Lower groundwater ¹4C age by atmospheric CO2 uptake during sampling and analysis.

Uptake of atmospheric CO2 during sample collection and analysis, and consequent lowering of estimated ages, has rarely been considered in radiocarbon dating of groundwater. Using field and laboratory experiments, we show that atmospheric CO2 can be easily and rapidly absorbed in hyperalkaline solutions used for the extraction of dissolved inorganic carbon, resulting in elevated ¹4C measurements. Kinetic isotope fractionation during atmospheric CO2 uptake may also result in decrease of δ¹³C, leading to insufficient corrections for addition of dead carbon by geochemical processes. Consequently, measured ¹4C values of groundwater should not be used for age estimation without corresponding δ¹³C values, and historical ¹4C data in the range of 1 to 10% modern Carbon should be re-evaluated to ensure that samples with atmospheric contamination are recognized appropriately. We recommend that samples for ¹4C analysis should be collected and processed in the field and the laboratory without exposure to the atmosphere. These precautions are considered necessary even if ¹4C measurements are made with an accelerator mass spectrometer.

Seasonal variation of oxygen-18 in precipitation and surface water of the Poyang Lake Basin, China.

Based on the monthly δ(18)O value measured over a hydrology period in precipitation, runoff of five tributaries and the main lake of the Poyang Lake Basin, combined with hydrological and meteorological data, the characteristics of δ(18)O in precipitation (δ(18)OPPT) and runoff (δ(18)OSUR) are discussed. The δ(18)OPPT and δ(18)OSUR values range from-2.75 to-14.12 ‰ (annual mean value=-7.13 ‰ ) and from-2.30 to-8.56 ‰, respectively. The seasonal variation of δ(18)OPPT is controlled by the air mass circulation in this region, which is dominated by the Asian summer monsoon and the Siberian High during winter. The correlation between the wet seasonal averages of δ(18)OSUR in runoff of the rivers and δ(18)OPPT of precipitation at the corresponding stations shows that in the Poyang Lake catchment area the river water consists of 23% direct runoff (precipitation) and 77% base flow (shallow groundwater). This high proportion of groundwater in the river runoff points to the prevalence of wetland conditions in the Poyang Lake catchment during rainy season. Considering the oxygen isotopic composition of the main body of Poyang Lake, no isotopic enrichment relative to river inflow was found during the rainy season with maximum expansion of the lake. Thus, evaporation causing isotopic enrichment is a minor component of the lake water balance in the rainy period. During dry season, a slight isotopic enrichment has been observed, which suggests a certain evaporative loss of lake water in that period.

Deuterium excess in precipitation of Alpine regions - moisture recycling.

The paper evaluates long-term seasonal variations of the deuterium excess (d-excess = delta(2)H - 8. delta(18)O) in precipitation of stations located north and south of the main ridge of the Austrian Alps. It demonstrates that sub-cloud evaporation during precipitation and continental moisture recycling are local, respectively, regional processes controlling these variations. In general, sub-cloud evaporation decreases and moisture recycling increases the d-excess. Therefore, evaluation of d-excess variations in terms of moisture recycling, the main aim of this paper, includes determination of the effect of sub-cloud evaporation. Since sub-cloud evaporation is governed by saturation deficit and distance between cloud base and the ground, its effect on the d-excess is expected to be lower at mountain than at lowland/valley stations. To determine quantitatively this difference, we examined long-term seasonal d-excess variations measured at three selected mountain and adjoining valley stations. The altitude differences between mountain and valley stations ranged from 470 to 1665 m. Adapting the 'falling water drop' model by Stewart [J. Geophys. Res., 80(9), 1133-1146 (1975).], we estimated that the long-term average of sub-cloud evaporation at the selected mountain stations (altitudes between about 1600 and 2250 m.a.s.l.) is less than 1 % of the precipitation and causes a decrease of the d-excess of less than 2 per thousand. For the selected valley stations, the corresponding evaporated fraction is at maximum 7 % and the difference in d-excess ranges up to 8 per thousand. The estimated d-excess differences have been used to correct the measured long-term d-excess values at the selected stations. Finally, the corresponding fraction of water vapour has been estimated that recycled by evaporation of surface water including soil water from the ground. For the two mountain stations Patscherkofel and Feuerkogel, which are located north of the main ridge of the Alps, the maximum seasonal change of the corrected d-excess (July/August) has been estimated to be between 5 and 6 per thousand, and the corresponding recycled fraction between 2.5-3 % of the local precipitation. It has been found that the estimated recycled fractions are in good agreement with values derived from other approaches.