1.
Chem Commun (Camb)
; 60(48): 6170-6173, 2024 Jun 11.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38804674
RESUMO
A titanium-mediated aza-BODIPY synthesis using diketopyrrolopyrrole bearing o-anisyl substituents provided B,O-chelated pyrrolopyrrole aza-BODIPYs in a one-pot manner via ether bond cleavage and chelation of the resulting nucleophilic oxygen to the boron atom. The B,O-chelation not only induces the redshifts of absorption and fluorescence but also endows chiroptical properties.