1.
Org Lett
; 18(12): 2864-7, 2016 06 17.
Artigo
em Inglês
| MEDLINE
| ID: mdl-27232158
RESUMO
Hg(OTf)2-catalyzed aryl-allene cyclization accompanied by formation of a quaternary carbon center has been realized. Deuterium-labeling experiments and computational modeling were used to propose a novel catalytic pathway involving direct H-transfer from the aromatic ring to the vinyl mercury moiety followed by mercury 1,2-migration.