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1.
Mass Spectrom (Tokyo) ; 12(1): A0115, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-37250597

RESUMO

Northwest Africa (NWA) 2977 is a lunar basaltic meteorite that was found in 2005 and has been classified as an olivine cumulate gabbro. This meteorite contains a shock melt vein (SMV) induced by an intense shock event. We report herein on an in-situ analysis of phosphates in the host gabbro and the shock vein for the U-Pb dating of NWA 2977 using an ion microprobe, NanoSIMS. The majority of the analyzed phosphates, in both the SMV and host-rock, lie on a linear regression in 238U/206Pb-207Pb/206Pb-204Pb/206Pb three-dimensional space, indicating a total Pb/U isochron age of 3.15±0.12 Ga (95% confidence level), which is consistent ages determined in previous isotopic studies of NWA 2977 (Sm-Nd age of 3.10±0.05 Ga, Rb-Sr age of 3.29±0.11 Ga, and Pb-Pb baddeleyite age of 3.12±0.01 Ga), and identical to the age of the U-Pb phosphate in a paired meteorite NWA 773, 3.09±0.20 Ga, derived from our dataset. There was no clear difference in the formation age between the phosphates found in the SMV and host-rock, although the shape and size of the grains and the Raman spectra show the evidence of intense shock metamorphism. Based on these findings, the cooling rate of the phosphate was very rapid, constrained to be larger than 140 K/s.

2.
J Nat Prod ; 76(6): 1085-90, 2013 Jun 28.
Artigo em Inglês | MEDLINE | ID: mdl-23755851

RESUMO

Four new abietane diterpenoids (1-4), a new 9(10→20)-abeo-abietane diterpenoid (5), and a new sesquiterpene pyridine alkaloid (6) were isolated from the roots of Euonymus lutchuensis along with 19 known compounds. The structures of the new compounds were elucidated by interpretation of the spectroscopic data.


Assuntos
Abietanos/isolamento & purificação , Alcaloides/isolamento & purificação , Euonymus/química , Piridinas/isolamento & purificação , Sesquiterpenos/isolamento & purificação , Abietanos/química , Alcaloides/química , Japão , Estrutura Molecular , Ressonância Magnética Nuclear Biomolecular , Raízes de Plantas/química , Piridinas/química , Sesquiterpenos/química
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