1.
Angew Chem Int Ed Engl
; 38(3): 397-400, 1999 Feb 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29711660
RESUMO
Regio- and stereoselective homoallylation of saturated aldehydes and ketones to give bishomoallyl alcohols 1,3-anti-1 is achieved with [Ni(acac)2 ] (cat.) and Et2 Zn [Eq. (a)]. This new catalyst system thus complements the previously reported combination of [Ni(acac)2 ] with Et3 B, which offers advantages in the homoallylation of unsaturated and aromatic aldehydes. acac=acetylacetonato.