Direct synthesis of hydrothermally stable Ge-IWR zeolites.

The poor hydrothermal stability of germanosilicate zeolites greatly retards their industrial application. Herein, we present a direct synthesis of Ge-containing IWR zeolites with outstanding hydrothermal stability. A simple quaternary ammonium cation, diethyldimethylammonium, was used as the structure-directing agent for the first time. The structure and chemical composition of the framework was studied by performing Rietveld refinement of XRD data combined with electron microscopy, thermogravimetric and chemical analysis techniques. Al-free and Al-containing IWR zeolites were subjected to high-temperature vapor (973 K, 4 h), water-immersion (room temperature, 12 h) and treatment with 65% HNO3 solution (423 K, 24 h) to test their hydrothermal stability. Materials before and after hydrothermal treatments were characterized by complementary methods (XRD, FTIR, NMR and N2 sorption). The set of experimental data unambiguously proves the high stability of the zeolite framework.

Trends and Prospects of Stem Cell Research in China.

Great progresses have been made in fundamental and clinical stem cell research in China in recent years. The official policy on stem cells, which was announced in 2015, seems as the spring of stem cell therapy in China. However, the regulation, governance, and management of clinical expectations are still challenging. This review summarized the current stem cell research and development in the field, as well as its rapidly evolving commercial, regulatory and ethical environment in China. As expected, the prospects of stem cells in China look prospective.

Shape selectivity extending to ordered supermicroporous aluminosilicates.

In the synthesis of polyoxymethylene dimethyl ethers (PODEn) catalyzed by ordered supermicroporous aluminosilicates, shape selectivity was observed and the high selectivity for target products (PODE3-8) was attributed to the particular pore diameter.