotle's theories of the male semen and of family resemblance. In addition, the impetus theory was even a convenient expedient to simplify the Aristotelian theory of movement and prevent it from drifting into non-Aristotelian territory.

Improving the treatment efficiency of constructed wetlands with zeolite-containing filter sands.

In this study the physical and chemical properties of three different lava sands used in constructed wetlands for municipal wastewater treatment were investigated. The aim was to identify those properties and mechanisms that render lava sands as highly efficient filter media which could substitute conventional, fluviatile sands. It was shown that although lava sands per se may be suitable filter materials, the presence of zeolite minerals within the lava sands enhances the purification efficiency tremendously. Zeolites not only increase the sorption capacity, but even more important, they are able to absorb water in large amounts, which in turn leads to stronger swelling. The latter reduces hydrological conductivity considerably, resulting in a longer contact time to eliminate pollutants. A simple mineralogical survey of filter materials for the presence of zeolites may render many installations of constructed wetlands successful.

Determination of anthropogenic input of Ru, Rh, Pd, Re, Os, Ir and Pt in soils along Austrian motorways by isotope dilution ICP-MS.

A joint study with the Federal Environment Agency of Austria was carried out to determine the distribution of Ru, Rh, Pd, Os, Ir and Pt (PGE) and Re in soils along major motorways. Emphasis was put on Ir as to date little is known about its anthropogenic input as this metal is now also used in automobile catalytic converters. Soil samples were analysed by ICP-MS through online-coupling of a chromatographic column to separate the PGEs from interfering matrix constituents. At all sampled sites not only Rh, Pd and Pt but also Ir and Re significantly exceed natural background values; concentrations reached 13 ng/g, 25 ng/g, 134 ng/g, 1.1 ng/g and 9.8 ng/g, respectively. The analytical procedure proved to be very selective and sensitive and, therefore applicable to routine soil analysis.